2024 Vol. 45, No. 4

Separating and Extracting of Vanadium and Titanium
Preparation and properties of polyvinylpyrrolidone & polyvinyl chloride composite proton exchange membrane for vanadium redox flow batteries
Dai Yu, Zeng Zehua, Zhang Dongbin, Teng Aijun, Liu Tianhao, Yin Xianglu, Yuan Xinran
2024, 45(4): 1-7. doi: 10.7513/j.issn.1004-7638.2024.04.001
Abstract(269) HTML (45) PDF(34)
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Proton exchange membrane (PEM), as a key component of vanadium redox flow battery (VRFB), plays an important role in controlling the performance and cost of VRFB. A series of PVP&PVC composite PEMs were prepared, wherein PVP carried out ion conduction in the membrane due to the protonation of am...
Study on the influences of melt components on the physical properties of molten salt chlorination system
He Yilin, Xu Jianlin, Ma Zhanshan, Pang Zhongya, Zhu Fuxing, Zou Xingli, Lu Xionggang
2024, 45(4): 8-15, 28. doi: 10.7513/j.issn.1004-7638.2024.04.002
Abstract(99) HTML (31) PDF(20)
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The physical properties of chloride molten salt are very important for the preparation efficiency of titanium tetrachloride produced by molten salt chlorination. To investigate the influence of changes in chloride-containing molten salt composition on the physical properties of molten salt systems, ...
Study on preparation of VOSO4 by chemical synthesis of sodium metavanadate
Xiafuhati Airikenjiang, Wen Jing, Yu Tangxia, Jiang Tao
2024, 45(4): 16-22. doi: 10.7513/j.issn.1004-7638.2024.04.003
Abstract(198) HTML (29) PDF(22)
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Vanadium sulfate (VOSO4) electrolyte is the active material and energy carrier of electrochemical reaction in vanadium battery, and its quality directly affects the performance of vanadium battery such as energy efficiency, energy density and service life. In this paper, VOSO4 was synthesized from s...
Preparation of high quality spherical powder of TC4 ELI titanium alloy
Chen Guangrun, Ma Lan, Yang Shaoli, Xiao Jian, Wang Qiangbing
2024, 45(4): 23-28. doi: 10.7513/j.issn.1004-7638.2024.04.004
Abstract(119) HTML (52) PDF(11)
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Using titanium alloy rod TC4 ELI as raw material, spherical TC4 ELI powder was prepared by plasma rotating electrode method (PREP). The effects of current and electrode speed on the particle size distribution and powder properties were investigated. The morphology of the powder was observed using a ...
Research on wet gringding dispersion properties of different rutile TiO2 initial products
Yang Fang, Liu Chan, Lu Ruifang, Shi Ruicheng
2024, 45(4): 29-33. doi: 10.7513/j.issn.1004-7638.2024.04.005
Abstract(98) HTML (35) PDF(16)
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In this work, four kinds of industrial TiO2 initial products were used as raw materials to study the wet gringding dispersion of Zn series TiO2 and Al series TiO2 at different concentrations. Then, the difference of dispersion properties was analyzed by the characterization of slurry viscosity, disp...
Effect of different support on the catalytic performance of V-Mo/Ti De-NOx catalyst
Yue Yanwei, Huang Li, Lu Luyang, Wang Suqin, Xu Shun, Wang Hu, Zong Yuhao, Xie Xingxing
2024, 45(4): 34-40. doi: 10.7513/j.issn.1004-7638.2024.04.006
Abstract(111) HTML (34) PDF(12)
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V-Mo/Ti de-NOx catalysts were prepared by two kinds of TiO2 with different BET surface area. XRD, N2-adsorption, H2-TPR, Raman, NH3-TPD, O2-TPD, and SO2-TPD analysis were used to characterize the physiochemical properties of the different catalysts. The catalytic performances of the catalysts were t...
Application of Vanadium and Titanium
Study on the biaxial tensile behavior of commercial pure titanium at room temperature
Miao Zihao, Chang Le, Zhou Changyu, He Xiaohua
2024, 45(4): 41-47. doi: 10.7513/j.issn.1004-7638.2024.04.007
Abstract(235) HTML (52) PDF(27)
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In this study, biaxial tensile tests were conducted on the commercial pure titanium plates using cruciform specimens. The impact of biaxial tensile stress state on the mechanical properties was explored through Digital Image Correlation (DIC) to capture the strain response. The effect of biaxial ten...
