2022 Vol. 43, No. 3

Separating and Extracting of Vanadium and Titanium
Synthesis of porous bentonite modified titanium-lithium ion sieve precursor
Huang Chenghua, Li Yan, Zhang Jingjing, Shui Yi, Wu Na, Zhang Liyuan
2022, 43(3): 1-8. doi: 10.7513/j.issn.1004-7638.2022.03.001
Abstract(305) HTML (90) PDF(48)
Abstract:
The lithium titanate precursor sol was prepared by inorganic precipitation-peptization method with titanium sulfate as titanium source, lithium acetate as lithium source, followed by adding bentonite as modifier. Bentonite modified Li2TiO3 powder was obtained after stirring, aging, drying and calcin...
Study on leaching kinetics of titanium from waste denitrification catalyst with salt roasting-acid leaching
Wang Luping, Mei Guangjun, Wu Min, Yuan Qinzhi, Yu Mingming
2022, 43(3): 9-13. doi: 10.7513/j.issn.1004-7638.2022.03.002
Abstract(224) HTML (47) PDF(26)
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Titanium from waste denitrification catalyst was recovered by salt roasting-acid leaching method. The leaching kinetics of titanium in sulfuric acid was studied by nuclear shrinkage model of liquid-solid multiphase reaction. The effects of sulfuric acid concentration and acid leaching temperature on...
Study on effect of Al-Zn composite salt treatment on the quality of rutile TiO2
Lu Ruifang, Sun Qiang, Yang Fang, Wang Xiaohui, Liu Chan, Cheng Xiaozhe
2022, 43(3): 14-19. doi: 10.7513/j.issn.1004-7638.2022.03.003
Abstract(180) HTML (124) PDF(66)
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Using hydrolyzed metatitanic acid as raw materials, the effect of Al-Zn composite salt treatment on the quality of rutile TiO2 was studied. Rutile TiO2 samples were prepared by adjusting the calcination temperature. The effects of the addition of Al2O3 and ZnO on the calcination temperature required...
Preparation of lithium vanadate by solution combustion synthesis and its electrochemical properties
Chen Zongling, Cao Zhiqin, He Kui, Zhang Xuefeng
2022, 43(3): 20-25. doi: 10.7513/j.issn.1004-7638.2022.03.004
Abstract(368) HTML (65) PDF(45)
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Using ammonium nitrate, ammonium metavanadate, lithium nitrate, glucose, citric acid and glycine as raw materials, LiVO3 powder as cathode material for lithium-ion battery was successfully prepared by solution combustion synthesis. The effects of calcination temperature and calcination time on the p...
Preparation and characterization of titanium dioxide as catalyst support for denitration
Li Huaquan, Qiu Guibao, Lv Xuewei
2022, 43(3): 26-32. doi: 10.7513/j.issn.1004-7638.2022.03.005
Abstract(336) HTML (79) PDF(37)
Abstract:
The specific titanium dioxide, a catalyst carrier for denitration, was prepared from metatitanic acid in the process of sulfuric acid titanium dioxide production, via ammonia neutralization, active element complexing, calcination and pulverization. The crystal structure and morphology of the powders...
Effect of biomass drying titanium concentrate on its acid hydrolysis performance
Wang Haibo, Sun Ke, Cheng Xiaozhe, Wang Bin, Wu Xiaoping
2022, 43(3): 33-39. doi: 10.7513/j.issn.1004-7638.2022.03.006
Abstract(235) HTML (63) PDF(30)
Abstract:
In view of the decline of acid hydrolysis performance of titanium concentrate directly dried by biomass, the influence of different drying methods on acid hydrolysis performance of titanium concentrate were found by comparing the difference of acid hydrolysis performance of titanium concentrate, and...
Application of Vanadium and Titanium
Study on vacuum electron beam welding process of 50 mm thick plate TC4 and TA17 titanium alloys
Li Dadong, Bai Wei, Deng Jian, Chen Rong, Geng Naitao
2022, 43(3): 40-46. doi: 10.7513/j.issn.1004-7638.2022.03.007
Abstract(676) HTML (287) PDF(43)
Abstract:
Based on the analysis of the density, specific heat and thermal conductivity of TC4 and TA17 titanium alloys by using JMATPRO thermodynamic software, the vacuum electron beam welding experiments of TC4 and TA17 titanium alloys with a thickness of 50 mm were carried out. The parameters of high and me...
