2020 Vol. 41, No. 6

Separating and Extracting of Vanadium and Titanium
Recovery of Titanium from Spent SCR Catalyst by Sodium Roasting
Jia Xiumin, Chen Tianbao, Huang Yong, Liu Huiwu, Liu Zhongchen, Li Peiyou, Xiang Qiulin
2020, 41(6): 1-5. doi: 10.7513/j.issn.1004-7638.2020.06.001
Abstract(103) PDF(3)
Abstract:
Titanium was recovered from spent SCR catalyst by sodium roasting.The effects of sodium dosage,roasting temperature,roasting time,material particle size and sulfuric acid concentration on titanium leaching rate were studied.From the experimental results,the optimum roasting conditions were selected ...
Leaching Kinetics of Ilmenite in Sulfuric Acid Solution
Wang Haibo, Wu Xiaoping, Gao Jian, Wang Bin, Cheng Xiaozhe
2020, 41(6): 6-10. doi: 10.7513/j.issn.1004-7638.2020.06.002
Abstract(219) PDF(22)
Abstract:
Using Panzhihua ilmenite and sulfuric acid as raw materials,the leaching kinetics of the ilmenite in sulfuric acid was studied,and the ilmenite coupled with the leaching residue was characterized by SEM,mineral analyzer and XRD.The research results show that at the reaction temperature of 83 ~ 111 ℃...
Study on Reducing the Loss of Titanium Liquid Entrained in Ferrous Sulfate Filter Cake
Zheng Chenggang, Liu Juexin, Ye Shichao
2020, 41(6): 11-15. doi: 10.7513/j.issn.1004-7638.2020.06.003
Abstract(124) PDF(3)
Abstract:
Adopting the technical route of experimental research combined with the industrial production,this paper determined the solubility of ferrous sulfate in water to explore its crystallization kinetics characteristics and investigate the filter cake liquid content with different crystal sizes.Simulatio...
Deoxidization Technology for Aerospace Grade Vanadium Aluminum Alloy
Chen Haijun, Shi Qihua, Yin Danfeng, Gao Leizhang
2020, 41(6): 16-20. doi: 10.7513/j.issn.1004-7638.2020.06.004
Abstract(117) PDF(6)
Abstract:
The oxygen content in aerospace-grade vanadium aluminum alloy has an important effect on the properties of downstream titanium alloy materials.Aiming at the problem of high oxygen content in vanadium aluminum alloy prepared by aluminothermic smelting,the occurrence state of oxygen in V-Al alloys was...
Production Technology of Upscale FeV50 Alloy
Li Dongming, Yu Jiyang, Jia Ligen, Wang Fang, Lu Yongjie, Qin Yunquan
2020, 41(6): 21-25. doi: 10.7513/j.issn.1004-7638.2020.06.005
Abstract(123) PDF(1)
Abstract:
Based on the electro-aluminothermic process for FeV50 alloy production,the influencing factors on Al and P content in FeV50 alloy and the causes of the oxidation surface of the alloy were analyzed.The technical parameters for production of upscale FeV50,with w(Al) ≤ 1.0%,w(P) <0.06% and without o...
Preparation of NH4VO3 by Carbonation Leaching of Calcium Vanadate
Fu Zibi
2020, 41(6): 26-29,34. doi: 10.7513/j.issn.1004-7638.2020.06.006
Abstract(154) PDF(11)
Abstract:
In view of the problems of high Na/V ratio and low vanadium concentration of carbonation leaching solution of calcium vanadate,a new method of preparing ammonium metavanadate by mixed leaching of sodium bicarbonate and ammonium bicarbonate was proposed.The effects of the leaching agent compositions,...
Application of Vanadium and Titanium
Effect of Zn on Catalytic Performances of Industrial V-Mo/Ti De-NOx Catalyst
Zong Yuhao, Huang Li, Chang Zhengfeng, Wang Hu, Zhou Jun, Li Jinke
2020, 41(6): 30-34. doi: 10.7513/j.issn.1004-7638.2020.06.007
Abstract(114) PDF(1)
Abstract:
Different contents of Zn was loaded on V-Mo/Ti catalyst by impregnation method,and the activity of selective catalytic reduction of NO by NH3 was evaluated.The catalysts were characterized by XRD,N2 adsorption-desorption,NH3-TPD,H2-TPR and NO-TPD.The results show that Zn loading does not change the ...
