2023 Vol. 44, No. 6

Separating and Extracting of Vanadium and Titanium
Global vanadium industry development report 2022
Wu You, Chen Donghui, Liu Wuhan, Zhang Bangxu, He Rui
2023, 44(6): 1-8. doi: 10.7513/j.issn.1004-7638.2023.06.001
Abstract(730) HTML (2288) PDF(246)
Abstract:
The overall situation of vanadium industry in 2022 was elaborated and analyzed from the global vanadium resources and production capacity, the output, supply and demand, import and export, as well as the market prices. Based on the current operating situation of the vanadium industry at home and abr...
Thoughts and countermeasures on the development of Panzhihua vanadium and titanium industry
Luo Jinhua
2023, 44(6): 9-16. doi: 10.7513/j.issn.1004-7638.2023.06.002
Abstract(255) HTML (248) PDF(42)
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The vanadium-titanium resource value chain, vanadium-titanium technology industry chain and industrial agglomeration development status of Panzhihua were comprehensively reviewed. The existing problems and development prospects of vanadium-titanium industry were analyzed. Combined with the construct...
Study on speciation analysis of vanadate
Pu Yuwen, Liu Xi, Tang Kang, Xu Zongyuan, Zheng Guocan, Chen Yan, Liu Zuohua, Du Jun, Peng Yi, Tao Changyuan
2023, 44(6): 17-23. doi: 10.7513/j.issn.1004-7638.2023.06.003
Abstract(293) HTML (34) PDF(26)
Abstract:
In the typical calcium calcination–acid leaching process of converter vanadium slag, the leaching solution contains many impurities, and the change of vanadium phase in this process will directly affect the overall recovery rate of vanadium. It is a great challenge to determine the migration and tra...
Controllable hydrothermal synthesis and zinc storage properties of ammonium vanadium oxides
Yang Zhi, Tang Yunqi, Lu Chao, Gong Ming
2023, 44(6): 24-31. doi: 10.7513/j.issn.1004-7638.2023.06.004
Abstract(241) HTML (44) PDF(15)
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Ammonium vanadium oxides are promising cathode materials for aqueous zinc-ion batteries due to their lightweight and high capacity, however, the controlled synthesis still remains a challenge. A series of ammonium vanadium oxides with different phases and morphologies were successfully synthesized b...
Leaching behavior of vanadium-chromium residue enhanced by ultrasonic
Gong Qian, Wang Xingxing, Jin Guixuan, Huang Jinlei, Tang Dan, Huang Huisheng, Li Bing, Shi Wenbing, Lin Yinhe, Peng Hao
2023, 44(6): 32-37. doi: 10.7513/j.issn.1004-7638.2023.06.005
Abstract(219) HTML (92) PDF(13)
Abstract:
Vanadium is existed as low-valence in the vanadium-chromium residue, it is hard to leach out in alkaline medium, high-energy consumption is accompanied by roasting-leaching process. In this paper, ultrasonic was introduced to enhance the leaching process of vanadium-chromium residue to oxidize the l...
Multivariate correlation analysis of qualified liquid and vanadium pentoxide composition during vanadium precipitation
Wu Jinshu, Rao Yuzhong, Wu Zhenxiu, Jiang Lin
2023, 44(6): 38-45. doi: 10.7513/j.issn.1004-7638.2023.06.006
Abstract(223) HTML (65) PDF(14)
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The effects of phosphorus, iron, manganese, silicon and vanadium in the qualified solution during vanadium precipitation on the composition of vanadium pentoxide were investigated through multivariate correlation analysis using Pearson coefficient statistics, probability density analysis and probabi...
Application of Vanadium and Titanium
Research status and prospect of high-strength β-titanium alloy
Wang Andong, Xiang Zhilei, Zhou Zongyi, Ma Xiaozhao, Han Jingyu, Chen Ziyong
2023, 44(6): 46-57. doi: 10.7513/j.issn.1004-7638.2023.06.007
Abstract(1488) HTML (288) PDF(172)
Abstract:
For titanium alloys, the type and content of alloying elements have a great impact on the properties of the alloy. For β-titanium alloy, the main problem is how to select β-stable elements and control the addition of β-stable elements. In this paper, the influence of different alloyed elements on β-...
