2024 Vol. 45, No. 1

Separating and Extracting of Vanadium and Titanium
Status, future and development of China’s titaniumdioxide industry in 2023
Bi Sheng
2024, 45(1): 1-3. doi: 10.7513/j.issn.1004-7638.2024.01.001
Abstract(2642) HTML (198) PDF(132)
Abstract:
This paper summarized the operation data of China’s titanium dioxide industry in 2023, including production capacity, output, market apparent demand, capacity concentration and so on. The recent growth trend of titanium dioxide production capacity and the corresponding changes in the supply and dema...
A new process for preparing Ti-Al alloys from low-valance titanium chlorides slurry by direct electrochemical reduction
Zhu Fuxing, Ma Zhanshan, Deng Bin, Mu Tianzhu, Qiu Kehui
2024, 45(1): 4-11. doi: 10.7513/j.issn.1004-7638.2024.01.002
Abstract(303) HTML (47) PDF(20)
Abstract:
Owing to the lack of systematic research on electrochemical behaviors and unclear high-temperature oxidation resistance characteristics of Ti-Al alloys prepared from low-valence titanium chlorides slurry by the electrochemical reduction in molten salt, the electrochemical workstation and differentia...
Research on preparation of nano sodium vanadium phosphate and its sodium storage properties
Zhang Dongbin, Yuan Xinran, Xin Yanan, Bi Xinqiang, Liu Tianhao, Han Huiguo, Du Guangchao, Teng Aijun
2024, 45(1): 12-18. doi: 10.7513/j.issn.1004-7638.2024.01.003
Abstract(593) HTML (53) PDF(42)
Abstract:
Based on the severe preparation conditions, large particle size and poor conductivity, a new method to prepare sodium vanadium phosphate was proposed. By the formation of alkaline vanadium compounds, vanadium hydroxyloxide, and the in-situ anions exchange reactions between PO43–, F and OH, nano va...
Comparative study on arc characteristics of hollow and solid electrode electric furnace melting titanium slag
Li Mengzhen, Li Baokuan, Yu Yang, Xiao Jun
2024, 45(1): 19-27. doi: 10.7513/j.issn.1004-7638.2024.01.004
Abstract(193) HTML (76) PDF(14)
Abstract:
In order to further explore the advantages of hollow electrode technology in titanium slag electric furnace smelting process, based on the actual electrode size of 25.5 MW titanium slag electric furnace, the mathematical models of hollow and solid electrode arc were established, and the distribution...
Phase transformation and electrical resistivity of reduced ilmenite concentrate carbon-containing pellets
Wu Enhui, Xu Zhong, Li Jun, Hou Jing, Huang Ping, Zhang Shiju, Tang Rong, Luo Yuqin
2024, 45(1): 28-33. doi: 10.7513/j.issn.1004-7638.2024.01.005
Abstract(211) HTML (38) PDF(11)
Abstract:
Using the graphite powder as a reducing agent, the phase transformation and electrical resistivity of the reduced products during the reduction process of carbon-containing ilmenite concentrate pellets were studied. The XRD analysis results indicate that the reduction process of carbon-containing il...
Study on the effect of the particle size of hydrolysis seeds prepared by industrial titanyl sulfate solution
Lu Ruifang, Dong Lichun, Yang Fang, Sun Qiang, Wu Jianchun, Liu Chan
2024, 45(1): 34-39. doi: 10.7513/j.issn.1004-7638.2024.01.006
Abstract(264) HTML (47) PDF(24)
Abstract:
With industrial titanyl sulfate solution as raw material, the hydrolysis seeds were prepared by sodium hydroxide solution neutralization method, which is commonly used in titanium pigments production by sulfuric process. And under different raw material indexes and process parameters, the changes of...
Application of Vanadium and Titanium
Research progress of micro-arc oxidation technology of titanium alloys
Yang Hongpei, Wang Ping, Yang Shaolan, Wang Xiangjie
2024, 45(1): 40-48. doi: 10.7513/j.issn.1004-7638.2024.01.007
Abstract(555) HTML (565) PDF(79)
Abstract:
China has developed the largest titanium industry system at present in the world, focusing on deepening the application and service behavior of titanium and titanium alloys, and vigorously developing new surface treatment technologies to improve the life of materials. Among them, micro-arc oxidation...
