2022 Vol. 43, No. 1

Separating and Extracting of Vanadium and Titanium
Thermolysis preparation of monoclinic phase vanadium dioxide with ultrafine particles under an inert gas atmosphere
Yin Xianglu, Zeng Zehua, Gao Rongrong, Dai Yu, Teng Aijun
2022, 43(1): 1-6. doi: 10.7513/j.issn.1004-7638.2022.01.001
Abstract(554) HTML (140) PDF(92)
Abstract:
M-phase vanadium dioxide (VO2) is a major thermally induced phase change material with a phase change temperature of 68 ℃. Due to obvious changes in physical and chemical properties before and after the phase change, M-phase VO2 can be widely used in the fields of phase change energy saving and sens...
Study on sodium roasting kinetics of vanadium removal slag of titanium tetrachloride
Du Weitong, Jiang Congxiang, Zheng Ruiqi, Chen Zhuo, Ju Dianchun
2022, 43(1): 7-12. doi: 10.7513/j.issn.1004-7638.2022.01.002
Abstract(484) HTML (79) PDF(188)
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Based on non-isothermal thermogravimetric analysis, the influences of Na2CO3 addition and heating rate on oxidation of vanadium removal slag of titanium tetrachloride (vanadium-containing tailings) were studied. The Kissinger-Akahira-Sunose (KAS) method was used to calculate the activation energy an...
Experimental study on the acidolysis reaction of low-grade titanium slag
Li Kaimao, Wang Haibo, Xiao Jun
2022, 43(1): 13-18, 98. doi: 10.7513/j.issn.1004-7638.2022.01.003
Abstract(299) HTML (38) PDF(38)
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Regarding the problem that low acidolysis rate occurs frequently at the beginning of the experiment in low-grade titanium slag, an investigation was proposed to elaborate the relationship among the phase composition, acidolysis temperature curve, and standard heat of reaction for the chemical reacti...
Research progress on removal of manganese from acidic vanadium solution
Zhang Juhua, Liang Yue, Chang Yuwei, Hui Xujie
2022, 43(1): 19-27. doi: 10.7513/j.issn.1004-7638.2022.01.004
Abstract(412) HTML (109) PDF(68)
Abstract:
Calcification roasting-acid immersion is a very promising clean process for vanadium extraction, but the resultant acidic vanadium solution contains a higher content of manganese, which seriously affects the quality and application of vanadium products. Thus the removal of manganese from the acidic ...
Exploration of roasting vanadium extraction from vanadium slag and Na2O2
Shao Shengqi, Yue Hongrui, Cao Xiaozhou, Cheng Gongjin, Liu Jianxing, Xue Xiangxin
2022, 43(1): 28-35. doi: 10.7513/j.issn.1004-7638.2022.01.005
Abstract(567) HTML (185) PDF(57)
Abstract:
Vanadium slag and sodium peroxide (Na2O2) were mixed, briquetted, roasted, and leached to rich vanadium into V2O5. The effects of roasting temperature, briquetting pressure, roasting time, Na2O2 content, and leaching temperature on the vanadium leaching rate were studied. The results showed that the...
Source analysis and control technology of impurity Al in titanium sponge
Duo Yunxia, Wang Lijuan, Li Yi, Wei Zhizhong
2022, 43(1): 36-39. doi: 10.7513/j.issn.1004-7638.2022.01.006
Abstract(350) HTML (58) PDF(54)
Abstract:
The sources of impurity Al in titanium sponge produced by the Kroll process were analyzed. The impurity Al is mainly derived from titanium tetrachloride and magnesium. Based on the source analysis of Al in titanium tetrachloride, water vapor was introduced for Al removal from titanium tetrachloride ...
Application of Vanadium and Titanium
Effect of Si on microstructure and mechanical properties of (Ti5Si3 + TiBw)/TC11
Zhong Liang, Fu Yu, Wang Yinyang, Han Jungang, Cao Zhaoxun, Song Yunkun, Li Lei, Xu Yongdong
2022, 43(1): 40-47. doi: 10.7513/j.issn.1004-7638.2022.01.007
Abstract(594) HTML (176) PDF(32)
Abstract:
The in-situ formed (Ti5Si3 + TiBw)/TC11 composites with network structure were prepared by powder metallurgy. The metallographic structure, microstructure, mechanical properties and fracture surface of (Ti5Si3 + TiBw)/TC11 were analyzed. The results show that TiBw and partial Ti5Si3 distribute aroun...