Study on the corrosion resistance of vanadium-based V3TiNi0.56Crx (x=0, 0.2, 0.4, 0.6)/NiMoW composite cathode for hydrogen evolution
Du Jinjing, Zhang Xuan, Zhou Yu, Cui Xinxin, Zhu Jun, Zuo Heng, Wang Bin, Bao Yanru, Liu Jingtian, Guo Yuehao
2024, 45(4): 48-53. doi: 10.7513/j.issn.1004-7638.2024.04.008
Abstract(153) HTML (31) PDF(16)
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This article mainly studied the influence of Cr element on the electrocatalytic performance and corrosion resistance of vanadium-based V3TiNi0.56Crx(x=0,0.2,0.4,0.6)/NiMoW composite cathode for hydrogen evolution. The phase, morphology, electrocatalytic performance, and corrosion resistance of V3TiN...
Effect of intermediate annealing on the microstructure and texture of cold rolled pure titanium plates
Tang Min
2024, 45(4): 54-61. doi: 10.7513/j.issn.1004-7638.2024.04.009
Abstract(92) HTML (58) PDF(10)
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A comparative and systematic study was conducted on the effects of annealing temperatures on the microstructure and texture of cold-rolled pure titanium plates using testing methods and analysis methods such as Electron Backscatter Diffraction (EBSD). The results show that when the intermediate anne...
Phase transformation mechanism of Ti-6Al-4V titanium alloy induced by tensile deformation
Sun Hao
2024, 45(4): 62-67. doi: 10.7513/j.issn.1004-7638.2024.04.010
Abstract(78) HTML (40) PDF(11)
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Phase transition behavior plays a crucial role on the plastic deformation and mechanical properties of titanium alloy. Therefore, it is very necessary to study the phase transition behavior and further reveal the corresponding mechanism of titanium alloy. In this paper, a novel heat treatment proces...
Influence of stacking direction on the local cyclic plastic behavior of selective laser melted TC4 alloy notched parts
Wang Zhiqiang, Li Jian, Zhao Xun, Zhao Xuetong, Xu Yingdong, Tang Mingyang, Liu Qing, Ge Junming, Xiao Min
2024, 45(4): 68-75. doi: 10.7513/j.issn.1004-7638.2024.04.011
Abstract(65) HTML (37) PDF(7)
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In this paper the influence of stacking direction on the local cyclic plastic behavior of selective laser melted (SLM) TC4 alloy notched parts had been investigated through digital image correlation technology. The results indicate that the plastic deformation near the root of the notched parts can ...
Prediction of high temperature rheological behavior of TC4 titanium alloy based on Z-A constitutive model
Shen Jiancheng, Jia Haishen, Zhang Jilin, Luo Wencui, Yi Xiangbin
2024, 45(4): 76-83. doi: 10.7513/j.issn.1004-7638.2024.04.012
Abstract(96) HTML (35) PDF(10)
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The constitutive model plays an important role in describing the response behavior of materials under different deformation conditions and in optimizing the hot forming process. Therefore, in order to obtain the physical constitutive model for accurately describing the high temperature rheological b...
Technical Review
Assessing the role of vanadium technologies in decarbonizing hard-to-abate sectors and enabling the energy transition
David A Santos, Manish K Dixit, Pranav Pradeep Kumar, Sarbajit Banerjee
2024, 45(4): 84-94. doi: 10.7513/j.issn.1004-7638.2024.04.013
Abstract(244) HTML (68) PDF(44)
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The decarbonization of heavy industry and the emergence of renewable energy technologies are inextricably linked to access to mineral resources. As such, there is an urgent need to develop benchmarked assessments of the role of critical elements in reducing greenhouse gas emissions. Here, we explore...
Research progress on deactivation mechanism and preventive measures of V2O5-WO3 / TiO2 catalyst
Jin Jiahao, Cai Zongying, Liang Jinglong, Song Shaofei, Cao Weigang
2024, 45(4): 95-104. doi: 10.7513/j.issn.1004-7638.2024.04.014
Abstract(184) HTML (46) PDF(26)
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With growing global energy demand and the improvement of environmental protection requirements, selective catalytic reduction (SCR) technology has attracted considerable attention as an effective way to reduce atmospheric nitrogen oxide (NOx) emissions. However, the vanadium-titanium-based V2O5-WO3/...