Effect of spark plasma sintering temperature on structure and properties of TiB2/Al composites
Lu Chao, Zhang Ao, Yang Zhi, Liu Jia, An Xuguang, Kong Qingquan, Feng Wei, Xu Zhiping
2022, 43(3): 47-52. doi: 10.7513/j.issn.1004-7638.2022.03.008
Abstract(263) HTML (84) PDF(37)
Abstract:
TiB2/Al composites were fabricated by spark plasma sintering using aluminum powders as matrix and TiB2 particles as reinforcement. The effects of different sintering temperatures (500, 525 ℃ and 550 ℃) on the phase composition, relative density, microhardness and tensile/compressive properties of th...
Study on fabrication and photocatalytic performance of Ag2C2O4/TiO2 heterojunctions
Ren Wang, Li Minjiao, Zhang Ying, Zhang Shulin
2022, 43(3): 53-58. doi: 10.7513/j.issn.1004-7638.2022.03.009
Abstract(253) HTML (45) PDF(31)
Abstract:
In this study, A-TiO2 was prepared by a Sol-Gel method, and then Ag2C2O4 was deposited on the surface of TiO2 to construct Ag2C2O4/TiO2 heterojunctions by a precipitation method. The textural properties, crystal structures and light response capacity were studied by Brunauer-Emmett-Teller (BET) meth...
Research on microstructure and mechanical properties of Ti(C0.5N0.5) particle reinforced Ti matrix composites
Han Wei, Jiang Zhongtao, Yang Xin, Jing Xiaolong
2022, 43(3): 59-64. doi: 10.7513/j.issn.1004-7638.2022.03.010
Abstract(282) HTML (51) PDF(23)
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Using pure Ti powder and Ti(C0.5N0.5) particles as raw materials, Ti(C0.5N0.5) particle reinforced Ti matrix composites were prepared by powder metallurgy process. The effects of Ti(C0.5N0.5) content on the microstructure and mechanical properties of titanium matrix composites were studied. The resu...
Research on application performance of titanium dioxide in ink
Yu Yaojie, Song Yue, Dong Shishun, Ren Xiulian, Wei Qifeng
2022, 43(3): 65-70. doi: 10.7513/j.issn.1004-7638.2022.03.011
Abstract(332) HTML (54) PDF(38)
Abstract:
In this paper, the application performance of titanium dioxide in ink was studied. Through the process of grinding, dispersing and inorganic coating of titanium dioxide crude products under different conditions, the study of pigment performance and application performance of ink was carried out, the...
Study on the microstructure and mechanical properties of the automotive titanium alloy based on friction stir processing
Li Shasha, Wang Lei, Lv Xinrui, Yu Lili
2022, 43(3): 71-76. doi: 10.7513/j.issn.1004-7638.2022.03.012
Abstract(188) HTML (36) PDF(24)
Abstract:
In this investigation, the friction stir processing (FSP) method was used to modify the surface layer of an as-cast Ti8LC automotive titanium alloy using different spindle rotation speeds and travel speeds. In addition, the microstructure and mechanical properties of the alloy samples were tested an...
Mining & Beneficiation
Experimental study on optimization of flotation reagents for ilmenite froman iron dressing tailing in Panxi area
Deng Jian, Yang Yaohui, Wang Hongbin, Yan Weiping, Zeng Xiaobo
2022, 43(3): 77-83. doi: 10.7513/j.issn.1004-7638.2022.03.013
Abstract(337) HTML (106) PDF(35)
Abstract:
In this paper, the optimization test of ilmenite flotation reagents was carried out for an iron dressing tailing in Panxi. With a TiO2 grade of 16.6%, this tailing is mainly composed of ilmenite, titanomagnetite, pyroxene and olivine, and the secondary minerals are plagioclase and chlorite. The type...
Study on the difference of iron separation between Indonesian beach placer and Panxi vanadium-titanium magnetite
Wang Hongbin, Liu Zhixiong, Zhu Yongtao, Chen Bi, Zhang Wang
2022, 43(3): 84-90. doi: 10.7513/j.issn.1004-7638.2022.03.014
Abstract(320) HTML (55) PDF(50)
Abstract:
An experimental study on iron separation of Indonesian beach placer and Panxi vanadium titanomagnetite was carried out by comparing the dry-cast tailings of a vanadium titanomagnetite from Panxi. The results show that the technological process of iron separation for Indonesian beach placer is simple...