Forming process, microstructure, strength and toughness of Ti6Al4V alloy by laser wire-feed additive manufacturing
Zhang Dayue, Wu Xinze, Wang Yijia, Si Shanshan, Jiang Yuanbo, Li Binzhou, Jiang Fengchun
2024, 45(1): 49-56. doi: 10.7513/j.issn.1004-7638.2024.01.008
Abstract(418) HTML (63) PDF(27)
Abstract:
In this paper, single-pass multi-layer Ti6Al4V alloy specimens were prepared by laser wire-feed additive manufacturing technology. The effects of laser power, scanning speed and wire feeding speed on the microstructure, tensile properties and impact properties of Ti6Al4V alloy were systematically st...
Studies on the influences of forging processes on the microstructures and properties of TA15 rods
Li Xiaoyu, Tang Min, Liu Xin, Xiao Qiang, Qin Haixu
2024, 45(1): 57-64. doi: 10.7513/j.issn.1004-7638.2024.01.009
Abstract(293) HTML (41) PDF(15)
Abstract:
TA15 rods with the diameter of 100 mm and 200 mm were produced by free forging and radial forging respectively. In this study, the effects on the microstructures and mechanical properties of TA15 rods were investigated. It is shown that there are dramatic differences in the microstructures at differ...
Simulation study on the effect of VAR magnetic stirring process on the melt flow
Huang Liqing, Fan Kai, Guo Jie, Li Chao, Li Junjie, Wang Jincheng
2024, 45(1): 65-70. doi: 10.7513/j.issn.1004-7638.2024.01.010
Abstract(523) HTML (112) PDF(38)
Abstract:
The flow behavior of melt in vacuum consumable arc melting affects the solidification characteristics of ingots. Direct observation of the melt motion is difficult, so revealing the flow behavior of the melt by simulation is crucial. In this paper, a self-developed three-dimensional simulation model...
Adiabatic shear sensitivity performance of Ti-1023 alloys at different heat treatment regimes
Guo Wenjing, Zhang Jilin, Jia Haishen, Yi Xiangbin, Luo Wencui
2024, 45(1): 71-77. doi: 10.7513/j.issn.1004-7638.2024.01.011
Abstract(190) HTML (36) PDF(9)
Abstract:
Using the Hopkinson pressure bar test system to conduct room temperature dynamic compression experiments for cylindrical samples, the formation characteristics of adiabatic shear bands and the microstructure of Ti-1023 titanium alloy under different heat treatment regimes were studied. The results s...
Study of explosive composition to mechanical properties and interfacial structure of large-sized titanium-steel clad plates
Yang Xueshan, Pang Lijuan, Deng Gang, Li Huirong, Zhang Xuefeng
2024, 45(1): 78-83. doi: 10.7513/j.issn.1004-7638.2024.01.012
Abstract(322) HTML (75) PDF(12)
Abstract:
In this paper TA2 plate of 3 mm × 3 m × 7 m and Q235 steel plate of 9 mm × 3.2 m × 7.2 m are used as the clad plate and the base plate, respectively, large-sized TA1-Q235 titanium-steel clad plates were prepared with four different components of explosives and the shear strength and interface bondin...
Resources Environment and Energy Saving
Study on the occurrence state of substances in sublimation sulfur from the tail gas of acid hydrolysis of titanium concentrate
Li Ping, Quan Xuejun, Li Li, Wang Haibo, Chen Xinhong, Qi Xueqiang, Li Gang, Xiang Quanjin
2024, 45(1): 84-90. doi: 10.7513/j.issn.1004-7638.2024.01.013
Abstract(252) HTML (66) PDF(20)
Abstract:
At present, the manufacturers of titanium dioxide produced by sulfuric acid process titanium dioxide face the problem that sublimed sulfur in the acid hydrolysis tail gas clogs the pipeline, which affects the continuity of the production of titanium dioxide by this process. In this paper, XRD, SEM a...
Study on calcification reduction sodium removal of vanadium extraction tailings by coal-based rotary kiln method
Wang Zhaocai, Zheng Fuqiang, Liu Chen, Hu Bing, Shi Benjing
2024, 45(1): 91-95. doi: 10.7513/j.issn.1004-7638.2024.01.014
Abstract(210) HTML (47) PDF(19)
Abstract:
In view of the high sodium content in vanadium extraction tailings, which leads to the difficulty of returning to the sintering-blast furnace process for recycling, herein we proposed a calcification reduction sodium removal technology route for vanadium extraction tailings based on coal-based rotar...
Effect of alkali leaching and sludge strengthening on phosphorus removal of steel slag ceramics
Tang Jing, Luo Shengyuan
2024, 45(1): 96-103. doi: 10.7513/j.issn.1004-7638.2024.01.015
Abstract(176) HTML (33) PDF(8)
Abstract:
In order to improve the phosphorus removal effect of steel slag, alkali leaching pretreatment was used and residual sludge was added to strengthen the preparation of alkali leaching slag–montmorillonite–sludge composite steel slag ceramic particles. The phosphorus removal performance and mechanism o...