Ferrous Metallurgy and Materials
Change of phase composition and valuable elements in V-Ti pellet during softening-melting and dripping process
Xie Hong’en, Zheng Kui, Huang Chu, Zhu Fengxiang, Liu Juan
2024, 45(4): 105-112, 128. doi: 10.7513/j.issn.1004-7638.2024.04.015
Abstract(186) HTML (55) PDF(22)
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The change of phase composition and valuable elements in the process of softening-melting and dripping of acidic V-Ti pellet of Pangang were quantitatively studied by simulating the smelting atmosphere in blast furnace. The results show that Ti and V gradually migrated from titanohematite and ilmeni...
Thermodynamic model of dephosphorization of CaO-SiO2-MgO-Al2O3-FeO-P2O5-TiO2 slag system based on IMCT theory
Liu Ran, Liu Yanting, Gao Yanjia, Lan Chenchen, Yan Guangshi, Lü Qing
2024, 45(4): 113-122. doi: 10.7513/j.issn.1004-7638.2024.04.016
Abstract(94) HTML (23) PDF(7)
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Based on the theory of ionic-molecular coexistence (IMCT), a seven-component slag phosphorus distribution ratio (LP) model for CaO-SiO2-MgO-Al2O3-FeO-P2O5-TiO2 was established. This model has been validated in multiple slag systems and has the ability to accurately predict the enrichment behavior of...
Effect of precipitates on the creep rupture behavior of GH4141 superalloy
Zhang Zhao, Feng Xu, Guo Xulong, Zhang Weiwei, Wang Kaimeng, Xin Ruishan, Pei Binghong, Xiao Dongping, Zhou Yang
2024, 45(4): 123-128. doi: 10.7513/j.issn.1004-7638.2024.04.017
Abstract(88) HTML (24) PDF(8)
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This study focused on the effect of precipitates on the creep rupture behavior of GH4141 superalloy, involving creep crack initiation and propagation. Microstructures including carbides, γ′ precipitate hardening phase, void and intergranular crack were characterized by SE and EBSD. Meanwhile, plasti...
Effect of alloying elements V and Cu on microstructure and properties of Cu-bearing steels
Yang He, Hou Ziyong, Zhao Jun, Wang Yaru, Liang Jie, Chang Zhiyuan, Zhang Ling, Huang Xiaoxu
2024, 45(4): 129-136. doi: 10.7513/j.issn.1004-7638.2024.04.018
Abstract(123) HTML (37) PDF(19)
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Three kinds of Cu-bearing high strength steels, namely 0V1Cu steel, 0.15V1Cu steel and 0.15V4Cu steel, respectively, were designed to study the effect of V and Cu elements on microstructure and properties. The phase transformation, microstructure and microhardness of experimental steels were investi...
Effects of solution treatment on the microstructures and properties of high nitrogen nickel-free stainless steel prepared by MIM
Zou Liming, Liu Ruiyang, Cai Ying, Ni Donghui
2024, 45(4): 137-142. doi: 10.7513/j.issn.1004-7638.2024.04.019
Abstract(76) HTML (26) PDF(7)
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In this study, subsequent solution heat treatment was carried out in order to improve the properties of high nitrogen nickel-free austenitic (HNNFA) stainless steel prepared by MIM. The effects of solution temperature and duration on the microstructures and mechanical properties of HNNFA stainless s...
Effects of transformation temperature and austenitization temperature on the transformation kinetics and microstructure of a Nb microalloyed high-carbon steel
Zhou Mingxing, Chi Yicheng, Liu Jingtao, Li Zhengqian, Liu Sihua, Zhang Daichen, Su Xue, Tian Junyu
2024, 45(4): 143-149. doi: 10.7513/j.issn.1004-7638.2024.04.020
Abstract(97) HTML (43) PDF(7)
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In order to optimize the heat treatment process of a Nb microalloyed high-carbon steel, the effects of reheating temperature and transformation temperature on pearlite transformation kinetics and microstructure and properties were studied by dilatometry, optical microscope, scanning electron microsc...
Effect of trace Mg addition on microstructure and mechanical properties in 2.25Cr1Mo steel
Cheng Yang, Li Xiaobing, Gao Ming, Liu Kui
2024, 45(4): 150-157. doi: 10.7513/j.issn.1004-7638.2024.04.021
Abstract(103) HTML (33) PDF(12)
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In order to reveal the function of Mg micro-alloying in low micro-alloyed steel, the 2.25Cr1Mo with 15 mm thick steel plates containing different Mg content were prepared with vacuum induction furnace and rolled with double-stick reversible rolling mill. The characteristics of heat-treated microstru...
