2024 Vol. 45, No. 2

Separating and Extracting of Vanadium and Titanium
Research on preparation of metal vanadium by carbothermal reduction
Li Lanjie, Chang Fuzeng, Liu Jing, Zhang Na, Zhang Suxin, Wang Haixu
2024, 45(2): 1-6. doi: 10.7513/j.issn.1004-7638.2024.02.001
Abstract(425) HTML (83) PDF(71)
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High-purity V2O5 powder was used as raw material and carbon powder was used as reducing agent. The process of preparing metals by carbothermal reduction was studied, and the effects of the amount of carbon, temperature, vacuum degree and reduction time on the products were discussed. The results sho...
Research on preparation and sodium storage properties of ultrafine nano-sodium ferric vanadium phosphate
Teng Aijun, Yuan Xinran, Zhang Dongbin, Xin Yanan, Liu Tianhao, Han Huiguo, Du Guangchao
2024, 45(2): 7-12. doi: 10.7513/j.issn.1004-7638.2024.02.002
Abstract(286) HTML (76) PDF(29)
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Due to the high price, large particle size and poor conductivity of vanadium based polyanion compounds, a new type of sodium ferric vanadium phosphate material was prepared by doping iron element to partially replace vanadium element. The phase information and sodium storage properties of sodium fer...
Study on the production of Fe-V alloy by the reduction of vanadium-enriched slag using aluminum dross
Yang Zhifei, Chen Min, Zhang Lingxi
2024, 45(2): 13-19. doi: 10.7513/j.issn.1004-7638.2024.02.003
Abstract(298) HTML (45) PDF(17)
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In order to solve the problems of low valuable metal yield and high production cost in the process of ferrovanadium production, this paper proposed the use of aluminum ash as a reductant to directly reduce the vanadium-rich slag for the preparation of ferrovanadium alloys. The effect of different re...
Study on phase and physical properties of molten salt system for chlorination of titanium slag
Xu Jianlin, He Yilin, Ma Zhanshan, Pang Zhongya, Tian Feng, Zhang Xueqiang, Zou Xingli, Zhu Fuxing
2024, 45(2): 20-27. doi: 10.7513/j.issn.1004-7638.2024.02.004
Abstract(275) HTML (32) PDF(26)
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The molten salt chlorination method is a technique developed specifically for the preparation of titanium tetrachloride using high-calcium magnesium titanium slag materials. During long-term production practices, it has been observed that improper control of the composition in the chlorination furna...
Simulation of arc characteristics in a titanium slag EAF with hollow electrode
Liu Quan, Guan Xiaoping, Xiao Jun, Yang Ning
2024, 45(2): 28-34. doi: 10.7513/j.issn.1004-7638.2024.02.005
Abstract(258) HTML (43) PDF(25)
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The arc characteristics inside the titanium slag electric arc furnace (EAF) play a crucial role in the melting and reduction of furnace materials. In this study, a method combining fluid mechanics and electromagnetic field was employed to establish a mathematical model for the arc region inside the ...
Structure-property relationship between surface structure and water dispersity of titanium dioxide
Quan Yuanxia, Xiang Quanjin, Quan Xuejun, Ke Lianghui, Li Li
2024, 45(2): 35-41. doi: 10.7513/j.issn.1004-7638.2024.02.006
Abstract(218) HTML (46) PDF(18)
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The wettability and dispersion of titanium dioxide in water is very important for the inorganic coating and application performance. In this study, the relationship between the surface structure and the water wettability and dispersion of titanium dioxide treated with zinc and aluminum salts was stu...
Application of Vanadium and Titanium
Research status and prospect of titanium alloys resistant to high temperature of 600 ℃ and above
Wang Bing, Xiang Zhilei, Zhou Zongyi, Shen Gaoliang, Huang Jingcun, Han Jingyu, Wang Andong, Chen Ziyong
2024, 45(2): 42-50, 71. doi: 10.7513/j.issn.1004-7638.2024.02.007
Abstract(1294) HTML (100) PDF(218)
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This paper reviews the development status of high-temperature titanium alloys resistant to 600 ℃ and above in domestic and foreign situations, and summarizes the composition and properties of IMI834 from UK, Ti-1100 from USA, BT36 from Russia and Ti60, TG6, Ti600, Ti65 and Ti750 from China. The main...