Influence of heat treatment on microstructure and mechanical properties of ZTC4 titanium alloy
Ran Xing, Wang Zhe, Lv Zhigang, Cao Jian, Chen Yao, Yang Chaorong, Li Peijie
2022, 43(1): 48-52. doi: 10.7513/j.issn.1004-7638.2022.01.008
Abstract(412) HTML (135) PDF(56)
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The optical microscope (OM) was employed to investigate the influence of heat treatment on microstructure evolution of ZTC4 titanium alloy, and the relationship between microstructure and mechanical properties was discussed. The results showed that the ZTC4 titanium alloy casting was composed of mar...
Research progress of weld formation and performance control of thin plate TC4 titanium alloy by laser welding
Yu Hang, Li Junzhao, Zhang Wangcheng, Sun Qingjie
2022, 43(1): 53-66. doi: 10.7513/j.issn.1004-7638.2022.01.009
Abstract(726) HTML (63) PDF(72)
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The research on welding process and weldability of TC4 titanium alloy has been widely concerned at home and abroad. Therefore, this paper mainly reviewed the current research progress of the effect of laser welding process on the geometrical dimensions, microstructure and mechanical properties of th...
Effect of P on catalytic performances of V-Mo/Ti denitration catalyst
Huang Li, Wang Hu, Zong Yuhao, Chang Zhengfeng, Gao Yibo, Li Jinke, Yu Yang
2022, 43(1): 67-73. doi: 10.7513/j.issn.1004-7638.2022.01.010
Abstract(400) HTML (100) PDF(43)
Abstract:
Industrial V-Mo/Ti denitration catalyst was modified by phosphorus (P) via impregnation method to enhance the catalytic performances. The catalyst was characterized by XRD, N2 adsorption and desorption, XPS, H2-TPR and UV-vis. The denitration activities of the catalyst were tested on a fixed-bed mic...
Photocatalytic process optimization study of vanadium and nitrogen co-doped Ti-bearing blast furnace slag
Huo Hongying, Tong Yanwei
2022, 43(1): 74-79. doi: 10.7513/j.issn.1004-7638.2022.01.011
Abstract(422) HTML (94) PDF(26)
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The characteristics of the photocatalysts can be prepared using Ti-bearing blast furnace slag containing TiO2 to realize Ti-bearing blast furnace slag′s high added value and reasonable comprehensive utilization. Photocatalytic material derived from vanadium and nitrogen co-doped Ti-bearing blast fur...
Influence of forging equipment on microstructure and mechanical properties of TA15 titanium alloy
Wang Zhe, He Jian, Zhang Shuai, Liu Chengcheng, Guo Minghui
2022, 43(1): 80-84. doi: 10.7513/j.issn.1004-7638.2022.01.012
Abstract(200) HTML (57) PDF(29)
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Deform software were employed to simulate hydraulic press and hammer press forging processes of TA15 titanium alloy, and two kinds of forging equipment were used to produce TA15 titanium alloy forgings. The results show that when hydraulic module of deform software is used to deform TA15 titanium al...
Resources Environment and Energy Saving
Study on the photocatalytic degradation of disinfection by-product TCM in drinking water by Fe3+/GO-TiO2 thin films
Li Yufei, Liu Yu
2022, 43(1): 85-90. doi: 10.7513/j.issn.1004-7638.2022.01.013
Abstract(295) HTML (88) PDF(32)
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This paper used the sol-gel method to prepare Fe3+ doped GO-TiO2 films with different proportions on glass substrates. The samples were characterized by X-ray diffraction (XRD) and ultraviolet-visible spectrometer (UV-Vis). The photocatalytic degradation of TCM was irradiated under a UV lamp with a ...
Enhancement of leaching of Ca from steelmaking slag by ultrasonic for CO2 mineral sequestration
Liu Jianping, Chen Lin, Yuwen Chao, Liu Bingguo, Guo Shenghui
2022, 43(1): 91-98. doi: 10.7513/j.issn.1004-7638.2022.01.014
Abstract(266) HTML (66) PDF(36)
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Steelmaking slags containing large amounts of Ca silicate is a potentially alkaline waste that can be used to capture CO2 to synthesize high-quality CaCO3. Here, effect of ultrasonic on leaching efficiency and selective leaching rate of Ca in steelmaking slags was studied in acetic acid solution. Ex...
