2018 Vol. 39, No. 4

Technical Review
Research Progress of Solvent Extraction for Separation of Vanadium and Chromium
Ying Ziwen, Ren Xiulian, Wei Qifeng
2018, 39(4): 1-10,16. doi: 10.7513/j.issn.1004-7638.2018.04.001
Abstract(146) PDF(11)
Abstract:
Vanadium and chromium have the similar chemical properties and naturally coexist at most occasions,so the problem for separation of vanadium and chromium has not been properly solved for a long time.The solvent extraction is currently the most common method for the separation of vanadium and chromiu...
Dynamic and Frontier of Modifications of Li4Ti5O12 Anode Material
Li Wang, Liu Jiali, Zhou Lan
2018, 39(4): 11-16. doi: 10.7513/j.issn.1004-7638.2018.04.002
Abstract(207) PDF(5)
Abstract:
As an anode material of lithium ion battery,lithium titanate(Li4Ti5O12) has the advantages of stable structure,long life and high safety,and it’s getting more and more attentions in the fields of power and energy storage.However,lithium titanate has a low conductivity and poor electroconductibility ...
Separating and Extracting of Vanadium and Titanium
Vanadium Extraction from Refractory Stone Coal Using a Streamlined Process
YANG Xiao
2018, 39(4): 17-23. doi: 10.7513/j.issn.1004-7638.2018.04.003
Abstract(166) PDF(6)
Abstract:
Based on the properties and petrographic analysis of a refractory stone coal from Hubei province,a novel vanadium extraction process of fluidized roasting-acid leaching with additive-solvent extraction-precipitation was proposed.The effects of roasting temperature,roasting time,dosage of additives,s...
Leaching of Vanadium and Chromium from Vanadium-chromium Residue Intensified with H2O2
Peng Hao, Guo Jing, Li Gang, Wang Feng, Wang Lilian, Li Bing, Liu Zuohua, Tao Changyuan
2018, 39(4): 24-29. doi: 10.7513/j.issn.1004-7638.2018.04.004
Abstract(68) PDF(2)
Abstract:
Vanadium and chromium in low valence are difficult to be leached in alkaline medium.For vanadium and chromium leaching,roasting with sodium salts might emit some poisonous gas and large amount of waste water,while roasting with calcium salts will consume much more energy.H2O2 as an oxidant was appli...
Investigation on Separation of Vanadium and Chromium in Alkaline Solution and Preparation of V2O5 and Cr2O3 Products
Li Ming, Jiang Lin, Wu Zhenxiu
2018, 39(4): 30-35,47. doi: 10.7513/j.issn.1004-7638.2018.004.005
Abstract(157) PDF(5)
Abstract:
This paper focused on vanadium and chromium separation in solution using hydrolysis technology.The factors of p H value,temperature and time for vanadium precipitation have been investigated to study their effect on the precipitation rate of vanadium,and the optimum parameters have been determined a...
Material Proportioning Calculations for Aluminothermic Reduction of Ti-containing Slag
Piao Rongxun, Ma Lan, Yang Shaoli, Yu Junzhi
2018, 39(4): 36-40,69. doi: 10.7513/j.issn.1004-7638.2018.04.006
Abstract(98) PDF(3)
Abstract:
The preparation of Ti-Al based alloy by aluminothermic reduction of Ti-bearing slag is a promising process due to the low cost of raw materials and products.To obtain a good slag-metal separation and required composition of Ti Al alloy,the material proportioning calculations are necessary. In this w...
Carbothermic Reduction Kinetics of Oxidized Panzhihua Ilmenite Concentrate
SONG Bing
2018, 39(4): 41-47. doi: 10.7513/j.issn.1004-7638.2018.04.007
Abstract(83) PDF(6)
Abstract:
The isothermal carbothermal reduction of oxidized ilmenite concentrate/carbon composite pellets was performed with coke as reductant,and the kinetics was analyzed by integration method. The reduction temperature was set at 1 000,1 100,1 200 and 1 300 ℃,respectively.The reduction degree of iron oxide...
