Citation: | LIU Zhitong, ZHANG Shuhui, LAN Chenchen, LÜ Qing, ZHANG Shuqing, SUN Yanqin. Discussion on the preparation of hydrogen-rich reducing gas by coupling metallurgical solid waste oxygen carrier and chemical looping gasification technology[J]. IRON STEEL VANADIUM TITANIUM, 2025, 46(2): 103-111. doi: 10.7513/j.issn.1004-7638.2025.02.015 |
[1] |
ZHANG S H, WU X Z, LIU R, et al. Discussion on smelting characteristics and problems of blast furnace with hydrogen-rich gas injection[J]. Iron & Steel, 2024,59(1):1-11. (张淑会, 武校章, 刘然, 等. 喷吹富氢气体高炉冶炼特点及存在问题的探讨[J]. 钢铁, 2024,59(1):1-11.
ZHANG S H, WU X Z, LIU R, et al. Discussion on smelting characteristics and problems of blast furnace with hydrogen-rich gas injection[J]. Iron & Steel, 2024, 59(1): 1-11.
|
[2] |
YUAN X, PENG F, SUN Z H. Analysis of reducing pollution and carbon for hydrogen-based shaft furnace direct reduction technology[J]. Energy for Metallurgical Industry, 2024,43(3):3-7,43. (员晓, 彭锋, 孙泽辉. 氢基竖炉直接还原技术减污降碳分析[J]. 冶金能源, 2024,43(3):3-7,43. doi: 10.3969/j.issn.1001-1617.2024.03.001
YUAN X, PENG F, SUN Z H. Analysis of reducing pollution and carbon for hydrogen-based shaft furnace direct reduction technology[J]. Energy for Metallurgical Industry, 2024, 43(3): 3-7,43. doi: 10.3969/j.issn.1001-1617.2024.03.001
|
[3] |
TANG G Y, GU J, YANG Q, et al. Research progress in chemical looping gasification technology of organic solid waste[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2021,37(3):700-718. (唐亘炀, 顾菁, 杨秋, 等. 有机固体废弃物化学链气化技术研究进展[J]. 石油学报(石油加工), 2021,37(3):700-718.
TANG G Y, GU J, YANG Q, et al. Research progress in chemical looping gasification technology of organic solid waste[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2021, 37(3): 700-718.
|
[4] |
BHAVSAR S, NAJERA M, VESER G. Chemical looping dry reforming as novel, intensified process for CO2 activation[J]. Chemical Engineering & Technology, 2012,35(7):1281-1290.
|
[5] |
TIAN X, NIU P J, MA Y X, et al. Chemical-looping gasification of biomass: Part II. Tar yields and distributions[J]. Biomass and Bioenergy, 2018,108:178-189. doi: 10.1016/j.biombioe.2017.11.007
|
[6] |
HUANG Z, HE F, FENG Y P, et al. Synthesis gas production through biomass direct chemical looping conversion with natural hematite as an oxygen carrier[J]. Bioresource Technology, 2013,140:138-145. doi: 10.1016/j.biortech.2013.04.055
|
[7] |
GUO W J, GE H J, SHEN L H, et al. Experimental study on chemical looping gasification of biomass with hematite base on 25 kWth fluidized beds[J]. Journal of Thermal Science and Technology, 2017,16(1):78-86. (郭万军, 葛晖骏, 沈来宏, 等. 基于铁矿石载氧体25kWth串行流化床生物质化学链气化实验研究[J]. 热科学与技术, 2017,16(1):78-86.
GUO W J, GE H J, SHEN L H, et al. Experimental study on chemical looping gasification of biomass with hematite base on 25 kWth fluidized beds[J]. Journal of Thermal Science and Technology, 2017, 16(1): 78-86.
|
[8] |
SUN G Z, AN Z W, CHEN Y M, et al. Research progress on sludge/biomass chemical looping gasification and ash-moisture influence on gasification characteristics[J]. Clean Coal Technology, 2023,29(9):1-13. (孙国震, 安泽文, 陈岩明, 等. 基于铁基载氧体的污泥/生物质化学链气化及其灰分-水分影响特性研究进展[J]. 洁净煤技术, 2023,29(9):1-13.