Preparation of high-purity TiSi2 and eutectic Si-Ti alloys by vacuum electromagnetic directional solidification
Zhang Yakun, Lei Yun, Ma Wenhui
2023, 44(6): 58-63. doi: 10.7513/j.issn.1004-7638.2023.06.008
Abstract(255) HTML (45) PDF(13)
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To prepare the high-purity TiSi2 and eutectic Si-Ti alloys, the vacuum electromagnetic directional solidification technique was used to separate and purify Ti-Si alloys in this study. The results show that the vacuum electromagnetic directional solidification can effectively purify the Ti-Si alloys....
Study on hot deformation and heat treatment of a novel series of high strength and wear resistance β titanium Ti-Al-Mo-V-Cr alloy
Yue Ke, Sun Yingjun, Peng Li, Lin Chongzhi
2023, 44(6): 64-69. doi: 10.7513/j.issn.1004-7638.2023.06.009
Abstract(278) HTML (52) PDF(16)
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Taking high strength and wear resistance β titanium Ti-Al-Mo-V-Cr alloy as the research object, the hot deformation behaviors with varying hot working conditions were studied, and the influence of heat treatment on the microstructure and mechanical properties of cold rolled sheet was analyzed. The r...
Wear properties of TiC particle reinforced iron matrix composites prepared by casting sintering method
Sun Xueli, Wang Shuai, Liu Chenyu, Fu Zhiqiang, Zheng Kaihong, Wang Juan, Ke Zhimin
2023, 44(6): 70-75. doi: 10.7513/j.issn.1004-7638.2023.06.010
Abstract(272) HTML (84) PDF(16)
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TiC particles reinforced high chromium cast iron matrix composites were prepared by casting sintering method. The effects of reinforced particles on the microstructure and wear behavior of the composites were studied by EDS and SEM. The results showed that the Rockwell hardness (HRC) of the composit...
Study on effect of rare earths on the mechanical and biological activity of HA/Ti composites
Fan Xingping, Yang Cheng
2023, 44(6): 76-80. doi: 10.7513/j.issn.1004-7638.2023.06.011
Abstract(202) HTML (49) PDF(5)
Abstract:
In order to further improve the properties of HA/Ti composite materials, using HA powder and commercial Ti powder as raw materials, adding a certain amount of different rare earth complexes (CeO2, LaF3 and SrO), a rare earth reinforced HA/Ti biological composite material was prepared by powder metal...
Effect of SPS sintering process on microstructure and mechanical properties of TiC / 6061Al composites
Zhang Yang, Liu Cansen, Wang Juan, Tian Zhuo, Zheng Kaihong, Ke Zhimin
2023, 44(6): 81-87. doi: 10.7513/j.issn.1004-7638.2023.06.012
Abstract(209) HTML (42) PDF(11)
Abstract:
The 2% TiC/6061Al composites were prepared by low-speed horizontal ball milling and spark plasma sintering ( SPS ). The effects of different sintering temperatures and pressures on the density, microstructure and mechanical properties of the composites were studied by optical microscope, scanning el...
Resources Environment and Energy Saving
Experimental study on upgrading and flotation of titanium concentrate in a concentrator in Panxi area
Su Xin, Hu Houqin, Wang Hongbin
2023, 44(6): 88-92. doi: 10.7513/j.issn.1004-7638.2023.06.013
Abstract(282) HTML (110) PDF(20)
Abstract:
The floating titanium concentrate grade of a concentrator in Panxi area is 46.84%, among which gangue minerals SiO2 and CaO are not conducive to the subsequent chlorination process of titanium dioxide. Adding inhibitors to acidified sodium silicate, sulfuric acid, sodium silicate, sodium fluorosilic...
Thermodynamic analysis of recovering valuable elements from steel slag by thermite reduction in converter
Cao Lei, Shi Jiahao, Gao Yuning
2023, 44(6): 93-97. doi: 10.7513/j.issn.1004-7638.2023.06.014
Abstract(247) HTML (91) PDF(18)
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Aiming at recovery of valuable elements such as Fe, P, Mn and Si from Bessemer steel slag and utilization of steel slag, the thermodynamic conditions and influencing rules of thermite reduction and recovery of valuable elements from Bessemer steel slag were analyzed by a Factsage8.2 software thermod...
