2018 Vol. 39, No. 1

Separating and Extracting of Vanadium and Titanium
Experimental Study on Ultrasonic-assisted Extraction of Vanadium and Chromium from High Chromium Vanadium Slag
Wen Jing, Jiang Tao, Liu Jiayi, Xue Xiangxin
2018, 39(1): 1-5. doi: 10.7513/j.issn.1004-7638.2018.01.001
Abstract(59) PDF(1)
Abstract:
In this paper,the leaching behavior of vanadium and chromium was studied by ultrasonic assisted leaching,and the optimum process parameters were obtained.The effects of ultrasonic power,leaching medium concentration,liquid-solid ratio,leaching temperature and leaching time on vanadium-chromium leach...
Measurement of Calcification of Vanadium Slag by XRD Semi-quantitative Method
Wang Minghua, Liu Zhenhui, Zhao Hui, Liu Yan, Lou Taiping, Sun Zhaohui, Tang Hongjian, Jing Han
2018, 39(1): 6-12. doi: 10.7513/j.issn.1004-7638.2018.01.002
Abstract(57) PDF(1)
Abstract:
Calcification roasting process of vanadium slag is just currently situated at pilot stage of industrialization in China,while the recovery ratio of vanadium from vanadium slag is only 69.7%.It is not clear so far whether the calcification or leaching process leads to the low recovery ratio. This pap...
Mineralogical Characteristics of Vanadium Slag
Wang Ling, Cui Zhaochun, Zhang Yuxi, Li Cunguo, Bai Wangmin, Li Zhiwei, He Peng
2018, 39(1): 13-17. doi: 10.7513/j.issn.1004-7638.2018.01.003
Abstract(158) PDF(8)
Abstract:
The mineral and chemical compositions,occurrence and distribution of the valuable elements,the structure and tectonics of vanadium slag were characterized by X-ray powder diffraction,optical microscope,X-ray fluorescence,scanning electron microscopy and energy dispersive spectrum,aiming to provide a...
Influence of Post-processing on Brightness of Titanium Dioxide
Wang Haibo
2018, 39(1): 18-23. doi: 10.7513/j.issn.1004-7638.2018.01.004
Abstract(84) PDF(4)
Abstract:
In order to solve the problem of low brightness and brightness fluctuation for titanium dioxide(TiO2) produced by a certain plant,a systemic investigation related to influences of the raw materials and process of post-processing on brightness of TiO2 was carried out in basis of industrial conditions...
Preparation of Titanium Powder by Reduction of TiO2 at Low Temperature with CaH2
DENG Bin
2018, 39(1): 24-30. doi: 10.7513/j.issn.1004-7638.2018.01.005
Abstract(157) PDF(4)
Abstract:
A new method for preparing Ti powder by thermal reduction at low temperature was explored with industrial titanium dioxide(TiO2) powder and AR(Analytical Reagent) calcium hydride(CaH2)powder as raw materials.The decomposition conditions of CaH2 and the process for reduction of TiO2 by decomposed CaH...
Study on the Influence Factors for Titanium Formation on Reactor Wall during Titanium Sponge Production by Kroll Process
SHENG Zhuo
2018, 39(1): 31-34. doi: 10.7513/j.issn.1004-7638.2018.01.006
Abstract(105) PDF(2)
Abstract:
In this paper,the microstructure of titanium formed on the reactor wall during titanium sponge production by Kroll process was investigated to further analyze the growth process of wall-adherent titanium and its influencing factors for accumulation.The results show that the generation of wall-adhere...
Application of Vanadium and Titanium
Exploring the Relationship of Structure and Electrochemical Activity of V(Ⅲ) Ion in Vanadium Electrolyte
Xu Jie, Fan Chuanlin, Yang Haitao, Zhu Qingshan
2018, 39(1): 35-39. doi: 10.7513/j.issn.1004-7638.2018.01.007
Abstract(241) PDF(6)
Abstract:
All-vanadium redox flow battery(VRFB) is one of the most promising large-scale energy storage technologies,owing to its inherent safety and long service life.During the charging-discharging process,the redox reaction of V(Ⅲ)↔V(Ⅱ) with standard electrode potential of-0.25 V(vs.NHE) is the main electr...