SUN G Z, AN Z W, CHEN Y M, et al. Research progress on sludge/biomass chemical looping gasification and ash-moisture influence on gasification characteristics[J]. Clean Coal Technology, 2023, 29(9): 1-13.
|
[9] |
DENG G X. Study on methane chemical looping combustion performance of red mud oxygen carrier[D]. Kunming: Kunming University of Science and Technology, 2018. (邓贵先. 赤泥氧载体的甲烷化学链燃烧性能研究[D]. 昆明: 昆明理工大学, 2018.
DENG G X. Study on methane chemical looping combustion performance of red mud oxygen carrier[D]. Kunming: Kunming University of Science and Technology, 2018.
|
[10] |
DONG X J, ZUO Z L, YANG H Q, et al. Calcination modification and redox characteristics of copper slag-based oxygen carrier[J]. Mining and Metallurgical Engineering, 2023,43(6):107-111. (董鑫江, 左宗良, 杨涵奇, 等. 铜渣氧载体煅烧改性及氧化还原特性研究[J]. 矿冶工程, 2023,43(6):107-111. doi: 10.3969/j.issn.0253-6099.2023.06.023
DONG X J, ZUO Z L, YANG H Q, et al. Calcination modification and redox characteristics of copper slag-based oxygen carrier[J]. Mining and Metallurgical Engineering, 2023, 43(6): 107-111. doi: 10.3969/j.issn.0253-6099.2023.06.023
|
[11] |
GAO Z F, LONG H M, GAO X P, et al. Preparation and characteristics of Mn-Ce-doped Fe-based catalysts using metallurgical dust and mud containing iron[J]. Chinese Journal of Engineering, 2024,46(3):407-419. (高志芳, 龙红明, 高翔鹏, 等. 冶金含铁尘泥制备的Mn–Ce掺杂Fe基催化剂及特性[J]. 工程科学学报, 2024,46(3):407-419.
GAO Z F, LONG H M, GAO X P, et al. Preparation and characteristics of Mn-Ce-doped Fe-based catalysts using metallurgical dust and mud containing iron[J]. Chinese Journal of Engineering, 2024, 46(3): 407-419.
|
[12] |
TIAN X, WANG K, ZHAO H B, et al. Chemical looping with oxygen uncoupling of high-sulfur coal using copper ore as oxygen carrier[J]. Proceedings of the Combustion Institute, 2017,36(3):3381-3388. doi: 10.1016/j.proci.2016.08.056
|
[13] |
BAO J H, CHEN L Y, LIU F, et al. Evaluating the effect of inert supports and alkali sodium on the performance of red mud oxygen carrier in chemical looping combustion[J]. Industrial & Engineering Chemistry Research, 2016,55(29):8046-8057.
|
[14] |
LIU L M, ZHAO H B, ZHENG C G. Advances on oxygen carriers of chemical-looping combustion[J]. Coal Conversion, 2006,29(3):83-93. (刘黎明, 赵海波, 郑楚光. 化学链燃烧方式中氧载体的研究进展[J]. 煤炭转化, 2006,29(3):83-93. doi: 10.3969/j.issn.1004-4248.2006.03.021
LIU L M, ZHAO H B, ZHENG C G. Advances on oxygen carriers of chemical-looping combustion[J]. Coal Conversion, 2006, 29(3): 83-93. doi: 10.3969/j.issn.1004-4248.2006.03.021
|
[15] |
MONAZAM E R, BREAULT R W, SIRIWARDANE R. Kinetics of magnetite (Fe3O4) oxidation to hematite (Fe2O3) in air for chemical looping combustion[J]. Industrial & Engineering Chemistry Research, 2014,53(34):13320-13328.
|
[16] |
MIAO Z W, HU Z F, JIANG E C, et al. Hydrogen-rich syngas production by chemical looping reforming on crude wood vinegar using Ni-modified HY zeolite oxygen carrier[J]. Fuel, 2020,279(1):118547.