Effect of Aluminum Purity on Vanadium Loss in Slag and Alloy Composition of Ferrovanadium Smelting Process
Yu Bin, Xiong Kaiwei, Sun Zhaohui, Pan Cheng, Liang Bin
2018, 39(4): 48-51. doi: 10.7513/j.issn.1004-7638.2018.04.008
Abstract(112) PDF(3)
Abstract:
Influence factors of low grade industrial aluminum for ferrovanadium preparation by aluminothermic reduction process were analyzed.Main components of different grades of reducing agent and its effects on vanadium loss and composition of alloy with different grades were investigated. The analysis sho...
Application of Vanadium and Titanium
Preparation and Properties of TiO2 Nanotubes
Xu Ying, Wang Huanhuan, He Shiyu, Cai Yanqing, Wang Bian
2018, 39(4): 52-57. doi: 10.7513/j.issn.1004-7638.2018.04.009
Abstract(276) PDF(9)
Abstract:
In order to make titanium based metals fit for the implant environment of human body and improve the wettability and corrosion resistance,TiO2 nanotubes were prepared on the surface of titanium by anodic oxidation method at 25 V of DC voltage using NH4F and ethylene glycol as electrolyte.The effects...
Preparation and Properties of Mesoporous TiO2 Photocatalytic Materials
Yang Zaizhi, Fu Xiaoming, Sun Hu
2018, 39(4): 58-62. doi: 10.7513/j.issn.1004-7638.2018.04.010
Abstract(59) PDF(1)
Abstract:
Nano-TiO2 photocatalyst was prepared by sol-gel method with tetrabutyl titanate as the raw material.The phase composition,microstructure and photocatalytic properties of the obtained nano-TiO2 samples were characterized by XRD,SEM,UV-Vis,specific surface and aperture analyzer,respectively. The resul...
Research on the Properties of Li4Ti5O12 Materials by Solid Phase Synthesis
Meng Weiwei, Xu Yongjun, Yan Beilei
2018, 39(4): 63-69. doi: 10.7513/j.issn.1004-7638.2018.04.011
Abstract(374) PDF(7)
Abstract:
Using titanium dioxide as the initial titanium source and lithium carbonate as the initial lithium source,lithium titanate samples were synthesized via solid phase routes with adjusting the ratio of Li/Ti at0.8,0.85,0.9 respectively,based on a deep study of the reaction principles for lithium titana...
Effect of Ti Content on Electrochemical Properties of MgNi Hydrogen Storage Alloy
Wang Haihua, Wang Xia
2018, 39(4): 70-73. doi: 10.7513/j.issn.1004-7638.2018.04.012
Abstract(67) PDF(2)
Abstract:
The electrochemical corrosion and electrochemical cycle stability tests of Mg2Ni-Ti hydrogen storage alloys with different contents of Ti were carried out.The results show that the addition of Ti as alloying element can improve the electrochemical corrosion resistance and electrochemical cycle stabi...
Microstructures and Defect Analysis of TC4 Titanium Alloy Joints by the TIG Welding
LU Xin
2018, 39(4): 74-79,92. doi: 10.7513/j.issn.1004-7638.2018.04.013
Abstract(165) PDF(9)
Abstract:
TIG welding experiments on 20 mm thick TC4 titanium alloy plate were carried out by two varying heat inputs,and the joints were investigated in terms of microstructure,mechanical properties and welding defects.Microstructural observations showed that martensite in welded zone is more dispersed than ...
Research on Fatigue Crack Growth Rate of Electron Beam Welded Joint of TA1 Medium Plate
BAI Wei
2018, 39(4): 80-84. doi: 10.7513/j.issn.1004-7638.2018.04.014
Abstract(64) PDF(7)
Abstract:
Electron beam welding( EBW) tests have been conducted on TA1 commercially pure titanium medium plates with a thickness of 30 mm.The effect of EBW welding process on microstructures and properties of TA1 material has been investigated by observing the microstructures and conducting Vickers hardness t...
Resources Environment and Energy Saving
Experiment Study on Utilization in Additive of Cement of Panzhihua Ti-bearing Blast Furnace Slag Flotation Tailings
Zheng Yu, Cui Yating, Chen Tao, Wang Weiqing
2018, 39(4): 85-92. doi: 10.7513/j.issn.1004-7638.2018.04.015
Abstract(69) PDF(2)
Abstract:
In order to utilize titanium-bearing blast furnace slag,taking Panzhihua Ti-bearing blast furnace slag as raw material and recovering the titanium component through high temperature modificationflotation separation process.For flotation tailings,the characteristics of the mineral composition,micro-m...