Research on Calculation Method for Hydrogen Induced Stress Corrosion Fracture Toughness of Metal in Deep Sea
Xi Qiang, Zheng Bailin, He Pengfei, Yang Biao, Li Yanqing
2018, 39(1): 40-45. doi: 10.7513/j.issn.1004-7638.2018.01.008
Abstract(162) PDF(6)
Abstract:
Focusing on the hydrogen induced stress corrosion cracking(HISCC) of titanium alloy in deep sea,this paper calculated hydrogen diffusion in metal with the stress induced diffusion method and introduced the hydrogen reducing surface energy model into HISCC process to simulate the cycling of the mater...
Research on Dry Sliding Wear Performances of Hot-dip Aluminized TC4 Alloy
Chen Wei, Wang Haohao, Guo Menglei, Jiang Wei, Wang Shuqi
2018, 39(1): 46-50. doi: 10.7513/j.issn.1004-7638.2018.01.009
Abstract(73) PDF(1)
Abstract:
The aluminized TC4 alloy was prepared by hot-dip aluminizing and subsequently high-temperature annealing treatment. The morphology,phase and compositions of aluminized coating were characterized with SEM,XRD and EDS.Dry sliding wear behaviors at different velocities and loadings were conducted for t...
Preparation of TiN by Reaction between Mg3N2 and TiCl4
Zhu Fuxing
2018, 39(1): 51-55,59. doi: 10.7513/j.issn.1004-7638.2018.01.010
Abstract(95) PDF(2)
Abstract:
Preparation of Ti N via reaction of Mg3N2 and TiCl4,and its yield ratio were studied respectively through XRD,SEM and orthogonal experiments.The results show that TiN can be obtained by the reaction of Mg3N2 and TiCl4,and the product is of irregular morphology with nonuniform particle size.The react...
Ultrasonic Casting Process Optimization of Vanadium-based Hydrogen Storage Alloy
Zheng Xin, Yang Yuling, Liu Ronghai
2018, 39(1): 56-59. doi: 10.7513/j.issn.1004-7638.2018.01.011
Abstract(46) PDF(1)
Abstract:
Ultrasonic casting of V3Ti0.56Cr0.1Mo0.1 vanadium-based hydrogen storage alloys was carried out at different ultrasonic vibration frequencies and pouring temperatures,and the hydrogen storage property and electrochemical cycling stability of the samples were tested and analyzed.The results show that...
Current Research Status and Development of High-temperature Titanium Alloys
Huang Dong, Yang Shaoli, Ma Lan, Liao Xin, Piao Rongxun
2018, 39(1): 60-66. doi: 10.7513/j.issn.1004-7638.2018.01.012
Abstract(780) PDF(34)
Abstract:
In this paper,the development and present application of high-temperature titanium alloys were introduced.The research status and influence of alloying elements on high-temperature titanium alloys domestic and abroad were contrasted and analyzed.Titanium alloys with 600℃ of working temperature mainl...
ResourcesI Environment and Energy Saving
Effect of Microwave on the Treatment of Gaseous Solid-state Low-cyclic PAHs in Coke Flue Gas
Shi Yan, Zhao Xin, Guan Wei, Feng Yingying, Zhao Ying, Hao Suju
2018, 39(1): 67-71. doi: 10.7513/j.issn.1004-7638.2018.01.013
Abstract(53) PDF(1)
Abstract:
The polycyclic aromatic hydrocarbons(PAHs) were collected from absorbing media of activated carbon and silicon carbide by dichloromethane and glass fiber. Ultrasonic extraction and high performance liquid chromatography(HPLC) were used to qualitatively and quantitatively analyze the low cyclic polyc...
Effect of Nucleating Agent on Crystallization Behavior and Kinetics of Blast Furnace Slag Glass Ceramics
Gao Yang, Gui Yongliang, Song Chunyan, Hu Binsheng, Wang Yawen
2018, 39(1): 72-77. doi: 10.7513/j.issn.1004-7638.2018.01.014
Abstract(115) PDF(2)
Abstract:
Taken Tangshan iron and steel blast furnace slag as the main raw material,Cr2O3,TiO2,Fe2O3 and P2O5 nucleating agent had been added with a certain proportion of other raw materials,and the blast furnace slag microcrystalline glass had been prepared by melting method. Differential thermal analyzer(SE...