Preparation of Non-stoichiometric Titanium Dioxide/Carbon Nanofiber Electrode and Its Performance for Supercapacitor
Ren Yaqi, Lü Yiying, Li Xi, Wang Rui
2020, 41(6): 35-39. doi: 10.7513/j.issn.1004-7638.2020.06.008
Abstract(107) PDF(1)
Abstract:
An integrated non-stoichiometric titanium dioxide/carbon nanofiber electrode was prepared by electrospinning-impregnating-calcination method and used for supercapacitor.Fine TiO2 nanoparticles were anchored onto the surface of carbon nanofiber substrate with the diameter of 80~100 nm.And non-stoichi...
Effect of Stirring Rate on Corrosion Resistance of Ni-Sn/TiO2 Composite Coating Prepared by Electrodeposition
Cui Pengfei, Zhang Kaiyi, Zhou Zongyi, Li Yungang, Yang Haili
2020, 41(6): 40-44. doi: 10.7513/j.issn.1004-7638.2020.06.009
Abstract(114) PDF(4)
Abstract:
The Ni-Sn/TiO2 composite coatings were prepared by electrodeposition. The effects of stirring rate on surface morphology,composition and corrosion resistance of Ni-Sn/TiO2 composite coatings were studied by scanning electron microscopy,energy dispersive spectroscopy,Tafel curve and electrochemical i...
Hollow 3D rGO/P-HC/TiO2 for Photocatalytic Degradation of Ammonia Nitrogen
Wang Min, Xia Lixin, Lin Qingxian
2020, 41(6): 45-51. doi: 10.7513/j.issn.1004-7638.2020.06.010
Abstract(111) PDF(5)
Abstract:
In this work,a series of catalyst were successfully fabricated via hydrothermal method,which were used as efficient UV light photocatalytic degradation of ammonia nitrogen from aqueous solution.The surface properties of the catalysts were characterized by scanning electron microscope(SEM),X-ray diff...
Preparation of High Temperature Sensible Heat Storage Material from Vanadium Extraction Tailings and Graphite
Po Rongxun, Li Xuan, Li Guowei, Zhao Junquan, Luo Weidong, Deng Liyun, Guo Anfen
2020, 41(6): 52-59. doi: 10.7513/j.issn.1004-7638.2020.06.011
Abstract(86) PDF(1)
Abstract:
The high temperature sensible heat storage material was prepared via powder metallurgy method,using the iron extraction tailing obtained by carbothermal reduction of the vanadium extraction tailing as the raw material and graphite as the modifier respectively.XRD results show that the main phases of...
Performance Optimization of Negative Electrode Material for Vanadium-based Nickel Metal Hydride Battery Based on Neural Network Algorithm
Wang Hong, Wang Qunqun
2020, 41(6): 60-65. doi: 10.7513/j.issn.1004-7638.2020.06.012
Abstract(94) PDF(1)
Abstract:
The neural network model with 6×36×12×1 four-layer topological structure was used to optimize the performances of the negative electrode material of vanadium based hydrogen storage battery.The input layer parameters were titanium content,nickel content,aluminum content,chromium content,holding tempe...
Resources Environment and Energy Saving
Beneficiation of a Vanadium-titanium Magnetite in Panxi
Li Jinlin, Li Weiwei, Zhu Yongtao, Wu Xuehong
2020, 41(6): 66-73. doi: 10.7513/j.issn.1004-7638.2020.06.013
Abstract(186) PDF(8)
Abstract:
Taking a vanadium-titanium magnetite in Panxi as the research object,a beneficiation test was carried out for the titanium magnetite and ilmenite.The titanium magnetite was recovered by the process of pre-throwing tailings followed by two-stage grinding and magnetic separation,and the iron concentra...
Mineral Processing Test on Olivine Type of Vanadium-titanium Magnetite in Panxi Hongge Area
Chen Tao, Hu Zhibo, Chen Cheng, Zheng Yu, Ying Hongwei, Deng Hao
2020, 41(6): 74-80. doi: 10.7513/j.issn.1004-7638.2020.06.014
Abstract(113) PDF(5)
Abstract:
In this paper the olivine type of vanadium-titanium magnetite had been analyzed by X-ray fluorescence spectrum and X-ray diffraction spectrum to identify the raw ore mineral compositions. The main valuable metal elements in raw ore are iron and titanium,thus comprehensive utilization of iron and tit...
Study on Process Mineralogy of Baima Iron Concentrate
Yang Daoguang
2020, 41(6): 81-87. doi: 10.7513/j.issn.1004-7638.2020.06.015
Abstract(76) PDF(4)
Abstract:
Taking the raw ore,concentrate and tailings from Baima concentrate in Panxi zone as the research object,the chemical elements,mineral compositions and monomer dissociation degree of the samples were analyzed by means of chemical analysis and AMICS.The content of titanomagnetite,ilmenite and gangue,t...
