2024 Vol. 45, No. 5

Separating and Extracting of Vanadium and Titanium
Preparation of VN via core-shell precursor method under the intervention of dispersants
Bo Wenbin, Zhang Yimin, Xue Nannan, Liu Hong
2024, 45(5): 1-8. doi: 10.7513/j.issn.1004-7638.2024.05.001
Abstract(418) HTML (58) PDF(39)
Abstract:
In this study, polyvinyl pyrrolidone (PVP) is used to optimize the core-shell V@C precursor structure, and the precursor is heat-treated to obtain vanadium nitride (VN) up to the National Standard VN16 grade of China. The addition of PVP promotes both the uniform dispersion of the carbon powders in ...
Research on the vanadium extraction from deactivated sulfuric acid catalyst featured with two-step and selectively
Jia Meili, Du Hao, Zhang Yi, Wang Shaona, Li Lanjie, Qi Jian, Zhou Bingjing, Zhao Beibei
2024, 45(5): 9-16. doi: 10.7513/j.issn.1004-7638.2024.05.002
Abstract(275) HTML (32) PDF(16)
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Based on the limited selectivity exhibited by current direct acid leaching and alkaline leaching processes for deactivated sulfuric acid catalysts, resulting in costly subsequent separation and challenging medium reuse, a new two-step process for selective extraction of vanadium was adopted. Using t...
Preparation of VN by reduction nitriding V2O3 with CH4
Xia Sanyuan, Jiang Tao, Chen Bojian, Wen Jing, Yang Guangdong, Liu Mengxia
2024, 45(5): 17-25. doi: 10.7513/j.issn.1004-7638.2024.05.003
Abstract(135) HTML (34) PDF(9)
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In this paper, the process conditions and reaction process of using CH4 instead of traditional carbon thermal reduction to prepare VN is explored by combining thermodynamic calculation and experimental process exploration. The results showed that the VN products with nitrogen and carbon contents of ...
Numerical simulation of fluidized chlorination velocity of high titanium slag
Cao Li, Zhu Kuisong, Xie Cong, Wang Jun, Zhao Yingtao, Sun Changqing, Cheng Xiangli
2024, 45(5): 26-34. doi: 10.7513/j.issn.1004-7638.2024.05.004
Abstract(144) HTML (29) PDF(13)
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Based on the physical parameters of high titanium slag and chlorine gas, the initial fluidization velocity of fluidized chlorination of high titanium slag was calculated by using the classical initial fluidization velocity formula. And the mathematical model of gas-solid two-phase flow of fluidized ...
Study on powder metallurgical properties of molten salt electrolytic titanium powder
Deng Bin, Mu Tianzhu, Zhou Xiangxing, Yuan Tiechui
2024, 45(5): 35-42. doi: 10.7513/j.issn.1004-7638.2024.05.005
Abstract(128) HTML (21) PDF(10)
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Electrolytic titanium powder was utilized as the raw material for fabricating porous titanium through press-sintering technique. The forming and sintering characteristics were investigated. Then the mechanical properties, pore structure, pore size distribution and permeability of the prepared porous...
Characterization of surface properties of titanium dioxide by inverse gas chromatography
Wang Xiaohui, Guo Jie, Xu Jinxiu, Tan Ling, Xie Lihua, Hu Yijie
2024, 45(5): 43-48. doi: 10.7513/j.issn.1004-7638.2024.05.006
Abstract(140) HTML (43) PDF(8)
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The surface energy and acid/base constants of three kinds of titanium dioxide (TiO2) were measured by inverse gas chromatography (IGC) to investigate the effect of organic treatment on the surface properties of TiO2. The non-polar surface energy of the samples were calculated by using different mole...
Application of Vanadium and Titanium
Review of MXenes as electrocatalysts for hydrogen production
Liu Enhao, Chen Chao, Dang Jie
2024, 45(5): 49-62. doi: 10.7513/j.issn.1004-7638.2024.05.007
Abstract(453) HTML (38) PDF(29)
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Renewable energy-based water electrolysis is the main method of producing “green hydrogen”, but it still faces difficulties in large-scale application due to high power consumption and the resulting high cost of electricity. The way to reduce power consumption lies in the development of high-perform...