Analysis on the Mechanism of Direct Reduction of Limonite by Coke Quenching Ash as Reducing Agent
Chen Weipeng, Wang Qiang, Feng Zhiming, Chen Xiaodan, Zhao Zengwu, Wu Wenfei, Li Baowei
2018, 39(1): 78-83. doi: 10.7513/j.issn.1004-7638.2018.01.015
Abstract(58) PDF(5)
Abstract:
The reaction mechanism of low-grade limonite powder in the process of heating with different carbon-oxygen ratio was revealed by thermal analysis at temperature of 20 ~1 100 ℃,using coke quenching ash as a new reducing agent.The effects of different carbon ratios on the reaction rate were studied.Th...
Thermodynamic Analysis on Effects of Chemical Composition on Mineral Composition in Medium-titanium Blast Furnace Slag
Zhang Shuhui, Yan Zhaozhao, Liu Xiaojie, Dong Xiaoxu, Lü Qing, Lan Chenchen
2018, 39(1): 84-91. doi: 10.7513/j.issn.1004-7638.2018.01.016
Abstract(87) PDF(2)
Abstract:
The equilibrium mineral components in the crystallization process of medium-titanium blast furnace slag are calculated by using FACTSage 7.0 thermodynamics software,and the influence of different chemical composition on mineral precipitation process and mineral composition of medium-titanium blast f...
Ferrous Metallurgy and Materials
Study on the Relationship between Carbon Consumption and Direct Reduction of Iron in Low Grade Ore
Yan Shuai, Huang Bangfu, Liu Jiangwei, Wang Weiwei, Zheng Jingqiang
2018, 39(1): 92-96. doi: 10.7513/j.issn.1004-7638.2018.01.017
Abstract(130) PDF(6)
Abstract:
In the blast furnace smelting,the consumption of carbon is determined by the sum of the calorific carbon consumption and the carbon loss of the reduction reaction.During the smelting process,as the direct reduction of iron rdincreases,the direct reduction carbon consumption increases,and as the reac...
Study of Slag Forming Path During Dephosphorization and Vanadium-extraction from Vanadium-containing Hot Metal
CHEN Lian
2018, 39(1): 97-102,123. doi: 10.7513/j.issn.1004-7638.2018.01.018
Abstract(55) PDF(2)
Abstract:
Processing slag and ending slag of vanadium-extraction converter was analyzed and the slag formation and the existing form of phosphorus in the slag had been investigated. It is found out that addition of lime into the vanadium-extraction converter during production can achieve dephosphorization fro...
Study on Adsorption Capacity of Adsorption Bar under Multi-factors
Wang Yufei, Zhao Dingguo, Gao Ming, Wang Shuhuan
2018, 39(1): 103-110. doi: 10.7513/j.issn.1004-7638.2018.01.019
Abstract(43) PDF(1)
Abstract:
The refractory absorption bar is inserted into the submersed nozzle by stopper to absorb the inclusion flowing through the nozzle and the cleanness of liquid steel during the continuous casting process can be improved. The influence of the depth of groove,the direction of rotation and the number of ...
Study on the Mold Flow State Influenced by Two-hole Nozzle
Liu Yi, Zhang Caijun, Wu Zhe
2018, 39(1): 111-117. doi: 10.7513/j.issn.1004-7638.2018.01.020
Abstract(96) PDF(1)
Abstract:
The particle image velocimetry-PIV technique was used to study the factors affecting the flow state in the continuous casting mold.i With the increase of casting speed,the distance of narrow face impact point to level decreases,and difference in the level flow velocity decreases,resulting in the flo...
Key Technologies of Macro Segregation Control in 320 mm×410 mm Continuous Casting Bloom for Railway Steel
Chen Liang, Song Bo, Chen Tianming, Li Yangzhou, Li Zhiqiang, Li Jianquan
2018, 39(1): 118-123. doi: 10.7513/j.issn.1004-7638.2018.01.021
Abstract(110) PDF(9)
Abstract:
The electromagnetic stirring,total amount of soft reduction and the matching between super heat and casting speed were researched in order to control carbon segregation index of transverse section and center segregation in rail steel bloom. The key technologies of segregation control in 320 mm×410 m...
Solidification Structure Optimization of 304 Stainless Steel
Wu Qingyu, Zhao Jing, Lü Junjie, Zhao Ziyu
2018, 39(1): 124-129. doi: 10.7513/j.issn.1004-7638.2018.01.022
Abstract(69) PDF(5)
Abstract:
In order to reduce the crack of 304 austenitic stainless steel pipe,the experiments of composition optimization,F-EMS and superheat controlling have been done to optimize solidification structure.The area fraction of δ ferrite in structure of billet center decreases from 8.6 % to 7.2 % through compo...
