Methods for preparation of titanium dioxide pigment and high purity Sc2O3 from B.F. slag at Panzhihua I. & S. Co. are introduced.The BA01-01 titanium dioxide was produced by rational use of element interaction in acidolysis liquor,control of aluminium removal,modification of total ion concentration in titanium liquor and preparation of high activity seed crystal.Sc2O3 of up to 99, 99% grade was recovered from waste acid after hydrolysis using full extraction method. The technology is widely applicable.