Research on TIG welding organizational and performance of TC4 forge alloy
Zhang Hang, Zu Guoqing, Wang Dachen, Wang Yafeng, Li Hanbo, Liu Jie
2024, 45(5): 63-69. doi: 10.7513/j.issn.1004-7638.2024.05.008
Abstract(139) HTML (26) PDF(12)
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TC4 forged titanium plates with a thickness of 14 mm were multi-layer and multi-pass butt welded by non-melting tungsten inert gas welding (TIG), and the metallographic structure, crystal orientation and mechanical properties of the joints were investigated. The results show that the weld seams of T...
Study on microstructure and properties of laser welded thin-walled straight seam titanium pipes
Yin Xin, Li Junzhao, Li Haiming, Fan Cheng, Liu Wenzheng, Peng Shengjun, Sun Qingjie, Zeng Xianshan
2024, 45(5): 70-73. doi: 10.7513/j.issn.1004-7638.2024.05.009
Abstract(134) HTML (24) PDF(8)
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The thin-walled Gr.1 pure titanium straight seam welded pipe was welded by laser, and the samples obtained from the experiment were analyzed for macroscopic morphology, microstructure and mechanical properties. The results show that the weld width of longitudinally welded thin-walled pipe is relativ...
Study on interfacial thermal stability of SiCf/TC25G composites
Sun Wu, Zhang Yuming, Yang Lina, Yang Qing, Liu Di, Wang Yumin
2024, 45(5): 74-82. doi: 10.7513/j.issn.1004-7638.2024.05.010
Abstract(149) HTML (44) PDF(11)
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The prolonged exposure of TMCs to high temperatures results in severe interfacial reactions between the matrix and the fiber, leading to a degradation in the mechanical properties of the composites. In this study, SiCf/TC25G composites were prepared using a magnetron sputtering precursor wire method...
Influence of pre strain on the mechanical properties of TA2 and the establishment of constitutive model
Li Yifan, Dai Qiao, Guo Cheng, Feng Libin
2024, 45(5): 83-90. doi: 10.7513/j.issn.1004-7638.2024.05.011
Abstract(127) HTML (50) PDF(9)
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To investigate the effect of prestrain on the mechanical properties of TA2, room temperature tensile tests were conducted on the TA2 original material and specimens with the prestrains of 10%, 20%, and 30%. Based on the influence of prestrain on the mechanical properties of TA2, prestrain variables ...
Microstructures, properties and high-temp oxidation behaviors of Ti-45Al-8Nb-xHf alloys
Wang Wei
2024, 45(5): 91-97, 115. doi: 10.7513/j.issn.1004-7638.2024.05.012
Abstract(181) HTML (34) PDF(10)
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Ti-45Al-8Nb-xHf (x=0.5, 1.0, 1.5, 2) alloys were prepared by argon-protected vacuum induction melting process, and the microstructure, compressive properties and antioxidant properties of the alloys were investigated by using optical microscope (OM), scanning electron microscope (SEM), energy spectr...
Resources Environment and Energy Saving
Research progress on resource utilization of spent SCR denitrification catalyst
Song Shizhe, Qian Feng, Liu Zhongcheng, Ma Guangyu, Hou Hongyu, Xu Pengfei
2024, 45(5): 98-107. doi: 10.7513/j.issn.1004-7638.2024.05.013
Abstract(359) HTML (66) PDF(33)
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Recently, due to the increasing application of selective catalytic reduction (SCR) technology, a large number of spent SCR denitrification catalysts were inevitably produced. In order to save the resources and protect the environment, much attention should be attracted on their proper disposal. Spen...
Carbon thermal reduction is used to enrich alumina from fly ash and prepare ferrosilicon alloy
Xia Wenjie, Jin Yongli, Zhang Wuzhen, Zhang Kaiyue
2024, 45(5): 108-115. doi: 10.7513/j.issn.1004-7638.2024.05.014
Abstract(131) HTML (26) PDF(7)
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The comprehensive utilization of fly ash is a solid waste industry with high technical content and application potential, which integrates environmental protection and resource recycling. Ferrosilicon alloy was prepared by carbothermal reduction of fly ash under laboratory conditions and alumina was...