Preparation of BiVO4/GO composites and their photocatalytic performance
Wang Li, Shi Zhaozhong, Cui Weina, Zhou Hua, Zhan Guirong, Liu Jin
2024, 45(2): 51-57. doi: 10.7513/j.issn.1004-7638.2024.02.008
Abstract(178) HTML (77) PDF(11)
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Bismuth vanadate (BiVO4) has attracted considerable attention in photocatalysis due to its cheap and easy availability, mild and simple preparation conditions, narrow bandgap (~2.4 eV), outstanding photoresponse ability, and excellent stability. A fishbone like bismuth vanadate/graphene (BiVO4/GO) c...
Effect of heat treatment process on the structure and properties of deformed TiAl sheets
Guo Jie, Teng Aijun, Huang Zhaokuo, Zhong Yong, Yang Liu
2024, 45(2): 58-62. doi: 10.7513/j.issn.1004-7638.2024.02.009
Abstract(177) HTML (65) PDF(15)
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TiAl based intermetallic compounds have attracted widespread attention of domestic to international researches due to their lightweight, high specific strength, and excellent high-temperature performance, and have been applied in key fields such as aerospace and aviation, etc. However, due to their ...
Rheological behaviours and constitutive models for titanium alloy TA31 at room temperature and high strain rate
Jia Haishen, Guo Wenjing, Zhao Lidong, Zhang Jilin, Ma Tianjiao, Zhang Wei
2024, 45(2): 63-71. doi: 10.7513/j.issn.1004-7638.2024.02.010
Abstract(249) HTML (79) PDF(10)
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At room temperature, quasi-static compression and dynamic impact tests were conducted on titanium alloy TA31 by using UTM5305 universal testing machine and ALT1000 split Hopkinson pressure bar device. Based on the stress-strain curves attained from experiments, the strain hardening effect, strain ra...
Synthesis and properties of the BiVO4 based composite photocatalysts
Liu Jingjing
2024, 45(2): 72-78, 124. doi: 10.7513/j.issn.1004-7638.2024.02.011
Abstract(175) HTML (80) PDF(10)
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Binary BiOCl/BiVO4 and ternary BiOCl/BiVO4/diatomite photocatalysts were in situ prepared by liquid phase precipitation using bismuth nitrate, ammonium metadadate, potassium chloride and diatomite as raw materials, and the phase structure and photocatalytic properties of the composites were characte...
Study on evolution and mechanism of adiabatic shear bands of cold rolled titanium
Qiu Xingyu, Li Yechao, Fang Hongmei, Cao Lili, Zhang Ya, Yang Dengke
2024, 45(2): 79-84. doi: 10.7513/j.issn.1004-7638.2024.02.012
Abstract(221) HTML (65) PDF(24)
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In order to study the evolution law and mechanism of titanium adiabatic localization shear band under cold rolling conditions, conclusions were drawn by exploring and analyzing the cold rolling process. Firstly, the morphology of the shear band was analyzed, followed by the microhardness, and finall...
Resources Environment and Energy Saving
Analysis and selection of technical paths for recycling and utilization of waste vanadium catalysts
Zhao Beibei, Li Lanjie, Qi Jian, Ma Ruifeng, Wang Hailong, Zhao Liang
2024, 45(2): 85-93. doi: 10.7513/j.issn.1004-7638.2024.02.013
Abstract(494) HTML (80) PDF(47)
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In order to promote the green development of manufacturing industry, the comprehensive recycling and utilization of waste vanadium catalysts has broad prospects, and is an urgent need to realize the circular economy of vanadium industry. Exploring a new process with low pollution, low energy consump...
Effect of sodium chlorite on surface modification and flotation behavior of ilmenite
Zhang Yun, Ye Guohua, Hu Yujie, Xiang Xinyue, Rong Yiyang, Song Changxu
2024, 45(2): 94-101. doi: 10.7513/j.issn.1004-7638.2024.02.014
Abstract(180) HTML (36) PDF(11)
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The surface modification of ilmenite with sodium chlorite was carried out to enhance the adsorption effect of collector. The mechanism of sodium chlorite modification was investigated by microflotation test and zeta potential. The results of microflotation test showed that the recovery of ilmenite i...