|
[17] |
RYDEN M, LYNGFELT A, MATTISSON T. Synthesis gas generation by chemical-looping reforming in a continuously operating laboratory reactor[J]. Fuel, 2006,85(12-13):1631-1641. doi: 10.1016/j.fuel.2006.02.004
|
[18] |
FRICK V, RYDEN M, LEION H. Investigation of Cu-Fe and Mn-Ni oxides as oxygen carriers for chemical-looping combustion[J]. Fuel Processing Technology, 2016,150:30-40. doi: 10.1016/j.fuproc.2016.04.032
|
[19] |
ZENG L P, HUANG F, ZHU X, et al. Chemical looping conversion of methane over CeO2-based and Co3O4-based Co3O4-CeO2 oxygen carriers: controlling of product selectivity[J]. Chemical Journal of Chinese Universities, 2017,38(1):115-125. (曾良鹏, 黄樊, 祝星, 等. 铈基与钴基Co3O4-CeO2氧载体上甲烷化学链转化特性: 产物选择性控制[J]. 高等学校化学学报, 2017,38(1):115-125. doi: 10.7503/cjcu20160411
ZENG L P, HUANG F, ZHU X, et al. Chemical looping conversion of methane over CeO2-based and Co3O4-based Co3O4-CeO2 oxygen carriers: controlling of product selectivity[J]. Chemical Journal of Chinese Universities, 2017, 38(1): 115-125. doi: 10.7503/cjcu20160411
|
[20] |
JOHANSSON M, And M T, Lyngfelt A. Creating a synergy effect by using mixed oxides of iron and nickel oxides in the combustion of methane in a chemical-looping combustion reactor[J]. Energy Fuels, 2006, 20(6): 2399-2407.
|
[21] |
GUO Q J, HU X D, LIU Y Z, et al. Coal chemical-looping gasification of Ca-based oxygen carriers decorated by CaO[J]. Powder Technology, 2015,275:60-68. doi: 10.1016/j.powtec.2015.01.061
|
[22] |
JERNDAL E, MATTISSON T, LYNGFELT A. Thermal analysis of chemical-looping combustion[J]. Chemical Engineering Research and Design, 2006,84(9):795-806. doi: 10.1205/cherd05020
|
[23] |
FENG F, GONGYE L P, WEI L, et al. Application of chemical looping combustion in carbon dioxide mitigation and research development[J]. Chemical Industry Times, 2009,23(4):67-71. (冯飞, 公冶令沛, 魏龙, 等. 化学链燃烧在二氧化碳减排中的应用及其研究进展[J]. 化工时刊, 2009,23(4):67-71. doi: 10.3969/j.issn.1002-154X.2009.04.019
FENG F, GONGYE L P, WEI L, et al. Application of chemical looping combustion in carbon dioxide mitigation and research development[J]. Chemical Industry Times, 2009, 23(4): 67-71. doi: 10.3969/j.issn.1002-154X.2009.04.019
|
[24] |
WU Y T, LIAO Y F, LIU G C, et al. Syngas production by chemical looping gasification of biomass with steam and CaO additive[J]. International Journal of Hydrogen Energy, 2018,43(42):19375-19383. doi: 10.1016/j.ijhydene.2018.08.197
|
[25] |
FENG Y. Experiments on coal and biomass chemical looping gasification based on CaO sorbent[D]. Hangzhou: Zhejiang University, 2017. (冯毅. 基于氧化钙载体的生物质与褐煤化学链气化过程的实验研究[D]. 杭州: 浙江大学, 2017.
FENG Y. Experiments on coal and biomass chemical looping gasification based on CaO sorbent[D]. Hangzhou: Zhejiang University, 2017.
|
[26] |
MOLINO A, CHIANESE S, MUSMARRA D. Biomass gasification technology: The state of the art overview[J]. Journal of Energy Chemistry, 2016,25(1):10-25. doi: 10.1016/j.jechem.2015.11.005
|
[27] |
WU Q. Study on coproduction of hydrogen and syngas by biomass chemical chain gasification with Ca-Fe based oxygen carrier[D]. Wuhan: Huazhong University of Science and Technology, 2022. (吴琼. Ca-Fe基氧载体生物质化学链气化共制备氢与合成气研究[D]. 武汉: 华中科技大学, 2022.