Study on process mineralogy of a low grade refractory vanadium-titanium magnetite ore in Xinjiang
Wang Yue, Yang Yaohui, Hui Bo, Lin Haitao
2024, 45(5): 116-122. doi: 10.7513/j.issn.1004-7638.2024.05.015
Abstract(175) HTML (36) PDF(15)
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In order to find out the ore properties of a low-grade refractory vanadium-titanium magnetite ore and the factors affecting the beneficiation index, carried out detailed process mineralogy research. The research shows that the ore is a low-grade vanadium-titanium magnetite ore of gabbro type. The gr...
Effect of steel slag ratio on the sintering of vanadium-titanium magnetite ore
Zhang Jianliang, Wang Qi, Liu Chenxin, Cao Chaozhen, Li Zhen, Zhu Jianqiu, Hao Liangyuan
2024, 45(5): 123-129. doi: 10.7513/j.issn.1004-7638.2024.05.016
Abstract(300) HTML (41) PDF(14)
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To optimize the recycling strategy of steel slag and enhance the economic and social benefits of steel companies, the study first analyzed the content of titanium and phosphorus elements in steel slag and conducted sintering pot tests based on different steel slag ratios. In the vanadium-titanium ma...
Ferrous Metallurgy and Materials
Research on theoretical combustion temperature control of V-Ti magnetite blast furnace smelting
Zheng Kui, Wang Wei, Gan Xian, Xie Hong’en, Fu Weiguo, Dong Xiaosen
2024, 45(5): 130-138. doi: 10.7513/j.issn.1004-7638.2024.05.017
Abstract(295) HTML (38) PDF(15)
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The theoretical combustion temperature in front of the tuyere is one of the important parameters for evaluating the thermal state of the blast furnace hearth. On the basis of the traditional theoretical combustion temperature calculation model, the influence of ash content, unburned coal powder, and...
Numerical simulation of solidification process for Q345R thick slab continuous casting
Zheng Xinyu, Sun Yanhui, Feng Qi, Gao Qing, Yang Wenzhi, Yang Jian
2024, 45(5): 139-146. doi: 10.7513/j.issn.1004-7638.2024.05.018
Abstract(162) HTML (32) PDF(12)
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In order to improve the quality of Xianggang Q345R thick slab casting billet, a solidification heat transfer model was established and was verified and corrected by nail shooting experiment. Through numerical simulation, the existing production process was evaluated, and the influence of casting spe...
Phase coexistence relationship of CaO-Al2O3-V2O5 slag system
Hao Guandi, Qiu Jiyu, Gong Henghui, Liu Yuan, Jiang Maofa
2024, 45(5): 147-150. doi: 10.7513/j.issn.1004-7638.2024.05.019
Abstract(134) HTML (24) PDF(14)
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CaO-Al2O3-V2O5 slag system is a basic metallurgical slag system for denitrification of liquid steel. The lack of thermodynamic information, such as the phase equilibrium relationship, limits the research and development of related slag systems. In this paper, the phase equilibrium relationship of Ca...
Effects of solidification structure on MnS in heavy rail steel bloom
Li Hongguang, Xu Mingli, He Wei, Wang Zhangyin
2024, 45(5): 151-157. doi: 10.7513/j.issn.1004-7638.2024.05.020
Abstract(135) HTML (41) PDF(7)
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The sizes and microstructures of MnS at different positions of the heavy rail steel bloom were measured by electro-chemical etching and Aspex scanning, and the effect of solidification structure on MnS was studied. The results show that when the solidification structure transforms from mixed-crystal...
Analysis of inclusions and carbides in mold casting billets of Cr12MoV steel
Lun Mingrui, Shen Ping, Liu Bin, Fu Jianxun
2024, 45(5): 158-166. doi: 10.7513/j.issn.1004-7638.2024.05.021
Abstract(159) HTML (29) PDF(14)
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The transformation of different phases, the precipitation of inclusions and carbides in the Cr12MoV cold work die steel were calculated using Factsage thermodynamic software. The inclusions and carbides of the mold casting billets were analyzed using OM and SEM. It is shown that Cr12MoV steel is dom...
Effect of vanadium on the microstructure and mechanical properties of 7Mn steel during cold rolling process
Yu Haicun, Lü Wei, Li Ning, Wei Haidong, Wang Xuming, Yu Tao, Ding Wanwu
2024, 45(5): 167-172. doi: 10.7513/j.issn.1004-7638.2024.05.022
Abstract(120) HTML (25) PDF(6)
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On the basis of 7Mn medium manganese steel, different contents of V element were added. Through cold rolling and annealing treatment, the influence of 0.1%~0.3% V addition on the microstructure and mechanical properties of the steel was preliminarily explored. The experimental results show that when...
Influence of final cooling temperature on the microstructure and mechanical properties of Ti microalloyed automobile beam steel
Han Chufei, Dong Yi, Shi Xiaoguang, Sun Chengqian, Wang Junxiong, Xu Haijian
2024, 45(5): 173-176, 204. doi: 10.7513/j.issn.1004-7638.2024.05.023
Abstract(139) HTML (38) PDF(9)
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In order to reveal the influence of final cooling temperature on microstructure and mechanical properties of Ti-microalloyed automobile 510L beam steel, the hot rolling and laminar cooling (LC) experiment was conducted on 0.11C-1.20Mn-0.055Ti beam steel. The experimental results showed that with the...
Study on combustion solution prepared Co0.25Ni0.25Cu0.25Mn0.25Fe2O4 and their photocatalytic performance
Xiong Xiaoying, Cao Zhiqin, Zuo Chengyang
2024, 45(5): 177-182. doi: 10.7513/j.issn.1004-7638.2024.05.024
Abstract(125) HTML (30) PDF(6)
Abstract:
Using cobalt nitrate (Co(NO3)2·6H2O), iron nitrate (Fe(NO3)3·9H2O), nickel nitrate (Ni(NO3)2·6H2O), manganese nitrate (Mn(NO3)2·4H2O), copper nitrate (Cu(NO3)2·3H2O) as raw materials and glycine as fuel, Co0.25Ni0.25Cu0.25Mn0.25Fe2O4 was prepared by solution combustion synthesis. The preparation and...
Low cycle fatigue characteristics and life prediction methods for different regions of 316L welded joints
Guo Yanjun, Zhang Wei, Yang Qiaofa, Zhou Changyu
2024, 45(5): 183-192. doi: 10.7513/j.issn.1004-7638.2024.05.025
Abstract(147) HTML (26) PDF(14)
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In this paper, the high-temperature low-cycle fatigue characteristics of three types of materials: 316L base metal, welded material, and welded joints were systematically studied. By introducing a fatigue life reduction coefficient into the traditional life prediction model, the low-cycle fatigue li...
Study on the phase transformation law of titanium microalloyed non-oriented silicon steel
Liang Xiaosong, Wang Peng, Chen Songjun, Li Liejun, Huo Xiangdong
2024, 45(5): 193-198. doi: 10.7513/j.issn.1004-7638.2024.05.026
Abstract(150) HTML (63) PDF(8)
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The CCT curves of 50W600 and 50W600-Ti were measured by thermal simulator. The phase transformation of the two test steels under continuous cooling had been studied and precipitation behavior in titanium-containing steels was also observed. The results show that the phase transformation temperature ...
Interpretation on GB/T 2965-2023: Titanium and titanium alloy bars
Xie Chen, Ma Zhongxian, Feng Junning, Li Wei, Wei Jiaqi, Feng Yongqi, Hu Zhijie, Ma Jiakun, Qing Daga, Wang Ruofei
2024, 45(5): 199-204. doi: 10.7513/j.issn.1004-7638.2024.05.027
Abstract(507) HTML (256) PDF(32)
Abstract:
In this paper the revision reasons and process evolution of new standard GB/T 2965-2023 had been briefed. And interpretation had been made on the following points such as terms and definition, product category, dimension and tolerance, heat treatment, mechanical properties, sampling and test result ...