2020 Vol. 41, No. 2

Separating and Extracting of Vanadium and Titanium
Synthesis and Mechanism of LiV3O8 Material by Solid Phase Coordination
Liu Jin, Wang Li, Sun Ruimin, Shi Zhaozhong, Zhao Hui, Luo Jing
2020, 41(2): 1-5. doi: 10.7513/j.issn.1004-7638.2020.02.001
Abstract(104) PDF(2)
Abstract:
Layered lithium vanadium oxide LiV3O8 was synthesized by solid phase coordination method,and the reaction mechanism was studied by TG-DTA and XRD.The results show that LiV3O8 with a single phase can be obtained at 550 ℃ of heat treatment temperature for 24 h.The initial discharge capacity of the mat...
Study on Alkali Fusion Process of V-Ti Magnetite Concentrate at Lower Temperature
Hou Yaobin, Hong Lukuo, Sun Caijiao, Ai Liqun
2020, 41(2): 6-13. doi: 10.7513/j.issn.1004-7638.2020.02.002
Abstract(111) PDF(3)
Abstract:
In order to realize the smelting of V-Ti magnetite concentrate at lower temperature,the direct reduction-smelting separation process was studied by coal-based direct reduction technique with NaOH as the alkali fusion agent.Effects of NaOH addition on metallization rate and smelting separation of V-T...
Effects of Hydrolysis Conditions on High Purity TiO2 Preparation from Industrial Low Concentration Titanyl Sulfate Solution
Tian Congxue
2020, 41(2): 14-19. doi: 10.7513/j.issn.1004-7638.2020.02.003
Abstract(200) PDF(12)
Abstract:
High purity TiO2 was prepared via authigenic seed thermal hydrolysis route by using industrial low concentration titanyl sulfate solution as titanium source.The as-prepared metatitanic acid and TiO2 powders were characterized by XRD,particle size distribution,BET analysis and TiO2 content determinat...
Effects of Heating Rate on Pigment Properties of Rutile TiO2
Chen Xinhong, Wang Rongkai, Li Li
2020, 41(2): 20-23,28. doi: 10.7513/j.issn.1004-7638.2020.02.004
Abstract(212) PDF(9)
Abstract:
Using industrial metatitanic acid as raw material,rutile TiO2 was prepared via bleaching,washing,salt treatment and calcination.The effects of heating rate on the crystal structure and pigment properties of titanium dioxide particles were investigated.The samples were characterized by XRD,SEM,laser ...
Effect of Slagging Agent on Quality of V-Al Alloy
Zhang Na, Li Lanjie, Zhang Suxin, Xu Feng, Wan Heli, Wang Haixu, Dai Baoshuang
2020, 41(2): 24-28. doi: 10.7513/j.issn.1004-7638.2020.02.005
Abstract(225) PDF(7)
Abstract:
The effects of types and addition amount of slagging agent on the recovery rate of vanadium(V) and qualification rate of products during vanadium aluminum alloy(V-Al alloy) preparation by electro-aluminothermic process were studied.The results show that during the selected agents of calcium vanadate...
Analysis of Difference between Zinc Salt and Aluminum Salt Treated Titanium Dioxide
Wu Jianchun, Lu Ruifang, Ma Weiping
2020, 41(2): 29-32. doi: 10.7513/j.issn.1004-7638.2020.02.006
Abstract(129) PDF(9)
Abstract:
Using metatitanic acid from titanium white production by sulphate process as the raw material,the aluminum salt and zinc salt were used as salt treatment agents to treat the metatitanic acid,and initial product of titanium white was obtained after calcination.The difference of viscosity and zeta pot...
Application of Vanadium and Titanium
High Temperature Mechanical Properties and Microstructure of TC4 Titanium Alloy Prepared by Selective Laser Melting
Song Jingwen, Fang Minhan, Hu Fuguo, Mao Jianwei
2020, 41(2): 33-37. doi: 10.7513/j.issn.1004-7638.2020.02.007
Abstract(930) PDF(32)
Abstract:
In this paper,the mechanical properties and microstructure of TC4 titanium alloy,prepared by selective laser melting(SLM),at room temperature(RT) to 550 ℃ were studied by universal tensile testing machine,optical microscopy,scanning electron microscopy,and transmission electron microscopy.The result...