Study on the occurrence state of iron and chromium in Hongge vanadium-titanomagnetite ore
Wang Lizhen, Jiang Chuling, Zhu Jiaxiang, Yang Hualing, Yi Luan
2024, 45(2): 102-107. doi: 10.7513/j.issn.1004-7638.2024.02.015
Abstract(218) HTML (112) PDF(26)
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By means of chemical multi-element analysis, phase analysis, X-ray diffraction analysis, optical microscopy, MLA and other modern testing methods, this paper studied in detail the chemical composition, mineral species and content, microcomponent analysis of energy spectrum for chromium-containing mi...
Experimental study on granulated blast furnace slag asfine aggregate self-compacting concrete
Shi Dongsheng, Li Hanghang, Zhang Peng, Han Ping, He Peiyuan
2024, 45(2): 108-114. doi: 10.7513/j.issn.1004-7638.2024.02.016
Abstract(286) HTML (48) PDF(14)
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The mix ratio of granulated blast furnace slag self-compacting concrete was designed based on the full calculation method. By studying its working performance to determine the final mix ratio and test its compressive strength, and then use the GM (1,1) grey prediction model can predict its compressi...
Ferrous Metallurgy and Materials
Overview of non-quenched and tempered steel for automotive
Liu Nianfu, Shen Wei, Tian Qianren, Fu Jianxun
2024, 45(2): 115-124. doi: 10.7513/j.issn.1004-7638.2024.02.017
Abstract(345) HTML (98) PDF(29)
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In this paper the development history and status quo of non-quenched and tempered steel for making auto parts worldwidely had been described, and the technologies such as strengthening & toughening, sulfide form and distribution control, and material segregation control had been highlighted. The...
Analysis on bulging strain of continuous casting slab during solidification
He Yumin, Luo Yang, He Bo
2024, 45(2): 125-131, 161. doi: 10.7513/j.issn.1004-7638.2024.02.018
Abstract(221) HTML (103) PDF(19)
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In view of the bulging deformation of slab during continuous casting, in order to eliminate fluctuation of the mold liquid level by means of reducing bulging strain at the boundary of two phases of the casting stream, considering influence of contact arc length between roller and casting stream on t...
Microstructures and high temperature properties of high Nb ferritic stainless steels for exhaust system
Li Wei, Bai Qingqing
2024, 45(2): 132-138. doi: 10.7513/j.issn.1004-7638.2024.02.019
Abstract(207) HTML (39) PDF(10)
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During the research and development of new hot end materials for automobile exhaust system, annealing experiments, grain coarsening resistance experiments, aging resistance experiments, high temperature tensile and high temperature creeping experiments were carried out on the experimental steels in ...
Study on the precipitation kinetics of carbides in austenite and ferrite of microalloyed steels
Zheng Yaxu, Yang Qin, Zhao Ziyu, Wei Cuihu, Hui Shixu, Wu Kangye
2024, 45(2): 139-148. doi: 10.7513/j.issn.1004-7638.2024.02.020
Abstract(304) HTML (44) PDF(17)
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According to the solid solution thermodynamic calculation of the multi-composite precipitated phases and the classical nucleation growth kinetic theory, the deposition and precipitation of carbides in austenite (γ) and ferrite (α) phases in Ti-Mo, Ti-Nb-Mo and Ti-Nb-Mo-V composite microalloyed-steel...
Effect of Cr and Ni on the microstructure and properties of corrosion-resistant steel
Wang Baoshan, Zhang Hongliang, Wang Weiwei, Ma Jian, Feng Guanghong
2024, 45(2): 149-155. doi: 10.7513/j.issn.1004-7638.2024.02.021
Abstract(476) HTML (74) PDF(38)
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Based on the base chemistry of Q345GNH steel, the steel samples with different Cr (mass fraction of 0.5%, 2%, 3%, 4% and 5%) and Ni (mass fraction of 0.5% and 1%) contents were prepared and their performances were compared by series of tests. Meanwhile, the effect mechanism of Cr and Ni on propertie...