Preparation and properties of high-strength fired water permeable brick containing vanadium-titanium iron ore tailings
Wu Pingchuan, Liu Zhibing, Liu Jing, Ping Haoyan, Ma Jintao, Wang Changlong, Zheng Yongchao, Jing Jianlin, Qi Yang, Zhai Yuxin, Liu Feng
2023, 44(6): 98-109. doi: 10.7513/j.issn.1004-7638.2023.06.015
Abstract(185) HTML (107) PDF(11)
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In order to promote the efficient comprehensive utilization of vanadium-titanium iron ore tailings (VTIOTs), the basic properties and firing mechanism of high-strength fired water permeable bricks (HSFWPB) containing VTIOTs were investigated by using orthogonal test method, X-ray diffraction (XRD), ...
Study on iron removal from industrial titanium gypsum
Peng Musen, He Lin, Li Haiyan, Luo Jianhong
2023, 44(6): 110-116. doi: 10.7513/j.issn.1004-7638.2023.06.016
Abstract(245) HTML (71) PDF(21)
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In this study, the removal of iron impurity contained in the industrial sulfuric acid leaching titanium gypsum was investigated, which leads to effective improvement of purity and whiteness of titanium gypsum, providing sufficient raw materials for the development and utilization of titanium gypsum ...
Ferrous Metallurgy and Materials
Effect of particle size composition of iron ore fines on the suitable amount of bonding phase in sintering process
Fan Xinsheng, Du Yu, Guo Xingmin
2023, 44(6): 117-125. doi: 10.7513/j.issn.1004-7638.2023.06.017
Abstract(221) HTML (141) PDF(8)
Abstract:
Calcium ferrite is main bonding phase in high-basicity sinter, its formation is closely related to the sinter quality, and the appropriate amount of bonding phase is also an important factor of energy saving and carbon reduction in the sintering process. In this work, mono-calcium ferrite (CF) as an...
Experimental study on sintering of fine grained high-grade vanadium titanium magnetite concentrate from Pangang
Wang Yujian, Hu Peng
2023, 44(6): 126-132. doi: 10.7513/j.issn.1004-7638.2023.06.018
Abstract(208) HTML (38) PDF(13)
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In view of the physical and chemical properties of high-grade vanadium titanium magnetite, single firing contrast experiment, different substitute ratio experiment of high-grade ore and orthogonal experimental study on parameter optimization of sintering technical and economic indexes of sintering f...
Study on microstructure evolution and austenitizing process of 1800 MPa grade ultra-high strength hot stamping steels
Liu Shuang, Chen Huiqin, Cao Miao, Che Xin, Yang Fan, Feng Yi
2023, 44(6): 133-138. doi: 10.7513/j.issn.1004-7638.2023.06.019
Abstract(167) HTML (182) PDF(7)
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The evolution of microstructures and properties of 1800 MPa ultra-high strength hot stamping steels under different austenitizing temperatures and holding times were experimentally studied in this paper, and the optimum hot stamping austenitizing process was established. The results show that when t...
Study on the role of CaF2 in CaO-Al2O3-based mold fluxes with different acid-base property
Shi Yi, Qi Jie, Liu Chengjun, Jiang Maofa
2023, 44(6): 139-148. doi: 10.7513/j.issn.1004-7638.2023.06.020
Abstract(255) HTML (71) PDF(8)
Abstract:
The new CaO-Al2O3 based mold fluxes can effectively inhibit the interfacial reaction between Al and slag components in high-aluminum steel casting. However, there were still some problems in the casting process, such as strong crystallization performance and uneven heat transfer. Fluxing agent was o...
Establishment of a constitutive model of aviation stainless steel 0Cr17Ni4Cu4Nb considering the coupling effects of strain, strain rate and temperature
Zhang Jilin, Zhang Youming, Luo Wencui, Yi Xiangbin, Tang Linhu, Yao Jiabao
2023, 44(6): 149-159. doi: 10.7513/j.issn.1004-7638.2023.06.021
Abstract(355) HTML (105) PDF(13)
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The aviation stainless steel 0Cr17Ni4Cu4Nb has excellent characteristics and is widely used in important parts of various machines. The machining process of these parts is accompanied by large strain, high temperature and high strain rate. Based on this coupling relationship, a constitutive model th...