Preparation and Properties of Ti-ZrO2 Bilayered Composites with Interfacial Doping Graphene
Xian Yong, Liu Wei, Chen Liming, Ding Yichao, Wang Jing, Liu Yao
2020, 41(2): 38-41. doi: 10.7513/j.issn.1004-7638.2020.02.008
Abstract(125) PDF(3)
Abstract:
Ti-ZrO2 bilayered composite was synthesized by vacuum hot pressing sintering under 1 200 ℃ and 10 MPa through interfacial doping of graphene.The interfacial bonding was characterized by tensile strength.The interfacial phase compositions and element distributions were analyzed by X-ray diffraction(X...
Effect of Mo2C/WC Ratio on Microstructure and Properties of Cermet
Ma Yichuan, Zhang Xuefeng, Chen Min, Zhang Ning
2020, 41(2): 42-47. doi: 10.7513/j.issn.1004-7638.2020.02.009
Abstract(87) PDF(2)
Abstract:
Ti(C,N)-based cermets were prepared by powder metallurgy using TiC,TiN,Mo2C,WC,Co and Ni as raw materials.The effects of Mo2C/(WC+Mo2C) ratio on the microstructure and mechanical properties of Ti(C,N)-based cermets were investigated by XRD,SEM and mechanical properties test.The results show that wit...
Diffusion and Control of Ti/Al Interface in Preparation of Ti/Al Alloy by Cold Rolling
Li Yaoping, Zhang Fuqin
2020, 41(2): 48-53. doi: 10.7513/j.issn.1004-7638.2020.02.010
Abstract(79) PDF(2)
Abstract:
The Al/Ti/Al sheet was prepared by cold rolling and it was annealed under different processes.The morphology of the Ti/Al interface before and after annealing was observed with a scanning electron microscope.The microhardness of the titanium layer was measured with a microhardness,and the growth rul...
Preparation and Properties of Vanadium-titanium-nickel Based Hydrogen Storage Alloys for New Energy Automotive Batteries
Cui Xiajing, Shou Haofang, Su Yuefeng
2020, 41(2): 54-57,81. doi: 10.7513/j.issn.1004-7638.2020.02.011
Abstract(144) PDF(5)
Abstract:
V-25 Ti-10 Ni and V-25 Ti-10 Ni-0.5 Ce alloys for new energy automobile batteries were prepared by self-propagating method,and their microstructures,hydrogen absorption properties and corrosion resistance were tested,compared and analyzed.The results show that the grain of V-25 Ti-10 Ni-0.5 Ce alloy...
Effect of Rolling Process on Microstructure and Properties of TC4 Titanium Alloy Plate
Ren Wanbo
2020, 41(2): 58-62. doi: 10.7513/j.issn.1004-7638.2020.02.012
Abstract(166) PDF(11)
Abstract:
In order to establish and optimize the rolling process of TC4 titanium alloy plate with moderate thickness and develop the TC4 titanium alloy plate with excellent comprehensive mechanical properties,the rolling industrial test of TC4 titanium alloy plate with moderate thickness was carried out in a ...
Resources Environment and Energy Saving
Photocatalytic Performance and Reaction Pathway of TiO2 Composite Materials on Ammonia and Nitrogen Degradation in Water
Wang Yingwei, Li Yufei
2020, 41(2): 63-68. doi: 10.7513/j.issn.1004-7638.2020.02.013
Abstract(219) PDF(7)
Abstract:
The nano-TiO2 composite photocatalysts,i.e.activated carbon supported TiO2(TiO2/AC),Tween-80,Cu2+and Fe3+doped TiO2,were separately prepared by sol-gel method,and the samples were characterized by X-ray powder diffraction(XRD) and ultraviolet-visible spectrometer(UV-VIS).The photocatalytic performan...
Mechanical Properties of High Titanium Heavy Slag Fiber-reinforced Concrete
Yang He, Liang Hezhi, Die Jian, Chen Wei, Wang Wei
2020, 41(2): 69-74. doi: 10.7513/j.issn.1004-7638.2020.02.014
Abstract(202) PDF(3)
Abstract:
Considering the three main factors of fiber content,water-binder ratio and fly ash content,20 sets of high titanium heavy slag fiber-reinforced concrete specimens were designed using orthogonal experiments.The effect of fiber content,water-binder ratio and other factors on mechanical properties of t...
Preparation of Ordinary Portland Cement Clinker from Vanadium-titanium Magnetite Tailing
Yang Fei, Sun Xiaomin
2020, 41(2): 75-81. doi: 10.7513/j.issn.1004-7638.2020.02.015
Abstract(78) PDF(3)
Abstract:
To efficiently utilize the vanadium–titanium magnetite tailing in Chengde area,ordinary portland cement clinker was prepared by high temperature calcination using the tailing,limestone and quartz sand as raw materials.The evolution of phase compositions and microstructure of the cement clinker durin...