Experimental Study on Heat Recovery of the Process of Gas Blowing for Blast Furnace Slag
Wang Zibing, Liu Yue, Zhang Yuzhu, Xing Hongwei, Wang Lili, Liu Zhenchao
2018, 39(4): 93-98. doi: 10.7513/j.issn.1004-7638.2018.04.016
Abstract(93) PDF(7)
Abstract:
Blast furnace slag has high level of heat energy,which belongs to high grade waste heat resource,and is of great value for recovery.Taking blast furnace slag as heat source,air as gas quenching medium,air and water as heat exchange medium,rotary slag cooler is applied to carry out high temperature r...
Experiment Study on Ammonia System Leaching Zinc from Blast Furnace Dust
Huang Ping, Zhang Yuan
2018, 39(4): 99-103. doi: 10.7513/j.issn.1004-7638.2018.04.017
Abstract(56) PDF(2)
Abstract:
For the purpose of effectively leaching zinc from blast furnace dust by means of NH3-(NH4)2SO4-H2O ammonia system,the effects of liquid-to-solid ratio,leaching time,leaching temperature,total ammonia concentration and stirring rate on the zinc leaching rate had been experimentally investigated,and t...
Experimental Study on Effect of Electrolytic Temperature on Performance of ZnO/semi Coke Desulfurizer
Dou Guanxiong, Long Yue, Zhang Liangjin, Sang Rongli, Pan Xiangyang
2018, 39(4): 104-108. doi: 10.7513/j.issn.1004-7638.2018.04.018
Abstract(41) PDF(1)
Abstract:
The active semi char loaded with Zinc Oxide was prepared by electrochemical deposition with a semi coke as the carrier,zinc nitrate(Zn(NO32) and six times methyl four amine( HMT) as the electrolyte.The samples were characterized by SEM,TEM and FT-IR,and the effects of different electrolysis tempera...
Ferrous Metallurgy and Materials
Effect of Al2O3 on the Formation Mechanism of Calcium Ferrite
Hu Changqing, Yang Jintao, Zhao Kai, Yan Longge
2018, 39(4): 109-113. doi: 10.7513/j.issn.1004-7638.2018.04.019
Abstract(90) PDF(3)
Abstract:
In the production of fluxed sinter,calcium ferrite as a low melting point compound which appears to be the starting point of liquid phase formation.During the sintering of iron ore the calcium ferrite acts as a reactant to form complex calcium ferrite in sinter,its amount and distribution affect the...
Analysis of Titanium Distribution Based on the Conditions of Furnace Protection with Titanium Ore
Chang Zhiyu, Jiao Kexin, Ning Xiaojun, Zhang Jianliang, Mo Chaoxing, Chen Rugang
2018, 39(4): 114-121. doi: 10.7513/j.issn.1004-7638.2018.04.020
Abstract(110) PDF(6)
Abstract:
In order to further analyze the influence of composition and temperature of slags and hot metal on the titanium distribution ratio under the conditions of furnace protection with titanium ore,the production data of a blast furnace in China was statistically analyzed. And with the help of thermodynam...
Single Taper Optimization of Beam Blank Mold
Chen Wei, Guo Gaoxiang, Yu Xingwang, Wang Jiaqi, Chen Ying, Yang Gaiyan
2018, 39(4): 122-128. doi: 10.7513/j.issn.1004-7638.2018.04.021
Abstract(130) PDF(7)
Abstract:
In order to control surface cracks in blank beam during continuous casting process,the thermomechanical coupling model of heat transfer,solidification and shrinkage of slab in mold was established by using multi-load step method.According to the calculation results about air gap,based on the princip...
Study on Improving Equiaxed Grain Ration of Ferritic Stainless Steel with Core Containing-Ti
Chen Yongfeng, Shi Xiaofang, Chang Lizhong
2018, 39(4): 129-136. doi: 10.7513/j.issn.1004-7638.2018.04.022
Abstract(64) PDF(1)
Abstract:
The reason and countermeasure of "ridging"defect on the surface of stainless steel products is clarified,the advantages and disadvantages of various methods to improve the solidification quality of the casting billet are analyzed. Based on the previous theoretical and experimental results,the idea o...