Effect of aging temperature on microstructure and properties of Monel K500 alloy
Jia Xuemei, Wang Jie, Liu Tingyao, Zheng Huaibei, Wang Qinying, Xi Yuchen, Dong Lijin
2023, 44(6): 160-166. doi: 10.7513/j.issn.1004-7638.2023.06.022
Abstract(290) HTML (72) PDF(19)
Abstract:
The heat treatment of solution + aging process was conducted on Monel K500 alloy. For investigating the effect of aging temperature on the microstructure and properties of Monel K500 alloy, the micro-hardness and tensile properties were measured and the microstructure of the samples was analyzed by ...
Influence of microstructure and carbide evolution of low-carbon martensitic stainless steel on tool performance
Li Guoqing, Lu Guangyi, Ti Chang, Lin Siwei, Liu Wenle, Wang Xuelin, Shang Chengjia, Guan Wenjie, Guo Fujian
2023, 44(6): 167-171. doi: 10.7513/j.issn.1004-7638.2023.06.023
Abstract(304) HTML (90) PDF(6)
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In the current study, the sharpness test and microstructure characterization for the 30Cr13 cutter under the regime of quenching and tempering processes was performed to investigate the relationship between distribution and type of carbides and sharpness of cutting tools. After the tempering process...
The evolution of hot-rolled banded microstructure in low carbon microalloyed steels
Wang Bo, Li Shuheng, Mo Chaoqun, Zhang Qingjun
2023, 44(6): 172-178. doi: 10.7513/j.issn.1004-7638.2023.06.024
Abstract(229) HTML (70) PDF(12)
Abstract:
Banded structure defects often appear in low carbon microalloyed steels during rolling process, which have a great impact on the product quality and service properties. In this study, Q345 hot-rolled slab in a plant was selected as the research object, and the evolution of the banded structure in di...
Study on size-dependence of tensile mechanical properties and plastic deformation mechanism in CoCrFeNiMn high entropy alloy
An Minrong, Yao Junfan, Chen Xuan, Wang Bo, Lü Jiangyi, Zhu Zhihao, Quan Kai, Li Teng
2023, 44(6): 179-185. doi: 10.7513/j.issn.1004-7638.2023.06.025
Abstract(266) HTML (63) PDF(17)
Abstract:
The mechanical properties of CoCrFeNiMn high entropy alloys (HEAs) with different cross section sizes were investigated by molecular dynamics simulation under tensile loading. Modified embedding atomic potential was employed to describe the interactions between Co, Cr, Fe, Ni and Mn atoms. The simul...
Study on the differences in microstructure, mechanical properties, and deformation mechanism between DH and DP steels
Zhou Li, Xue Renjie, Cao Xiaoen, Wen Caijun
2023, 44(6): 186-191. doi: 10.7513/j.issn.1004-7638.2023.06.026
Abstract(210) HTML (52) PDF(13)
Abstract:
High speed tensile test, comprehensive forming test, field emission scanning electron microscope (SEM), X-ray diffraction (XRD), electron backscatter diffraction (EBSD) and other characterization methods were used to study the differences of microstructure and properties between DH780 and DP780 cold...
The hardness and softening behavior of HAZ in Ti and Nb precipitation strengthened 600 MPa wheel steel
Dong Xianchun, Liu Xinyao, Cai Ning, Zhang Dawei, Zhang Xiazhou, Li Xuetao
2023, 44(6): 192-197. doi: 10.7513/j.issn.1004-7638.2023.06.027
Abstract(162) HTML (33) PDF(4)
Abstract:
A 22.5 × 9.0 wheel rim made of Ti and Nb precipitation strengthened 600 MPa wheel steel was manufactured by continuous flash butt welding process to. The lap joint of rim and spoke was welded under gas shielded welding process. The flash butt welded joint of the rim cracked during the flaring proces...
Prediction of primary carbide size in high carbon chromium bearing steel
Feng Qian, Zeng Yanan, Li Junguo, Wang Yitong, Wang Yajun, Tang Guozhang
2023, 44(6): 198-204. doi: 10.7513/j.issn.1004-7638.2023.06.028
Abstract(192) HTML (34) PDF(7)
Abstract:
A Thermo-Calc thermodynamic calculation software was used to conduct thermodynamic analysis on the phase transformation, primary carbide phase type, and primary carbide precipitation temperature during solidification process of bearing steel. Based on both Scheil segregation model and Goto model, th...