Study on preparation of silicon vanadium alloy by direct smelting of corundum slag with low vanadium content
Li Liang
2022, 43(1): 99-104. doi: 10.7513/j.issn.1004-7638.2022.01.015
Abstract(208) HTML (48) PDF(30)
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Corundum slag is a solid waste produced in smelting 50 or 80 vanadium iron by thermite process. In order to improve the utilization value of corundum slag, the primary raw materials in this investigation were corundum slag, ferrosilicate, limestone, calcium carbide and sodium carbonate, respectively...
Failure mechanism and numerical simulation of High titanium heavy slag concrete
Wang Hao, Li Xiaowei, Wang Jun
2022, 43(1): 105-112. doi: 10.7513/j.issn.1004-7638.2022.01.016
Abstract(337) HTML (100) PDF(29)
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The mix proportion of high titanium heavy slag concrete (HTHS) and normal concrete was designed. Four groups of concrete cubic and prism specimens were made and tested. Using the PFC discrete element software, the meso-structure mechanical parameters of HTHS and normal concrete specimen were calibra...
Ferrous Metallurgy and Materials
Experimental study on reduction of vanadium-titanium magnetite with hydrogen and biomass
Yuan Yipang, Zhou Yuqing, Hong Lukuo, Li Yaqiang, Ai Liqun, Liu Zehua, Lei Yue
2022, 43(1): 113-118. doi: 10.7513/j.issn.1004-7638.2022.01.017
Abstract(325) HTML (62) PDF(50)
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Vanadium-titanium magnetite has its unique characteristics like containing many valuable elements, complex phase structure and close intergrowth of iron and titanium, as well as the difficulty of full comprehensive utilization. In this paper, the phase change of vanadium-titanium magnetite reacted w...
Study on microstructure and properties of low-alloy steel fabricated by laser wire-feed additive manufacturing
Liu Xuming, Zhang Dayue, Zhang Jian, Li Binzhou, Zhao Yang, Wang Junsheng
2022, 43(1): 119-124. doi: 10.7513/j.issn.1004-7638.2022.01.018
Abstract(256) HTML (63) PDF(37)
Abstract:
In this investigation, the low-alloy steel wire applied in additive manufacturing was made by clean steelmaking, hot rolling and drawing; subsequently, laser wire-feed additive manufacturing was carried out with this steel wire. The mechanical properties of the 3D printed parts are the yield strengt...
Numerical model of collision aggregation and remove of inclusions after aluminum deoxidization in RH reactor
Hao Jiujiu
2022, 43(1): 125-130. doi: 10.7513/j.issn.1004-7638.2022.01.019
Abstract(197) HTML (33) PDF(38)
Abstract:
Based on the classical model of collision aggregation of inclusions, the growth mode of exponential increase of inclusions is used to establish the numerical model of reaction of aluminum and oxygen, collision and aggregation of inclusions, remove of inclusions, for the purpose of predicating the ma...
Study on the effect of electromagnetic stirring of mold on the removal of non-metallic inclusions in billet
Wang Yong
2022, 43(1): 131-134, 151. doi: 10.7513/j.issn.1004-7638.2022.01.020
Abstract(273) HTML (73) PDF(34)
Abstract:
Based on the principle that electromagnetic force affects the distribution of non-metallic inclusions and the velocity of particles in molten metal, the effect of electromagnetic stirring in mold on the removal of non-metallic inclusions in billet was studied. The inclusion separation and removal ex...
Review on development of metal solidification process under vibration
Yang Bao, Zhang Hui, Wang Minglin, Zhao Wenbo, Liu Bin, Liu Shuai
2022, 43(1): 135-144. doi: 10.7513/j.issn.1004-7638.2022.01.021
Abstract(427) HTML (52) PDF(39)
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The development of vibration introduced into the metal solidification process was reviewed and the vibration methods, application fields, metallurgical effects, and advantages/disadvantages of mechanical vibration technology, vibration excitation nucleation technology, ultrasonic vibration technolog...
Effect of high temperature and high strain rate on the dynamic mechanical properties of 06Cr19Ni10 austenitic stainless steel
Zhang Jilin, Jia Haishen, Yi Xiangbin, Dou Jianming, Tang Linhu, Qin Juanjuan, Xu Chuangwen
2022, 43(1): 145-151. doi: 10.7513/j.issn.1004-7638.2022.01.022
Abstract(442) HTML (129) PDF(51)
Abstract:
The dynamic mechanical properties of austenitic stainless steel 06Cr19Ni10 were studied by a high temperature split-Hopkinson pressure bar (SHPB) at temperatures of 25–300 ℃ and strain rates of 1000–3000 s−1. The austenitic stainless steel 06Cr19Ni10 shows strain rate strengthening effect in the ran...