Experimental Study on Carbonization Resistance of Concrete Containing Iron Tailings
Sun Qiurong, Liu Lei
2020, 41(2): 82-88. doi: 10.7513/j.issn.1004-7638.2020.02.016
Abstract(88) PDF(2)
Abstract:
The carbonization resistance and mechanical properties of concrete containing iron tailings sand under carbonization environments were investigated in this paper.Three factors including water-binder ratio,iron tailings sand content and binder content were analyzed and discussed by orthogonal tests.T...
Ferrous Metallurgy and Materials
Effect of NaOH on Direct Reduction of Vanadium Titano-magnetite
Wang Xufeng, Hong Lukuo, Sun Caijiao
2020, 41(2): 89-93. doi: 10.7513/j.issn.1004-7638.2020.02.017
Abstract(55) PDF(3)
Abstract:
In order to reduce the direct reduction temperatures of vanadium titano-magnetite and improve the metallization ratio of pellets,sodium-treatment was adopted to the direct reduction of vanadium titano-magnetite.The vanadium titano-magnetite was direct reduced with coal and NaOH,and the influences of...
Influence of TiO2 Content and Basicity Level on the Metallogenic Regularity of V-Ti Sinter
Lin Wenkang, Hu Peng
2020, 41(2): 94-100. doi: 10.7513/j.issn.1004-7638.2020.02.018
Abstract(58) PDF(2)
Abstract:
In order to investigate the influence of different TiO2 content and basicity level on the technical and economic indexes of V-Ti sintering and the metallurgical properties of V-Ti sinter,so as to determine a better sintering and blast furnace material mixture,an experimental study was carried out to...
Deoxidation of Steel by Aluminum-magnesium Alloys and Inclusion Analysis
Gong Hongjun, Yang Xingdi, Li Long, Ge Wensun
2020, 41(2): 101-107. doi: 10.7513/j.issn.1004-7638.2020.02.019
Abstract(154) PDF(4)
Abstract:
In order to solve the common problem of Al2O3 inclusion modification in aluminum deoxidized steel,the deoxidation of steel by Al-Mg alloys was explored and practiced.Al-Mg deoxidation can achieve slightly better result than that of aluminum deoxidization.The oxygen activity after Al-Mg deoxidization...
Effect of TiO2 in Refining Slag on Inclusions in Ti-Ferritic Stainless Steel
Feng Xiaoxia, Wang Qi, Tan Bo, Wang Lijun, Zhou Guozhi
2020, 41(2): 108-113. doi: 10.7513/j.issn.1004-7638.2020.02.020
Abstract(92) PDF(4)
Abstract:
The effect of TiO2 in the refining slag on the inclusions in Ti-containing stainless steel was investigated under laboratory conditions during Al deoxidation.The results indicate that the inclusions initial Al2O3 forms then change into MgO-Al2O3 type inclusions with the dimention of 4 μm when the to...
Effect of Interaction Between Superheat Degree and Combined EMS on Dendritic Structure and Homogeneity of Heavy Rail Steel Bloom
Li Hongguang
2020, 41(2): 114-119. doi: 10.7513/j.issn.1004-7638.2020.02.021
Abstract(76) PDF(2)
Abstract:
In order to determine the effect of interaction between superheat degree and combined EMS on dendritic structure and C,Mn homogeneity of heavy rail steel bloom,comparing experiment for different superheat degrees were carried out based on the specific combined EMS process.The effects of superheat de...
Morphology of Ti-Al Inclusions in Ultrapure Ferritic Stainless Steel
Zhang Yimin, Sun Yanhui, Bai Xuefeng, Chen Ruimei
2020, 41(2): 120-127. doi: 10.7513/j.issn.1004-7638.2020.02.022
Abstract(83) PDF(5)
Abstract:
In this paper,the Ti-Al inclusions in ultra-pure ferritic stainless steel were studied.The Ti-Al inclusions in steel were observed by two-dimensional metallographic method and three-dimensional anhydrous electrolysis.Tungsten filament and field emission scanning electron microscope were used to obse...