Study on Process Mineralogy of a Titanium Magnetite in Ankang Area
Hui Bo, Yang Yaohui, Chen Wei, Deng Bing
2020, 41(6): 88-93,123. doi: 10.7513/j.issn.1004-7638.2020.06.016
Abstract(48) PDF(2)
Abstract:
The process mineralogy characteristics of a titanomagnetite in Ankang region were studied by means of X-ray fluorescence spectrometry(XRF),optical microscope,scanning electron microscope(SEM),X-ray energy spectrum probe(EDS),etc.The chemical analysis results of the crude ore show that the main eleme...
Ferrous Metallurgy and Materials
Experimental Study on Decarburization of Iron-carbon Alloy Sheet under CO-CO2 Atmosphere
Zhou Meijie, Ai Liqun, Hong Lukuo, Hou Yaobin, Zhou Chaogang
2020, 41(6): 94-98. doi: 10.7513/j.issn.1004-7638.2020.06.017
Abstract(64) PDF(1)
Abstract:
In order to study the effect of temperature,holding time and thickness of steel sheet on decarburization of Fe-C alloy sheet in CO-CO2 atmosphere,the experiments were carried out in a weak oxidation atmosphere of Ar-CO-CO2 on 2 mm,1.5 mm and 1 mm thick Fe-C alloy sheet with initial carbon content of...
Industrial Test of Titanium Powder and Pulverized Coal Co-injection
Dong Yafeng, Guo Peimin, Liu Keming, Zhai Dan
2020, 41(6): 99-106. doi: 10.7513/j.issn.1004-7638.2020.06.018
Abstract(67) PDF(1)
Abstract:
Titanium powder and pulverized coal co-injection is the process in which rich titanium powder is mixed with raw coal and injected into blast furnace through tuyeres.The industrial test of titanium powder and pulverized coal co-injection was carried out in a 2 500 m3 blast furnace to verify the pract...
Strengthening Mechanism and Mechanical Behavior of Low Carbon Microalloyed Steel Containing Ti
Guan Jianhui, Zhang Jiming, Sun Lin, Qu Jinbo, Yang Guanlin
2020, 41(6): 107-111. doi: 10.7513/j.issn.1004-7638.2020.06.019
Abstract(272) PDF(3)
Abstract:
Microstructure and strengthening mechanism of low carbon micro-alloyed steel with different contents of titanium were characterized by OM and SEM analysis and tensile and impact testing.With the increase of titanium content,the strength and yield ratio of the tested steel increased,while the elongat...
Study on Thermal Recycling of LF Refining Slag
Li Shujun, Du Xueyan
2020, 41(6): 112-118,134. doi: 10.7513/j.issn.1004-7638.2020.06.020
Abstract(214) PDF(5)
Abstract:
In this paper,ithe thermal recycling of LF furnace refining slag for the production of non-low silicon aluminum killed steel was studied.Slag samples and liquid steel samples were taken from LF refining furnace,and the changes of compositions of liquid steel and quantity density of inclusions in LF ...
Experimental Study on the Effect of Rare Earth on Inclusions in High-sulfur Free-cutting Steel
Fan Lei, Li Chen, Jiang Maofa
2020, 41(6): 119-123. doi: 10.7513/j.issn.1004-7638.2020.06.021
Abstract(118) PDF(2)
Abstract:
In order to explore the effect of rare earth on inclusions in high-sulfur free-cutting steel,the high temperature simulation experiments and thermodynamic analysis were carried out in this work.The results showed that the types of inclusions were MnS and CeAlO3.MnS could precipitate on the surface o...
Study on the Transformation and Precipitation Behavior of Ferrite at Different Positions in High-rise Building Steel
Zheng Feifan, Zhang Caijun, Wu Shaowen, Li Kangkang
2020, 41(6): 124-129. doi: 10.7513/j.issn.1004-7638.2020.06.022
Abstract(75) PDF(2)
Abstract:
The phase transformation and precipitation behavior of acicular ferrite in high-rise construction steel was observed in situ by high temperature laser confocal microscope.According to its nucleation site the ferrite can be classified into crystal interface,grain boundary edge and inclusions.The nucl...