Experimental and simulation on the granulation process of blast furnace slag
Shao Chen, Kang Yue, Xing Hongwei, Liu Chao, Lin Wenlong, Sun Ruijing, Zhou Jun
2024, 45(1): 104-114. doi: 10.7513/j.issn.1004-7638.2024.01.016
Abstract(338) HTML (73) PDF(22)
Abstract:
Emphasis was placed on the centrifugal granulation process and gas quenching granulation process during the dry granulation process. Due to the high-temperature transient process of granulation and crushing of blast furnace slag, it is difficult to monitor its specific change process solely through ...
Ferrous Metallurgy and Materials
Study on deterioration of physicochemical properties of tundish slag for high carbon steel during continuous casting process
Hu Hao, Wang Xianyang, Wu Chenhui, Shi Peng, Xie Xin, Zeng Jianhua, Long Mujun, Chen Dengfu
2024, 45(1): 115-121. doi: 10.7513/j.issn.1004-7638.2024.01.017
Abstract(274) HTML (69) PDF(22)
Abstract:
Well keeping physicochemical properties of tundish slag during continuous casting is of great significance to stabilize the cleanness of molten steel. In this study, the physicochemical properties of tundish slag for high carbon steel bloom in the process of continuous casting were tested and studie...
Precipitation behavior of composite precipitates in Nb-Ti micro-alloy EH36 offshore steel
Qiao Jialong, Guo Feihu, Shi Pengzhao, Cao Ruihong, Xiong Chenguang, Xu Lijun
2024, 45(1): 122-130. doi: 10.7513/j.issn.1004-7638.2024.01.018
Abstract(203) HTML (69) PDF(9)
Abstract:
Based on the principal component regression analysis of the factors affecting the yield strength of EH36 offshore steel, combined with the solid solution precipitation calculation of composite precipitation phase and the classical precipitation kinetics theory, the main factors affecting the yield s...
Effect of La on non-metallic inclusions in FeCrAl alloy
Wen Jiahang, Qi Jie, Liu Chengjun
2024, 45(1): 131-138. doi: 10.7513/j.issn.1004-7638.2024.01.019
Abstract(158) HTML (42) PDF(8)
Abstract:
In order to study the influence of rare earth La addition on the type and distribution of inclusions in FeCrAl alloys, based on thermodynamic analysis, the three-dimensional morphology and composition of inclusions were observed and analyzed by SEM-EDS, and the size and quantity of inclusions were s...
Effect of heating temperature on the mechanical properties and microstructures of X80M pipeline steels
Xu Haijian, Han Chufei, Guo Cheng, Long Shan, Tian Yongjiu, Sha Xiaochun
2024, 45(1): 139-144. doi: 10.7513/j.issn.1004-7638.2024.01.020
Abstract(162) HTML (117) PDF(17)
Abstract:
The effects of heating temperatures on the prior austenite grain size, microstructure and mechanical properties of X80M pipeline steels with a large wall thickness were investigated in this paper. The results showed that the heating temperature has a great effect on the drop weight tear test (DWTT) ...
Study on viscous flow characteristics of CaO-SiO2- MgO-Al2O3-TiO2-CaCl2 slag system
Qiao Junqiang, Wang Zhenfei, Pan Yuejun, Xing Xiangdong, Zhang Jianliang, Xu Runsheng
2024, 45(1): 145-151. doi: 10.7513/j.issn.1004-7638.2024.01.021
Abstract(169) HTML (26) PDF(11)
Abstract:
The viscous flow characteristics of slag are closely related to the stability of the blast furnace. In this paper, the viscosity and melting temperature of chlorine-containing high-titanium slag (CaO-SiO2-MgO-Al2O3-TiO2-CaCl2) were studied, and their structural evolution was analyzed by Fourier tran...
Study on the high-temperteraure tensile property and damage behavior in GH4141 superalloy
Zhang Zhao, Pei Binghong, Feng Xu, Xin Ruishan, Guo Xiaodong, Xiao Dongping, Zhou Yang
2024, 45(1): 152-157. doi: 10.7513/j.issn.1004-7638.2024.01.022
Abstract(245) HTML (42) PDF(16)
Abstract:
This study focuses on the tensile properties of GH4141 superalloy tested at room temperature, 300 ℃ and 500 ℃, respectively. The tensile strength obtained at high temperatures of 300 ℃ and 500 ℃ with serrated stress-strain curves are lower than that obtained at room temperature. In addition, the ten...