Effect of bismuth-tin alloy quenching medium on microstructure and properties of boron steel
Zhang Chi, Hou Huaxing, Wang Yitong, Dai Chunduo, Li Jiangwen, Liu Wenyue
2024, 45(2): 156-161. doi: 10.7513/j.issn.1004-7638.2024.02.022
Abstract(267) HTML (41) PDF(10)
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Bismuth tin alloy is thought suitable as a cooling media after comparing it with common low melting point metals. Thus, the maximum cooling rate and corresponding temperature cooling characteristics of bismuth tin alloy at different temperature states were characterized by using a cooling medium cha...
Study on characteristics of hot deformation in Super304H austenitic heat-resistant steel
Gu Meirong, Cao Yanfeng, Peng Lingling, Yu Hongxing, Ou Ping, Wang Hebin, Li Chengbo, Liu Xiaoming, Rong Sheng, Li Ling
2024, 45(2): 162-170. doi: 10.7513/j.issn.1004-7638.2024.02.023
Abstract(221) HTML (101) PDF(8)
Abstract:
Hot compression test of Super304H austenitic steel was carried out by using a MMS-100 thermal mechanical simulator at 900~1200 ℃ and 0.1~10 s−1. Based on the true stress-true strain test data, the Zener-Hollomon constitutive model of the studied steel was established by using a strain compensation m...
Effects of stress gradient and temperature on mechanical properties of GH4169 superalloy
Guo Xulong
2024, 45(2): 171-175, 204. doi: 10.7513/j.issn.1004-7638.2024.02.024
Abstract(410) HTML (50) PDF(31)
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GH4169 alloy was obtained by a specific metallurgical process and tensile experiments were carried out at different temperature gradients of 550 ℃, 650 ℃ and 750 ℃ and different stress levels of 590 MPa, 690 MPa and 790 MPa. The mechanical properties of the alloy were obtained, which in turn provide...
Effect of laser power on microstructure and mechanical properties of high entropy alloy /316L stainless steel materials
Sun Ying, Zhang Huiyun, Zheng Liuwei
2024, 45(2): 176-181. doi: 10.7513/j.issn.1004-7638.2024.02.025
Abstract(264) HTML (63) PDF(16)
Abstract:
Selective laser additive manufacturing (SLM) fabricated metal matrix composites have many advantages such as flexible structure and controllable composition. In this paper, 316L stainless steel was used as the matrix material and Al0.5CoCrFeNiTi0.5 high entropy alloy (HEA) powder was used as the par...
The addition of anadium and nitride alloy on the solidificationstructure and hardness of M2 high-speed steel
Shang Guangmin, Liu Hongyu, Deng Weijie, Li You, Sun Boxiang, Li Ruilin
2024, 45(2): 182-189. doi: 10.7513/j.issn.1004-7638.2024.02.026
Abstract(175) HTML (43) PDF(11)
Abstract:
In order to fully exploit the potential role of vanadium-Nitride alloy on high-speed steel, the evolution of solidification structure and hardness of M2 high-speed steel with vanadium-Nitride alloy addition had been investigated by using a rapid solidification melt-sampling apparatus, where the vana...
Effect of bismuth content on the microstructure and properties of free cutting steels
Li Binzhou, Wang Dong, Wang Yijia, Jiang Yuanbo, Shao Zhibao, Li Changsheng
2024, 45(2): 190-197. doi: 10.7513/j.issn.1004-7638.2024.02.027
Abstract(227) HTML (35) PDF(14)
Abstract:
The bismuth-containing free-cutting steel served as an environment-friendly material has a broad application prospect. Bismuth was alloyed by preparing bismuth ferromanganese alloy, which was then added to the molten steel in the process of vacuum induction melting. After casting the melt and hot ro...
Study on microstructure and mechanical properties of welded joints of 15Cr1Mo1V steel pipeline in service
Wang Yansong, Liu Fuguang, Mi Zihao, Han Tianpeng, Zhang Lei, Yang Erjuan, Ba Teer
2024, 45(2): 198-204. doi: 10.7513/j.issn.1004-7638.2024.02.028
Abstract(273) HTML (68) PDF(24)
Abstract:
The microstructure, hardness, tensile strength, impact and failure position of the welded joint of 15Cr1Mo1V steel for high temperature reheat steam pipeline, which has been operated for about 130000 hours in a power plant, were studied and analyzed. The results show that there are the polygonal fer...