Experimental study on comprehensive recovery of a beach placer ore abroad
Liang Taomao, Yang Zhaojun, Zhong Senlin, Hong Qiuyang, Wu Chengcai, Wang Fengyu, Zhang Chaoda
2022, 43(3): 91-97. doi: 10.7513/j.issn.1004-7638.2022.03.015
Abstract(212) HTML (33) PDF(28)
Abstract:
There is a beach placer ore abroad, which is rich in ilmenite, zircon, monazite and other valuable minerals. Oxidation alteration of ilmenite and some contaminated zircon surface with iron change the magnetic and electrical properties of the minerals, which makes it difficult to separate. In view of...
Experimental study on beneficiation of a foreign primary ilmenite ore
Zhong Senlin, Xie Baohua, Wang Fengyu, Liang Taomao, Zhang Chaoda
2022, 43(3): 98-103. doi: 10.7513/j.issn.1004-7638.2022.03.016
Abstract(239) HTML (67) PDF(46)
Abstract:
A primary ilmenite ore from overseas has a TiO2 grade of 8.23% and a Fe2O3 grade of 16.47%. The mainly titanium-containing minerals contain ilmenite, a small amount of rutile and sphene, and a trace amount of titanium-containing magnetite. The gangue minerals are mainly hornblende and feldspar, foll...
Research and industrial practice on improving quality and reducing impurities of Baima vanadium-titanium magnetite
Liu Zhixiong
2022, 43(3): 104-110. doi: 10.7513/j.issn.1004-7638.2022.03.017
Abstract(226) HTML (44) PDF(41)
Abstract:
In order to further improve the grade of vanadium-titanium-iron concentrate and realize the policy of blast furnace concentrate, the process mineralogy of vanadium-titanium magnetite concentrate produced by a concentrator in Baima mining area of Panxi was studied. It is pointed out that the presence...
Study on beneficiation process of a low grade ilmenite in Panxi
Yang Daoguang
2022, 43(3): 111-117. doi: 10.7513/j.issn.1004-7638.2022.03.018
Abstract(651) HTML (293) PDF(52)
Abstract:
The TiO2 content of a low grade ilmenite in Panxi is 6.15% and its mineral composition is complex. In order to fully recover ilmenite, mineral processing experiments were carried out. According to the occurrence state and particle size distribution characteristics of titanium, the combined technolog...
Ferrous Metallurgy and Materials
Study on high temperature properties and optimal ore blending of Pangang iron ore powder
Hu Peng, Tang Wenbo, Huang Chu, Rao Jiating, Yang Mingrui
2022, 43(3): 118-124. doi: 10.7513/j.issn.1004-7638.2022.03.019
Abstract(442) HTML (119) PDF(46)
Abstract:
The results from micro sintering test on high temperature properties of Pangang iron ore power show that the assimilation temperature of high V-Ti magnetite used in Pangang exceeds 1 320 ℃, while the liquid phase fluidity index is only 0.1 and the bonding phase strength is greater than 3 500 N. It i...
Microstructure and hardenability of vanadium microalloyed high temperature carburized SCM420H gear steel
Liu Nianfu, Hu Tao, Tian Qianren, Wang Gaofeng, Fu Jianxun
2022, 43(3): 125-131. doi: 10.7513/j.issn.1004-7638.2022.03.020
Abstract(378) HTML (99) PDF(44)
Abstract:
The high-temperature carburized SCM420H gear steel was modified with vanadium microalloying, and the structure and hardenability of the steel were studied. The results show that the V and N contents in SCM420H gear steel should be controlled within the range of 0.03%~0.05% and 0.012%~0.018%, respect...
Investigation on the effects of V and Ti on continuous cooling transformation behaviour of weathering steel
Cui Kaiyu, Li Zhengrong, Zhao Zhengzhi, Ye Xiaoyu, Wang Chuangwei, Zhang Kaihua, Hu Yunfeng, Xiong Xuegang
2022, 43(3): 132-138. doi: 10.7513/j.issn.1004-7638.2022.03.021
Abstract(266) HTML (52) PDF(24)
Abstract:
Continuous cooling transformation thermal simulation experiment of weathering steel with various V or Ti contents was conducted, and effects of cooling rate and V or Ti element on microstructure transformation and property of weathering steel were investigated. When V content increases from 0.03% to...