WU Q. Study on coproduction of hydrogen and syngas by biomass chemical chain gasification with Ca-Fe based oxygen carrier[D]. Wuhan: Huazhong University of Science and Technology, 2022.
|
[28] |
WANG S D. Characteristics and mechanism of biomass chemical looping gasification with Fe2O3/CaO[D]. Qingdao: China University of Petroleum (East China), 2021. (王士铎. Fe2O3/CaO作用下生物质化学链气化特性与机理研究[D]. 青岛: 中国石油大学(华东), 2021.
WANG S D. Characteristics and mechanism of biomass chemical looping gasification with Fe2O3/CaO[D]. Qingdao: China University of Petroleum (East China), 2021.
|
[29] |
CHEN Z H. Characteristic and mechanism investigation on biomass chemical looping gasification based on Mn-Fe composite oxygen carriers[D]. Guangzhou: South China University of Technology, 2020. (陈智豪. 基于锰铁复合载氧体的生物质化学链气化特性及机理研究[D]. 广州: 华南理工大学, 2020.
CHEN Z H. Characteristic and mechanism investigation on biomass chemical looping gasification based on Mn-Fe composite oxygen carriers[D]. Guangzhou: South China University of Technology, 2020.
|
[30] |
XIAO Y. Experiment and reaction mechanism on chemical looping gasification of biomass with barium ferrite oxygen carrier[D]. Nanjing: Southeast University, 2021. (肖艳. 基于铁酸钡载氧体的生物质化学链气化实验和反应机理研究[D]. 南京: 东南大学, 2021.
XIAO Y. Experiment and reaction mechanism on chemical looping gasification of biomass with barium ferrite oxygen carrier[D]. Nanjing: Southeast University, 2021.
|
[31] |
OREIZ M, DE DIEGO L F, ABAD A, et al. Hydrogen production by auto-thermal chemical-looping reforming in a pressurized fluidized bed reactor using Ni-based oxygen carriers[J]. International Journal of Hydrogen Energy, 2010,35(1):151-160. doi: 10.1016/j.ijhydene.2009.10.068
|
[32] |
ISHIDA M, JIN H G. A novel chemical-looping combustor without NOx formation[J]. Industrial & engineering chemistry research, 1996,35(7):2469-2472.
|
[33] |
WANG X D, JIN B S, DONG Y H, et al. Thermodynamic performance investigation on coal chemical looping combustion coupling with hydrogen generation in moving bed[J]. Electric Power Technology and Protection, 2022,38(4):300-306. (王旭东, 金保昇, 董月红, 等. 移动床煤化学链燃烧耦合制氢系统的热力学特性研究[J]. 电力科技与环保, 2022,38(4):300-306.
WANG X D, JIN B S, DONG Y H, et al. Thermodynamic performance investigation on coal chemical looping combustion coupling with hydrogen generation in moving bed[J]. Electric Power Technology and Protection, 2022, 38(4): 300-306.
|
[34] |
JIANG J Z. Design and test of a hydrogen production system based on chemical looping combustion theory[D]. Beijing: North China Electric Power University, 2011. (蒋景周. 基于化学链燃烧原理的制氢系统设计与实验[D]. 北京: 华北电力大学, 2011.
JIANG J Z. Design and test of a hydrogen production system based on chemical looping combustion theory[D]. Beijing: North China Electric Power University, 2011.
|
[35] |
LEION H, MATTISSON T, LYNGFELT A. Solid fuels in chemical looping combustion[J]. Int. J. Greenhouse Gas Control, 2008,2(2):180-600. doi: 10.1016/S1750-5836(07)00117-X
|
[36] |
LÜ Y L. Study on the characteristics of chemical chain co-gasification of coal and biomass[J]. Energy Consery Ation, 2024,43(6):87-90. (吕玉林. 煤和生物质化学链共气化特性研究[J]. 节能, 2024,43(6):87-90. doi: 10.3969/j.issn.1004-7948.2024.06.025
LÜ Y L. Study on the characteristics of chemical chain co-gasification of coal and biomass[J]. Energy Consery Ation, 2024, 43(6): 87-90. doi: 10.3969/j.issn.1004-7948.2024.06.025
|
[37] |
WU J K, GONG Z Q, LU C M, et al. Preparation and performance of modified red mud-based catalysts for selective catalytic reduction of NOx with NH3[J]. Catalysts, 2018,8(1):35. doi: 10.3390/catal8010035
|
[38] |
HE J. Study on the Chemical looping combustion performance of red mud-based oxygen carriers[D]. Maanshan: Anhui University of Technology, 2021. (何静. 赤泥基载氧体化学链燃烧性能研究[D]. 马鞍山: 安徽工业大学, 2021.