Effect of Annealing Temperature on Microstructure,Mechanical Properties and Retained Austenite of 1 000 MPa Q&P Steel
Lu Qianqian, Gu Hairong, Cui Lei, Xiao Yangyang, Leng Deping
2020, 41(6): 130-134. doi: 10.7513/j.issn.1004-7638.2020.06.023
Abstract(236) PDF(8)
Abstract:
In this work effect of annealing temperature on microstructure,mechanical properties and retained austenite of 1 000 MPa Q&P Steel were studied by means of SEM,EBSD,XRD and tensile test at room temperature.Results showed that the microstructure at room temperature was mainly composed of ferrite(F) +...
Modified Morphology of Mn S Inclusions in Tellurium Treated 303Cu Stainless Steel
Li Jie, Zhu Qiangbin, Tian Qianren, Fan Tian, Xie Jianbo, Fu Jianxun
2020, 41(6): 135-141. doi: 10.7513/j.issn.1004-7638.2020.06.024
Abstract(143) PDF(7)
Abstract:
In order to study the influence of tellurium on the morphology of MnS inclusions in 303Cu freecutting stainless steel,various amount of tellurium was added into 303Cu steel,and then the morphology and distribution of MnS inclusions in steels was analyzed by means of OM,SEM and microelectrolysisdding...
Ca Treatment Effect on the Evolution and Microstructure of Ti Alloyed Inclusions in HG785 Steel
Zhao Huanling
2020, 41(6): 142-150. doi: 10.7513/j.issn.1004-7638.2020.06.025
Abstract(77) PDF(1)
Abstract:
To reveal the inclusion evolution and its influence on the inner microstructures of high strength steel treated by Ti alloying Ca,we used scanning electron microscope and energy dispersive spectroscopy to characterize the inclusion characteristics and its induction to ferrite behaviors.We compared t...
Effect of Inclusions on High Cycle Fatigue Characteristics of Spring Steel
Liu Yong, Tian Zhiqiang, Ma Chao, Zhao Haitao, Chen Hongwei, Ceng Yanan, Feng Qian
2020, 41(6): 151-157. doi: 10.7513/j.issn.1004-7638.2020.06.026
Abstract(190) PDF(7)
Abstract:
In this paper the size and quantity of inclusions in different parts of spring steel slab and steel was determined by using Aspex inclusion automatic scanning electron microscope,and the fatigue properties of the materials were tested using a rotating bending fatigue tester.The rules of the distribu...
Effect of FTSR Hot Rolling Process on Microstructure and Mechanical Properties of 65Mn Strip
Li Xiujing, Wang Shuhua, Zhang Xing, Li Hongwei
2020, 41(6): 158-163. doi: 10.7513/j.issn.1004-7638.2020.06.027
Abstract(121) PDF(5)
Abstract:
Microstructure and mechanical properties of FTSR 65Mn steel strips produced by different hot coiling technologies was investigated,and simulated quenching heat-treatment were carried on. The result shows that ferrite reduces in term of its volume fraction and finically disappears with coiling temper...
Experimental Research on Microstructure and Properties of a 9%Ni-Fe Alloy Laser Cladding Coating
Liu Xiyan, Jiang Wei, Wang Shuqi, Cui Xianghong
2020, 41(6): 164-169. doi: 10.7513/j.issn.1004-7638.2020.06.028
Abstract(93) PDF(1)
Abstract:
In order to improve the hardness and heat resistance stability of H13 steel surface,a 9% Ni-Fe alloy coating was prepared on the surface of H13 steel by laser cladding technology.Microstructure,phase composition,and micro-hardness of the alloy coating and thermal stability was investigated by X-ray ...
Study on the Properties of a New Type of Mechanical Die Steel Containing Titanium
Ding Xiangqin, Ji Shijun
2020, 41(6): 170-174. doi: 10.7513/j.issn.1004-7638.2020.06.029
Abstract(57) PDF(1)
Abstract:
In this paper,a new type of mechanical die steel specimens containing titanium with different titanium contents were prepared,and their wear resistance at room temperature,high temperature wear resistance and high temperature oxidation resistance were tested and analyzed.The results show that with t...
Analysis on Notch Sensitivity of Low Thermal Expansion Superalloys GH2909
Chen Qi
2020, 41(6): 175-180. doi: 10.7513/j.issn.1004-7638.2020.06.030
Abstract(215) PDF(14)
Abstract:
Superalloy GH2909 bars produced by a Chinese supplier present high notch sensitivity during high temperature creep performance test.In order to understand the reason for this issue,the imported and studied GH2909 alloy bars had been compared in terms of their chemical compositions,microstructures an...