Effect of titanium content on the microstructure and mechanical properties of 0.17C-0.30Si-1.40Mn steel
Liu Yangchun, Bai Fengxia, Xu Bin, Zhang Yunhe, Li Bei, Zhang Shilong
2022, 43(3): 139-145. doi: 10.7513/j.issn.1004-7638.2022.03.022
Abstract(216) HTML (88) PDF(24)
Abstract:
0.17C-0.30Si-1.40Mn steels with different titanium contents were prepared by smelting process. After hot rolling into hot-rolled coils, samples were taken for mechanical property test and metallographic structure inspection. Thin-film samples were made by the carbon replica extraction method for tra...
Influence of vanadium-microalloying on microstructure and property of 5CrNiMo die steel
Zhang Yuping, Wei Guangzhen, Wang Menghan
2022, 43(3): 146-151. doi: 10.7513/j.issn.1004-7638.2022.03.023
Abstract(309) HTML (59) PDF(24)
Abstract:
5CrNiMoVx (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) with different vanadium contents were prepared by adding different amounts of alloying element vanadium into the 5CrNiMoV die steel. The microstructure of the sample was analyzed by optical and scanning electron microscopes, and the hot cracking resistance ...
Thermodynamic study on effect of TiO2 addition on Al and Ti distribution during electroslag remelting of Incoloy825
Ju Jiantao, Wang Huayong, Zhu Zhihong, Yang Kangshuai, Gu Yue
2022, 43(3): 152-160. doi: 10.7513/j.issn.1004-7638.2022.03.024
Abstract(224) HTML (50) PDF(29)
Abstract:
To investigate the variation of elements in ingots produced by electroslag remelting in low-fluorine slag system, based on Incoloy825 different contents of TiO2 and deoxidizer were added into slag to carry out four sets of electroslag remelting experiments. A thermodynamic model was established base...
Study of carbide evolution in a 6Cr13Mo stainless steel
Song Lingxi, Zheng Huaibei, Yang Yaguang, Wang Yinghu
2022, 43(3): 161-166. doi: 10.7513/j.issn.1004-7638.2022.03.025
Abstract(319) HTML (66) PDF(19)
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Thermo-Calc thermodynamic software was used to calculate the phase diagram of 6Cr13Mo stainless steel. The heating, cooling, and solidification processes of 6Cr13Mo stainless steel were simulated via an ultra-high temperature confocal microscope, and the evolution of carbide was observed and analyze...
Evolution of inclusions in IF steel during continuous casting process
Hao Xiaoshuai, Bai Xuefeng, Sun Yanhui, Guo Zhijie, Zeng Jianhua, Zhang Min, Wu Chenhui
2022, 43(3): 167-175. doi: 10.7513/j.issn.1004-7638.2022.03.026
Abstract(228) HTML (141) PDF(34)
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The evolution of inclusions in steel of the continuous casting process of IF steel produced by a plant was studied by systematically sampling including molten steel and casting billet. The methods of analysis mainly include analysis of total oxygen and nitrogen content, ASPEX scanning electron micro...
Research on multi-condition synchronous heating of titanium billet in large billet heating furnace
Guo Hong
2022, 43(3): 176-184. doi: 10.7513/j.issn.1004-7638.2022.03.027
Abstract(270) HTML (40) PDF(24)
Abstract:
Titanium is widely used in national defense and civil fields due to its various excellent properties. In order to continuously produce large coils of heavy titanium strip with high efficiency and low cost, conventional hot tandem rolling production lines for co-linear production of titanium, titaniu...
Effect of tempering time on hydrogen embrittlement sensitivity of martensitic steel
Ye Gaoqi
2022, 43(3): 185-190. doi: 10.7513/j.issn.1004-7638.2022.03.028
Abstract(228) HTML (61) PDF(33)
Abstract:
The effect of annealing time on the hydrogen embrittlement sensitivity of martensitic steel was studied by slow strain rate tensile and hydrogen permeation tests. The results show that the hydrogen embrittlement sensitivity decreases first and then increases with the extension of tempering time. Whe...
Research and development of low-cost light gauge L485M pipeline steel
Xu Haijian, Guo Cheng, Gao Hong, Ren Yi, Qiao Xin, Sha Xiaochun
2022, 43(3): 191-196. doi: 10.7513/j.issn.1004-7638.2022.03.029
Abstract(212) HTML (40) PDF(21)
Abstract:
Effects of heating temperature, rolling process, and cooling rates on microstructure variation and mechanical properties for low-cost L485M were studied. The results show that the austenite grains grow continuously with increasing temperatures. The average austenite grains can be controlled within 5...