Effect of Heating Temperature on Microstructure and Mechanical Properties of Q235/Ti Composites Plates with Ni Interlayer
Peng Lin
2020, 41(2): 128-134. doi: 10.7513/j.issn.1004-7638.2020.02.023
Abstract(91) PDF(3)
Abstract:
In this paper,a comparative experiment was carried out to prepare titanium/steel rolled composite plates under different heating temperature conditions with Ni as intermediate layer.Scanning electron microscope,energy spectrometer,X-ray diffractometer and Instron universal tensile testing machines a...
Roless of Ti in Cr12MoV Steel
Peng Pan, Luo Dengjie, He Yi, Liu Jinyun, Jin Yingrong
2020, 41(2): 135-141. doi: 10.7513/j.issn.1004-7638.2020.02.024
Abstract(106) PDF(3)
Abstract:
The effects of Ti on the formation of austenite and carbides during solidification and cooling in Cr12 MoV die steel were investigated by calculating the solubility products of carbides such as Ti,V,Mo and Cr in different temperature ranges.The results show that TiC can be precipitated only when Ti ...
Microstructure and Mechanical Properties of Fe-0.4C-2Mn-4Al System δ-TRIP Steel
Zhang Dongmei, Feng Yunli, Cao Kuo
2020, 41(2): 142-146. doi: 10.7513/j.issn.1004-7638.2020.02.025
Abstract(234) PDF(7)
Abstract:
The microstructure of Fe-0.4 C-2 Mn-4 Al experimental steel in as-cast and hot-rolled state was analyzed by SEM,XRD and EBSD.The mechanical properties of the experimental steel before and after rolling were studied.The results show that the TRIP steel contains a large amount of δ-ferrite in the micr...
Influence of Nb/Ti on Corrosion Resistance Properties of Low Chromium Ferritic Stainless Steels
Dang Jie, Zhou Peng, Shi Hongyuan
2020, 41(2): 147-150. doi: 10.7513/j.issn.1004-7638.2020.02.026
Abstract(70) PDF(2)
Abstract:
The corrosion resistance of low-chrome ferritic stainless 409 L,409 M,410 L,410 S were evaluated by the chemical immersion erosion test,electrochemical corrosion test and intergranular corrosion test,and morphology and component analysis of corrosion film on the tested stainless steels’ surface were...
Microstructure and Property of Vanadium Micro-alloyed Cold Rolling Dual Phase Steel
Yu Cansheng
2020, 41(2): 151-157. doi: 10.7513/j.issn.1004-7638.2020.02.027
Abstract(82) PDF(3)
Abstract:
The effect of coiling temperature after hot rolling and annealing temperature on the microstructure and properties of vanadium micro-alloy cold-rolled dual phase steels was studied in laboratory.Microstructure and property were compared between the as-hot rolled and after annealing strip,strength me...
Kinetics of Precipitation for AlN in Austenite of Grain-oriented Silicon Steel
Liu Lei, Qiao Jialong, Yin Sibo, Hu Jinwen, Xiang Li, Chou Shengtao
2020, 41(2): 158-162. doi: 10.7513/j.issn.1004-7638.2020.02.028
Abstract(83) PDF(2)
Abstract:
The kinetics of precipitation of AlN in austenite of oriented silicon steel was calculated by the theory of second phase precipitation.The results show that the critical nucleation sizes of AlN in austenite under different nucleation mechanisms are identical and the critical nucleation size increase...
Precipitation Behaviors of Second Phase in Er-containing Stainless Steel Shielding Material
Zhao Yong, Liu Yunming, Gu Mingfei, Pan Qianfu, Wang Yurong, Wu Yu
2020, 41(2): 163-168. doi: 10.7513/j.issn.1004-7638.2020.02.029
Abstract(70) PDF(3)
Abstract:
The precipitation behaviors of the second phase in Er-containing stainless steel were investigated by means of optical microscope(OM) and scanning electron microscope(SEM).The second phase in stainless steel is mainly Ni-Er system,there are two second phases with the same elements but showing obviou...
As-cast Microstructure and Mechanical Properties of Fe-12Mn-8.5Al-0.8C Low Density Steel
Wang Yinghu
2020, 41(2): 169-174. doi: 10.7513/j.issn.1004-7638.2020.02.030
Abstract(139) PDF(2)
Abstract:
The as-cast structure and mechanical properties of Fe-12 Mn-8.5 Al-0.8 C low density steel were studied by means of optical microscopy(OM),scanning electron microscopy(SEM),energy dispersive spectrometer(EDS),X-ray diffraction(XRD).The results show that the as-cast structure is mainly composed of fe...