CHEN Jinliang, JIN Xueyuan, YI Jianhong. Effect of annealing on microstructure and mechanical properties of CrCoNi medium entropy alloy rolled at room temperature and liquid nitrogen temperature[J]. IRON STEEL VANADIUM TITANIUM, 2025, 46(3): 167-173, 204. doi: 10.7513/j.issn.1004-7638.2025.03.023
Citation: CHEN Jinliang, JIN Xueyuan, YI Jianhong. Effect of annealing on microstructure and mechanical properties of CrCoNi medium entropy alloy rolled at room temperature and liquid nitrogen temperature[J]. IRON STEEL VANADIUM TITANIUM, 2025, 46(3): 167-173, 204. doi: 10.7513/j.issn.1004-7638.2025.03.023

Effect of annealing on microstructure and mechanical properties of CrCoNi medium entropy alloy rolled at room temperature and liquid nitrogen temperature

doi: 10.7513/j.issn.1004-7638.2025.03.023
  • Received Date: 2024-04-12
  • Publish Date: 2025-06-30
  • The as-casted CrCoNi medium entropy alloy was rolled at room temperature and liquid nitrogen temperature, respectively, and then annealed at medium and low temperatures in short period respectively. The difference of strength and improvement of the alloy under room temperature rolling + annealing and liquid nitrogen temperature rolling + annealing conditions was studied. The experimental results show that when the annealing parameter is 700 ℃/30 min, the yield strengths of studied alloy under both two rolling conditions are much higher than 1000 MPa, and the fracture elongation of LNTR-700℃ sample is 26.2%, which is much higher than the reported values of strength and elongation for same alloy under same annealing conditions. When the annealing parameter is 800 ℃/30 min, the yield strength of RTR-800℃ alloy is 987 MPa and the fracture elongation is 37.2%, while the yield strength of LNTR-800℃ sample is 947 MPa and the fracture elongation is 58%. In other words, compared with room temperature rolling + annealing, liquid nitrogen temperature rolling + annealing process can significantly improve the strength and ductility of CrCoNi medium entropy, which is attributed to the finer grains, higher recrystallization degree and lower dislocation density benefited from liquid nitrogen temperature rolling + annealing process.
  • [1]
    YEH J, CHEN S, LIN S. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes[J]. Advanced Engineering Materials, 2004,6:299-303. doi: 10.1002/adem.200300567
    [2]
    CANTOR B, CHANG I T H, KNIGHT P. Microstructural development in equiatomic multicomponent alloys[J]. Materials Science and Engineering A, 2004,375:213-218.
    [3]
    HSU Y J, CHIANG W C, WU J K. Corrosion behavior of FeCoNiCrCux high-entropy alloys in 3.5% sodium chloride solution[J]. Materials Chemistry and Physics, 2005,92(1):112-117. doi: 10.1016/j.matchemphys.2005.01.001
    [4]
    ZHANG W, LIAW P K, ZHANG Y. Science and technology in high-entropy alloys[J]. Science China Materials, 2018,61(1):2-22. doi: 10.1007/s40843-017-9195-8
    [5]
    GAO M C, YEH J W, LIAW P K, et al. High-entropy alloys[J]. Cham: Springer International Publishing, 2016.
    [6]
    ZHANG Y. High-entropy materials[J]. Springer Nature Singapore Pte Ltd, 2019,2:215-232.
    [7]
    MIAHRA R S, HARIDAS R S, AGRAWAL P. High entropy alloys – tunability of deformation mechanisms through integration of compositional and microstructural domains[J]. Materials Science and Engineering: A, 2021,812:141085. doi: 10.1016/j.msea.2021.141085
    [8]
    ZHANG Y, ZUO T T, TANG Z, et al. Microstructures and properties of high-entropy alloys[J]. Progress in Materials Science, 2014,61:1-93. doi: 10.1016/j.pmatsci.2013.10.001
    [9]
    YEH J. Alloy design strategies and future trends in high-entropy alloys[J]. JOM, 2013,65(12):1759-1771. doi: 10.1007/s11837-013-0761-6
    [10]
    TSAI K Y, TSAI M H, YEH J W. Sluggish diffusion in Co–Cr–Fe–Mn–Ni high-entropy alloys[J]. Acta Materialia, 2013,61(13):4887-4897. doi: 10.1016/j.actamat.2013.04.058
    [11]
    SLONE C E, MIAO J, GEORGE E P, et al. Achieving ultra-high strength and ductility in equiatomic CrCoNi with partially recrystallized microstructures[J]. Acta Materialia, 2019,165:496-507. doi: 10.1016/j.actamat.2018.12.015
    [12]
    WU Z, BEI H, PHARR G M, et al. Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures[J]. Acta Materialia, 2014, 81: 428.
    [13]
    SONG Li Y, WANG Y F, WANG M S, et al. Microstructure and mechanical behavior of CrCoNi medium entropy alloys in 1000 MPa grade[J]. Joural of Aeronautical Materials, 2020,40(4):62-70. (宋凌云, 王艳飞, 王明赛, 等. 1000 MPa级CrCoNi中熵合金的微观组织和力学行为[J]. 航空材料学报, 2020,40(4):62-70.

    SONG Li Y, WANG Y F, WANG M S, et al. Microstructure and mechanical behavior of CrCoNi medium entropy alloys in 1000 MPa grade[J]. Joural of Aeronautical Materials, 2020, 40(4): 62-70.
    [14]
    PRAVEEN S, BAE J W, ASGHARI Rad P, et al. Ultra-high tensile strength nanocrystalline CoCrNi equiatomic medium entropy alloy processed by high-pressure torsion[J]. Materials Science and Engineering: A, 2018,735:394-397. doi: 10.1016/j.msea.2018.08.079
    [15]
    SCHNEIDER M, GEORGE E P, MANESCAU T J, et al. Analysis of strengthening due to grain boundaries and annealing twin boundaries in the CrCoNi medium-entropy alloy[J]. International Journal of Plasticity, 2020,124:155-169. doi: 10.1016/j.ijplas.2019.08.009
    [16]
    LIANG Y, YANG X, MING K. et al. In situ observation of transmission and reflection of dislocations at twin boundary in CoCrNi alloys[J]. Science China Technological Sciences volume, 2021,64:407-413. doi: 10.1007/s11431-019-1517-8
    [17]
    LAPLANCHE G, KOSTKA A, REINHART C, et al. Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi[J]. Acta Materialia, 2017,128:292-303. doi: 10.1016/j.actamat.2017.02.036
  • Relative Articles

  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(8)

    Article Metrics

    Article views (14) PDF downloads(3) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return