Process parameter optimization of 1725/WC composite coating on cast iron surface by laser cladding
Yang Haili, Zhou Haikuan, Zhang Kaiyi
2022, 43(1): 152-157. doi: 10.7513/j.issn.1004-7638.2022.01.023
Abstract(291) HTML (93) PDF(41)
Abstract:
1725/WC composite coatings were prepared on the surface of cast iron by laser cladding. The effects of process parameters including laser power, scanning speed and powder feed rate on dilution ratio and hardness of the cladding coating were studied through orthogonal experiments. The results showed ...
Effect of Ti treatment process on inclusions in steel
Xiao Aida, Zheng Qing, Liang Liang, Zhou Jianfeng, Xie Shizheng, Wang Bo, Zhang Bo, Liu Chunquan
2022, 43(1): 158-164. doi: 10.7513/j.issn.1004-7638.2022.01.024
Abstract(333) HTML (48) PDF(57)
Abstract:
In this work, the influence of Ti treatment on inclusions in steel and the formation conditions and evolution process of Ti oxide inclusions were studied by a combination of simulation calculation and experiment. The results show that at 1 600 ℃, when the content of [O] in steel is greater than 22×1...
Effect of SO42− concentration on corrosion damage of 304 stainless steel in Cl solution
Su Jianwen, Dong Xiaoping, Gao Tengyuan, Zhang Zhaoqing, Sun Zhenduo, Su Dandan
2022, 43(1): 165-173. doi: 10.7513/j.issn.1004-7638.2022.01.025
Abstract(368) HTML (153) PDF(30)
Abstract:
In order to investigate the effect of SO42− on the corrosion damage of 304 stainless steel in a solution containing 0.7 mol/L Cl, acoustic emission technology and morphology observation technology were used to test the acoustic signal generated during the corrosion process and the surface morpholog...
Influence of rare earth modifier on the nonmetallic inclusion morphology and size distribution about hot stamping
Yang Li, Sun Yaping, Li Yongliang, Chen Tong, Sun Tianhao
2022, 43(1): 174-179. doi: 10.7513/j.issn.1004-7638.2022.01.026
Abstract(344) HTML (119) PDF(12)
Abstract:
The influence of rare earth modifier on nonmetallic inclusion morphology and size distribution of 1500 MPa grade hot stamping steel were investigated by optical microscope and scanning electron microscope. And the microstructure and plastic property of resulted steel at room temperature were compare...
Study on microstructure and properties of new titanium bearing high strength building steel
Yang Ming, Liu Fang, Chen Jiuquan, Zhao Lixia
2022, 43(1): 180-184. doi: 10.7513/j.issn.1004-7638.2022.01.027
Abstract(217) HTML (35) PDF(20)
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In this paper, the microstructure, corrosion resistance and wear resistance of Fe-Si-Mn-C-Ti high-strength building steel with different titanium content were tested and analyzed. The results show that the addition of alloy element titanium is helpful to refine the internal structure and improve the...
Analysis and control strategy of bending force saturation for HC tandem cold mill
Zhou Yilin
2022, 43(1): 185-189, 196. doi: 10.7513/j.issn.1004-7638.2022.01.028
Abstract(202) HTML (76) PDF(23)
Abstract:
The work roll bending force of the last stand of the four stands 6-Hi HC tandem cold rolling mill is usually in saturation state when the brightwork roll is used in the last stand. This production phenomenon leads to the lack of the ability to control the strip shape, and then the shape defects are ...
Analysis on surface crack defects of SAE1144 free-cutting octagonal steel bar
Wang Gaofeng, Zhong Liangmei, Zhou Nan, Zhang Zhiming, Fu Jianxun
2022, 43(1): 190-196. doi: 10.7513/j.issn.1004-7638.2022.01.029
Abstract(265) HTML (149) PDF(39)
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The surface crack area of SAE1144 free cutting steel during cold drawing from 18 mm round bar to 15 mm octagonal bar was studied by means of optical microscope, sample electrolysis, SEM+EDS and ImageJ software. The results show that there exist large granular MnS inclusions, elongated strip cluster ...