Thermodynamic behaviour of second phases precipitation in vanadium-bearing high-speed steel for railway wheel
Ding Xiaoming, Li Feng, Guo Xiaopei, Li Tao, Ju Liying, Song Xiaohui
2024, 45(1): 158-164. doi: 10.7513/j.issn.1004-7638.2024.01.023
Abstract(224) HTML (59) PDF(12)
Abstract:
A thermodynamic Thermo-calc software was used to calculate the precipitation behavior of second phase in vanadium-bearing high-speed railway wheel steel. The composition of equilibrium phase in low-carbon wheel steel and the influence of temperature and vanadium content on the precipitation of the s...
Numerical simulation study on the mechanical properties and failure of laser spot welding joint
Zheng Bangzhi, Tian Xiaolin, Wang Zelong, Feng Zhaolong
2024, 45(1): 165-170. doi: 10.7513/j.issn.1004-7638.2024.01.024
Abstract(161) HTML (151) PDF(22)
Abstract:
The static and dynamic mechanical properties of three kinds of laser welded joints under tensile, shearing and peeling conditions were tested, and the microstructure characteristics and hardness distribution of the spot welded joints were analyzed. The results show that the shape of solder joints is...
Study on rolling wear and rolling contact fatigue behavior of pearlite/bainite rail steels at the low temperature of −35
Wang Honghao, Ding Haohao, Wang Yuan, Chen Chongmu, Wang Wenjian, Zhou Zhongrong
2024, 45(1): 171-176. doi: 10.7513/j.issn.1004-7638.2024.01.025
Abstract(203) HTML (71) PDF(33)
Abstract:
The rail in the high altitude and high latitude regions faces the low temperature service environment. The rolling wear and damage behaviors under low temperature are the significant factors influencing the rail service safety. The wear and rolling contact fatigue (RCF) damage laws of pearlite rail ...
Corrosion behavior of HRB500aE seismic corrosion resistant reinforcement in sodium sulfite solution
Zhang Zhigang, Liu Yong, Wang Jiaojiao, Zhang Hongqi
2024, 45(1): 177-181. doi: 10.7513/j.issn.1004-7638.2024.01.026
Abstract(173) HTML (39) PDF(7)
Abstract:
In the alternate wet and dry environment of sodium sulfite solution, periodic corrosion tests were carried out for both the newly developed anti-seismic rebar resistant to industrial atmospheric corrosion and reference HRB400 ordinary rebar, in order to investigate its corrosion behavior in the simu...
Effect of micro-content tellurium on cutting performance of 38MnVS non-quenched and tempered steel
Liu Nianfu, Li Jie, Tian Qianren, Xu Xiangyu, Fu Jianxun
2024, 45(1): 182-187. doi: 10.7513/j.issn.1004-7638.2024.01.027
Abstract(233) HTML (74) PDF(8)
Abstract:
In order to explore the mechanism of effect of tellurium modification on the machinability of non-quenched and tempered steel (NQTS), a sulfide modification test of 38MnVS NQTS with tellurium was carried out, and effect of tellurium modification on morphology of sulfide and machinability of steel wa...
Evenness of solidification structure and solute distribution in the continuous casting billet of gear steel
Wang Haijie, Li Pingfan, Lan Peng, Chen Liang, Ai Hongzhou, Wang Zhangyin, Zhang Jiaquan
2024, 45(1): 188-196. doi: 10.7513/j.issn.1004-7638.2024.01.028
Abstract(169) HTML (41) PDF(7)
Abstract:
The evenness of solidification structure and solute distribution in the continuous casting billet of 20CrMnTi gear steel was experimentally investigated, and the symbiotic relationship and formation mechanism of coarse equiaxed dendrites and spot segregation were proposed. The control strategy on th...
Analysis of standard GB/T 10561-2023: Determination of content of nonmetallic inclusions in steel-micrographic method using standard diagrams
Zhang Zhenwei, Ma Yuchen, You Yanglijun, Wang Ruolan, Chen Min, Zhao Jie, Jiang Rui, Li Yulei
2024, 45(1): 197-204. doi: 10.7513/j.issn.1004-7638.2024.01.029
Abstract(697) HTML (1343) PDF(247)
Abstract:
The inspection standard for non-metallic inclusions (GB/T 10561-2023) has been revised. In order to more precisely implement the revised standard, in this paper, we provide a detailed analysis on the revised contents of the new standard GB/T 10561-2023 “Determination of Non-metallic Inclusion Conten...