Molecular dynamics simulation study on the tensile behavior of FeC alloy
Li Jiajun, Sun Miao, Wu Huijuan, Lü Shining, Gao Youshan, Wang Aihong
2024, 45(4): 158-162. doi: 10.7513/j.issn.1004-7638.2024.04.022
Abstract(119) HTML (30) PDF(14)
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In order to investigate the effects of temperature and strain rate on the micro-mechanical properties of FeC alloys, molecular dynamics methods were used to simulate the tensile properties of FeC alloys. The stress-strain curves of FeC alloys at different temperatures and strain rates were obtained ...
Effect of pre-strain on impact fracture behavior of X80 pipeline steel
Wang Zhaoyang, You Jingze, Meng Tong, Zhang Lianwang, Sun Chao, Wang Hui, Yu Zhenyang, Song Ming
2024, 45(4): 163-169. doi: 10.7513/j.issn.1004-7638.2024.04.023
Abstract(81) HTML (20) PDF(10)
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The influence of pre-strain on the impact fracture behavior of X80 pipeline steel was studied. Fracture morphology and inclusions were analyzed by OM, SEM, EDS spectroscopy, and the crystallographic characteristics near the secondary crack on the fracture cross-section were obtained by EBSD. The res...
Study on the influence of Si addition on the mechanical properties of high Mn-N type TWIP stainless steels
Zeng Zeyao, Luo Xu
2024, 45(4): 170-175. doi: 10.7513/j.issn.1004-7638.2024.04.024
Abstract(91) HTML (38) PDF(6)
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The effects of different heat treatment processes on the microstructure and mechanical properties of high Mn-N TWIP stainless steels with 1.5% Si addition were studied by SEM and TEM. The results showed that the annealing twin thickness of the tested steel increased with the increase in solution tem...
Effect of continuous annealing fast cooling outlet temprature on the microstructures and properties of SPCC cold rolled sheet
Zhou Bowen, Jiang Cailing, Fan Lei, Liu Yihu, Lu Maosen, Yang Yuebiao
2024, 45(4): 176-180. doi: 10.7513/j.issn.1004-7638.2024.04.025
Abstract(68) HTML (23) PDF(5)
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Effect of continuous annealing fast cooling outlet temprature on the microstructures and properties of SPCC cold rolled sheet was studied. The results show that there are equiaxed ferrite grains, massive carbides on grain boundaries and granular carbides in grains in the continuous annealed SPCC col...
Study on mechanical properties of resistance spot welded joints with single pulse unequal thickness of 22MnB5/DP590
Yu Yongmei, Li Zhiguo, Lou Guodong, Jing Yi
2024, 45(4): 181-188. doi: 10.7513/j.issn.1004-7638.2024.04.026
Abstract(94) HTML (43) PDF(7)
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In this paper, the single pulse resistance spot welding technology was used to study the section characteristics and tensile properties of 22MnB5/DP590 spot welding joints with varying thickness section under different welding current and welding time, and the variation of microhardness of spot weld...
Analysis of microstructures, inclusions and carbides of G95Cr18 bearing steel billets by mold casting
Fu Yuhao, Wu Qiang, Zhu Haoran, Ji Dengping, Liu Bin, Fu Jianxun
2024, 45(4): 189-197. doi: 10.7513/j.issn.1004-7638.2024.04.027
Abstract(106) HTML (33) PDF(10)
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Based on Thermo-calc software, the matrix structure, phase transformation and carbides precipitation of G95Cr18 bearing steel were analyzed. Metallographic microscope and scanning electron microscope were used to analyze the mold casting billets structures, inclusions and carbides. The research show...
Study on the hot deformation behaviors of B50A789G blade steel
Yu Zhanyang, Xin Ruishan, He Yudong, Yao Bin, Wu Zhiwei, Zhao Jiqing, Li Xiaokai, Cao Chenxing
2024, 45(4): 198-204. doi: 10.7513/j.issn.1004-7638.2024.04.028
Abstract(78) HTML (25) PDF(8)
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The isothermal hot compression test of B50A789G blade steel was conducted by Gleeble-3800 thermo-mechanical simulator in the strain rate range of 0.01-10 s−1 and the deformation temperature range of 950-1200 ℃. Based on Arrhenius hyperbolic sine equation, the constitutive equation was established.Th...