HE J. Study on the Chemical looping combustion performance of red mud-based oxygen carriers[D]. Maanshan: Anhui University of Technology, 2021.
|
[39] |
DUAN Z. Red mud removal of sodium iron extraction and oxygen storage regulation[D]. Kunming: Kunming University of Science and Technology, 2023. (段珍. 赤泥脱钠提铁及储氧性能调控[D]. 昆明: 昆明理工大学, 2023.
DUAN Z. Red mud removal of sodium iron extraction and oxygen storage regulation[D]. Kunming: Kunming University of Science and Technology, 2023.
|
[40] |
ZHANG H F, CHEN L, LIU X Y, et al. Characteristics of cyanobacteria pyrolysis and gasification during chemical looping process with red mud oxygen carrier[J]. Journal of Fuel Chemistry and Technology, 2021,49(12):1802-1811. (张海峰, 陈璐, 刘先宇, 等. 基于赤泥载氧体的蓝藻化学链热解和气化特性研究[J]. 燃料化学学报, 2021,49(12):1802-1811. doi: 10.1016/S1872-5813(21)60087-7
ZHANG H F, CHEN L, LIU X Y, et al. Characteristics of cyanobacteria pyrolysis and gasification during chemical looping process with red mud oxygen carrier[J]. Journal of Fuel Chemistry and Technology, 2021, 49(12): 1802-1811. doi: 10.1016/S1872-5813(21)60087-7
|
[41] |
LIN S. Study on modification of red mud for chemical looping combustion of coal[D]. Kunming: Kunming University of Science and Technology, 2020. (林伸. 赤泥用于煤化学链燃烧的改性研究[D]. 昆明: 昆明理工大学, 2020.
LIN S. Study on modification of red mud for chemical looping combustion of coal[D]. Kunming: Kunming University of Science and Technology, 2020.
|
[42] |
LIU Y. Research on gasification utilization technology of traditional Chinese medicine waste slag based on chemical looping technology[D]. Xuzhou: China University of Mining and Technology, 2019. (刘阳. 基于化学链的中药废渣气化利用技术研究[D]. 徐州: 中国矿业大学, 2019.
LIU Y. Research on gasification utilization technology of traditional Chinese medicine waste slag based on chemical looping technology[D]. Xuzhou: China University of Mining and Technology, 2019.
|
[43] |
ZHANG S H, WANG B Y, LAN C C, et al. Research status and prospect of recycling technologies of valuable metallic elements from copper slag[J]. China Nonferrous Metallurgy, 2022,51(3):84-93. (张淑会, 王宝勇, 兰臣臣, 等. 铜渣中有价金属元素回收技术的研究现状及展望[J]. 中国有色冶金, 2022,51(3):84-93.
ZHANG S H, WANG B Y, LAN C C, et al. Research status and prospect of recycling technologies of valuable metallic elements from copper slag[J]. China Nonferrous Metallurgy, 2022, 51(3): 84-93.
|
[44] |
DENG Z B, HUANG Z, HE F, et al. Evaluation of calcined copper slag as an oxygen carrier for chemical looping gasification of sewage sludge[J]. International Journal of Hydrogen Energy, 2019,44(33):17823-17834. doi: 10.1016/j.ijhydene.2019.05.039
|
[45] |
DONG N H, HUO R Q, LIU M, et al. Chemical looping gasification of sewage sludge using copper slag modified by NiO as an oxygen carrier[J]. Chinese Journal of Chemical Engineering, 2021,29:335-343. doi: 10.1016/j.cjche.2020.09.007
|
[46] |
WANG Y H, LIU M, DONG N H, et al. Chemical looping gasification of high nitrogen wood waste using a copper slag oxygen carrier modified by alkali and alkaline earth metals[J]. Chemical Engineering Journal, 2021,410(15):128344.