Effect of Composition on Solidification Structure of Low Carbon Steel Based on CAFE Method
Wen Juwen, Zhu Liguang, Zhang Yuanjie, Yang Gaiyan, Liu Yi
2018, 39(1): 130-135. doi: 10.7513/j.issn.1004-7638.2018.01.023
Abstract(56) PDF(1)
Abstract:
The composition of steel is an important factor affecting the solidification structure of slab.In this paper,the influence of the composition of low carbon steel Q235 on the solidification structure is studied based on the CAFE method. The increase of C content and the increase of C content make the...
Surface Transversal Crack on S355ML Beam Blank
Zhao Pengze, Sun Yanhui, Dong Jian, Wu Baoqiao, Wang Houxin
2018, 39(1): 136-142. doi: 10.7513/j.issn.1004-7638.2018.01.024
Abstract(52) PDF(1)
Abstract:
The causes of surface transverse crack on S355 ML beam blanks had been investigated by metallographic,SEM,TEM observations and nozzle flow field analysis,in combination with thermal imaging temperature of continuous casting billet. Results show that the flow field distribution of through-type nozzle...
Analysis of IAF Nucleation and Grain Refinement Behavior in EH460 Steel
Qin Shuyang, Liu Zengxun, Wang Shuoming, Zhu Liguang
2018, 39(1): 143-147. doi: 10.7513/j.issn.1004-7638.2018.01.025
Abstract(67) PDF(1)
Abstract:
The structure,composition,particle size of micro-inclusions in laboratory as-cast shipbuilding steel with different content and type of elements were analyzed. It was found out that some kinds of inclusions in steel can induce nucleation of IAF and the needle tip of IAF can insert into other ferrite...
Comparison of Quality between C70S6 Steels Produced by Chinese and Oversesa Steelmakers for Fracture Splitting Connection Rod
Deng Xiangyang, Li Jian, Xie Jianbo, Hu Delin, Wang Yang, Fu Jianxun
2018, 39(1): 148-154. doi: 10.7513/j.issn.1004-7638.2018.01.026
Abstract(174) PDF(5)
Abstract:
Cracking technology requires materials with advanced performances of high strength,low toughness,well-cutting and small plastic deformation during brittle fracture.The C70 S6 steel is an important material for fracture splitting connection rod.The steels produced by Chinese and overseas steelmakers ...
Numerical Simulation of Spray Angle in the Process of Atomization Process of SmFe Melt
Wang Shuhuan, Cui Shaopu, Sun Xin, Zhao Dingguo, Fang Yunchu, Song Chunyan
2018, 39(1): 155-159. doi: 10.7513/j.issn.1004-7638.2018.01.027
Abstract(70) PDF(2)
Abstract:
To explore the influence of spray angle on the atomization process of Sm Fe melt,the structure of nozzle based on the close-coupled nozzle,the atomization process of Sm Fe melt has been simulated using Fluent,and the influence of different spray angles on the flight distance before solidification of...
Production Practice of Process Optimization of 780 MPa Cold Rolled Dual Phase Steel
Li Xia, Wang Xigang
2018, 39(1): 160-164. doi: 10.7513/j.issn.1004-7638.2018.01.028
Abstract(105) PDF(2)
Abstract:
In order to obtain excellent mechanical property of 780 MPa cold rolled dual phase steel,process optimization had been done including adjusting the chemical elements C、Si、Nb、Ti、Cr and coiling temperature.And the microstructure observation and mechanical properties measurement of hot and cold rolling...
FEM Analysis and Pass System Optimization of 16#Ⅰ Beam during Rolling
Tang Rui, Zhang Zheng, Xie Yongchun
2018, 39(1): 165-168. doi: 10.7513/j.issn.1004-7638.2018.01.029
Abstract(83) PDF(1)
Abstract:
In this paper FEM software were used to simulate rolling process of conjugated pass system of some enterprise,bend and twist of rolled piece during rolling had been identified. The reasons which caused these problems had been found out by quantification and transformation analysis,and optimization o...
2018, 39(1): 169-170.
Abstract(58) PDF(2)
Abstract: