Study on the corrosion resistance of vanadium-based V3TiNi0.56Crx (x=0, 0.2, 0.4, 0.6)/NiMoW composite cathode for hydrogen evolution

Du Jinjing; Zhang Xuan; Zhou Yu; Cui Xinxin; Zhu Jun; Zuo Heng; Wang Bin; Bao Yanru; Liu Jingtian; Guo Yuehao

doi:10.7513/j.issn.1004-7638.2024.04.008

Volume 45 Issue 4

Aug. 2024

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Article Navigation > IRON STEEL VANADIUM TITANIUM > 2024 > 45(4): 48-53

Du Jinjing, Zhang Xuan, Zhou Yu, Cui Xinxin, Zhu Jun, Zuo Heng, Wang Bin, Bao Yanru, Liu Jingtian, Guo Yuehao. Study on the corrosion resistance of vanadium-based V3TiNi0.56Crx (x=0, 0.2, 0.4, 0.6)/NiMoW composite cathode for hydrogen evolution[J]. IRON STEEL VANADIUM TITANIUM, 2024, 45(4): 48-53. doi: 10.7513/j.issn.1004-7638.2024.04.008

Citation:

Du Jinjing, Zhang Xuan, Zhou Yu, Cui Xinxin, Zhu Jun, Zuo Heng, Wang Bin, Bao Yanru, Liu Jingtian, Guo Yuehao. Study on the corrosion resistance of vanadium-based V₃TiNi_0.56Cr_x (x=0, 0.2, 0.4, 0.6)/NiMoW composite cathode for hydrogen evolution[J]. IRON STEEL VANADIUM TITANIUM, 2024, 45(4): 48-53. doi: 10.7513/j.issn.1004-7638.2024.04.008

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Study on the corrosion resistance of vanadium-based V₃TiNi_0.56Cr_x (x=0, 0.2, 0.4, 0.6)/NiMoW composite cathode for hydrogen evolution

doi: 10.7513/j.issn.1004-7638.2024.04.008

1.
School of Metallurgical Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, Shaanxi, China
2.
Shaanxi Wuzhou Mining Co., Ltd., Shangluo 726000, Shaanxi, China

Received Date: 2023-12-20
Publish Date: 2024-08-30

Abstract

Abstract

This article mainly studied the influence of Cr element on the electrocatalytic performance and corrosion resistance of vanadium-based V₃TiNi_0.56Cr_x(x=0,0.2,0.4,0.6)/NiMoW composite cathode for hydrogen evolution. The phase, morphology, electrocatalytic performance, and corrosion resistance of V₃TiNi_0.56Cr_x(x=0,0.2,0.4,0.6)/NiMoW alloy during the electrocatalytic process is analyzed. A passivation film is formed on the surface of the matrix alloy, which can create a passivation zone in the electrochemical corrosion process of the matrix material. It is considered to contain Ni and Cr interstitial substituents. The electrocatalytic ability of vanadium-based composite cathode for hydrogen evolution slightly decreases. The self-corrosion current decreases by 3.61 mA/cm and the self-corrosion potential shifts forward by 0.154 V, which is calculated by the polarization curve extrapolation method. After long-term electrolysis, the amount of gaps formed on its surface decrease, and only slight changes existed in the amplitude of current density change, indicating that its corrosion resistance and long-term stability have been improved.
- vanadium based composite hydrogen evolution cathode,
- mechanical alloying,
- electrodeposition,
- electrocatalysis,
- corrosion resistance,
- long-term stability

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