|
[47] |
WANG J S, LI Y, FENG H X, et al. Progress in treating difficult-to-handle dust and sludge and full-scale resource utilization in an iron and steel industry cluster[J]. Chinese Journal of Engineering, 2021,43(12):1737-1749. (王静松, 李岩, 冯怀萱, 等. 钢铁产业集聚区难处理尘泥处理与全量资源化利用进展[J]. 工程科学学报, 2021,43(12):1737-1749. doi: 10.3321/j.issn.1001-053X.2021.12.bjkjdxxb202112014
WANG J S, LI Y, FENG H X, et al. Progress in treating difficult-to-handle dust and sludge and full-scale resource utilization in an iron and steel industry cluster[J]. Chinese Journal of Engineering, 2021, 43(12): 1737-1749. doi: 10.3321/j.issn.1001-053X.2021.12.bjkjdxxb202112014
|
[48] |
LIU H T. Study on preparation of doped iron-based oxygen carrier by metallurgical dust[D]. Maanshan: Anhui University of Technology, 2019. (刘海涛. 冶金尘泥制备掺杂型铁基载氧体的研究[D]. 马鞍山: 安徽工业大学, 2019.
LIU H T. Study on preparation of doped iron-based oxygen carrier by metallurgical dust[D]. Maanshan: Anhui University of Technology, 2019.
|
[49] |
NIU F S, HE S T, ZHANG J X, et al. Study on ultrasonically-enhanced deep eutectic solvents leaching of zinc from zinc-containing metallurgical dust sludge[J]. Metals, 2022,12(11):1856. doi: 10.3390/met12111856
|
[50] |
GAO Z F, WU Z J, LIU W M. Preparation and chemical looping combustion properties of Fe2O3/Al2O3 derived from metallurgy iron-bearing dust[J]. Journal of Environmental Chemical Engineering, 2016,4(2):1653-1663. doi: 10.1016/j.jece.2016.02.031
|
[51] |
GAO Z F, SU C, LI N, et al. Preparation of Ca-Fe oxygen carrier using metallurgical dust[J]. Journal of Iron and Steel Research, 2018,30(10):782-788. (高志芳, 苏畅, 李娜, 等. 冶金尘泥制备钙铁双氧载体材料[J]. 钢铁研究学报, 2018,30(10):782-788.
GAO Z F, SU C, LI N, et al. Preparation of Ca-Fe oxygen carrier using metallurgical dust[J]. Journal of Iron and Steel Research, 2018, 30(10): 782-788.
|
[52] |
HILDOR F, LEION H, LINDERHOLM C J, et al. Steel converter slag as an oxygen carrier for chemical-looping gasification[J]. Fuel Processing Technology, 2020,210(15):106576
|
[53] |
ZHANG Z Y, WANG X T, ZHANG L L, et al. Characteristics of steel slag as an oxygen carrier for chemical looping gasification of sewage sludge[J]. Energy, 2022,247(15):123534.
|
[54] |
HAN J. Investigation on chemical looping gasification of sewage sludge using sewage sludge ash as oxygen carrier[D]. Hefei: University of Science and Technology of China, 2021. (韩静. 以污泥灰为载氧体的污泥化学链气化特性研究[D]. 合肥: 中国科学技术大学, 2021.
HAN J. Investigation on chemical looping gasification of sewage sludge using sewage sludge ash as oxygen carrier[D]. Hefei: University of Science and Technology of China, 2021.
|
[55] |
CHEN J, SU M, ZHANG X B, et al. Research progress in preparation of reducing gases for hydrogen metallurgy[J]. China Metallurgy, 2023,33(1):24-33. (陈健, 苏敏, 张新波, 等. 氢冶金还原性气体的制备研究进展[J]. 中国冶金, 2023,33(1):24-33.
CHEN J, SU M, ZHANG X B, et al. Research progress in preparation of reducing gases for hydrogen metallurgy[J]. China Metallurgy, 2023, 33(1): 24-33.
|