Research on Large Inclusion Behavior of Carbon Structural Steel before Steel Slag Modified
Qin Shuyang, Wu Bo, Li Sheng, Wang Shuoming, Zhu Liguang, Liu Zengxun, Han Yihua
2018, 39(4): 137-141. doi: 10.7513/j.issn.1004-7638.2018.04.023
Abstract(54) PDF(1)
Abstract:
The content,type,size and origin of large inclusions in two kinds of low cost carbon structural steel Q235 D in a steel factory in north China were studied systematically by inclusion tracing.The results shows: 120 tons BOF—CC process,the average content of T[O]in steady casting billets is 76×10-6,a...
Microstructure Evolution of 316 Stainless Steel During Tensile Process
Sun Lingli, Ho Hsinshen, Liu Kunkun, Zhang Erliang
2018, 39(4): 142-145,151. doi: 10.7513/j.issn.1004-7638.2018.04.024
Abstract(374) PDF(9)
Abstract:
To investigate the microstructure evolution of 316 stainless steel during the slow strain tensile test,strain control is adopted and the strain rate is 10-3 s-1. The specimens are mechanically polished,then chemically-etched,and the tensile test is carried out. The microstructure is investigated by ...
Continuous Casting Process Optimization of High-strength Steel 700L Thin Slab
Hou Mingshan, Zhou Chaogang, Ai Liqun, Li Mengying, Zhang Yao, Wei Shenghui, Dong Jiliang, Lu Boxun, Li Zhonghua
2018, 39(4): 146-151. doi: 10.7513/j.issn.1004-7638.2018.04.025
Abstract(58) PDF(3)
Abstract:
In order to solve the quality problems of 700 L thin slab during Tangshan iron and steel company FTSC continuous casting,force situation of solidification shell in funnel-typed mold and FTSC( Flexible Thin Slab Casting) spray of secondary cooling was analyzed for thin slab continuous casting,at the ...
Cause Analysis of Fine Longitudinal Stripe Defect on Ferritic Rolled IF Steel
Wang Jiangong, Li Lang, Zhou Xun, Qiu Chenyang, Xia Yinfeng, Chen Yongping, Kang Yonglin
2018, 39(4): 152-158. doi: 10.7513/j.issn.1004-7638.2018.04.026
Abstract(80) PDF(2)
Abstract:
In the development of IF steel in ferrite rolling process,the fine longitudinal stripe defects had been observed on the surface of cold rolled product,and the defect is different from the conventional rolling process.In order to find the reason of causing this kind of defects and thereby solve the p...
Research on Resistance Spot Welding Process of DP780 Cold Rolled Sheet
Zhou Leilei, Yu Tengyi
2018, 39(4): 159-163. doi: 10.7513/j.issn.1004-7638.2018.04.027
Abstract(46) PDF(1)
Abstract:
In this paper,the spot welding performance of DP780 cold rolled sheet was evaluated by measuring the nugget diameter and penetration rate,detecting the shear force,texting the hardness of the welded joints,amd analyzing the microstructure and morphology,in order to propose the weldable process scope...
Study on Surface Modification Technology of Mechanical Steel Gasket
Gao Shengxiang, Deng Lixia
2018, 39(4): 164-167. doi: 10.7513/j.issn.1004-7638.2018.04.028
Abstract(63) PDF(1)
Abstract:
The surface modification of mechanical gasket made of 1Cr5MoVSr steel was carried out using laser-cladding technique with varying laser power,spot diameter and scanning speed.Its wear resistance and impact resistance performances were tested and analyzed. The results show that with increasing the la...
Impact Performance and Wear Resistance of Automotive Flywheel Plates Subjected to Press Forging Forming
WAWang Hao, Cao Yuan
2018, 39(4): 168-172. doi: 10.7513/j.issn.1004-7638.2018.04.029
Abstract(44) PDF(1)
Abstract:
In this paper,the effects of initial forging temperature and final forging temperature on the press forging of 1045 steel for the automotive flywheel plate was investigated.The impact performance and wear resistance were tested and analyzed.The results show that when the initial forging temperature ...