A complex desulfurizer and its application to the desulfurization of hot metal by pneumatic injection were discussed. Using CaC2 mixed with the supplemental reactants, the rate of desulfurization was the same as that of pure CaC2.Operational results show that the average desulfurization rate was 90.45%,the average final S content in the hot metal 0.0065% and the average temperature loss of hot metal 19℃, while the average initial S content in the hot metal was 0.071% and the average desulfurizer consumption 8.08kg/tFe. The effect of desulfurization was the same as the level of KR process.