2015 Vol. 36, No. 5

Separating and Extracting of Vanadium and Titanium
Research on Vanadium Extraction from Vanadium-chromium Solution by Ion-exchange
Gao Guanjin, Peng Yi, Cao Hongbin
2015, 36(5): 1-5. doi: 10.7513/j.issn.1004-7638.2015.05.001
Abstract(99) PDF(3)
Abstract:
According to the characteristics of vanadium extraction from vanadium slag,selective extraction of vanadium from vanadium-chromium (V-Cr) containing solution by ion exchange was put forward to evade V-Cr separation problem. Partial vanadium was selectively adsorbed from high concentration of vanadiu...
Mechanism Research on the Thermal Decomposition of NH4VO3
Wang Tanglin, Sun Zhaohui, Xian Yong, Yin Danfeng, Li Qianwen
2015, 36(5): 6-10. doi: 10.7513/j.issn.1004-7638.2015.05.002
Abstract(466) PDF(35)
Abstract:
The mechanism of the thermal decomposition of NH4VO3 was investigated by TG-DSC in this paper. The analysis results indicate that the decomposition process experiences four steps including the initial three endothermic reactions and a last exothermic reaction. The kinetic parameters of the formation...
Study on Precipitation and Growth Kinetics of Rutile Phase in High-titanium Slag
He Min, Lou Taiping, Du Xinghong, Sui Zhitong
2015, 36(5): 11-15. doi: 10.7513/j.issn.1004-7638.2015.05.003
Abstract(129) PDF(5)
Abstract:
The concentration process of titanium into rutile phase in the high-titanium slag was observed at different quenching temperatures using the high-titanium slag produced from the titanium concentrate in Panxi area as raw material,and the precipitation and growth kinetics of rutile were also investiga...
Analysis of Process of Melting Salt Chlorination with Titanium Slag in Panzhihua
Qin Xinghua
2015, 36(5): 16-19. doi: 10.7513/j.issn.1004-7638.2015.05.004
Abstract(131) PDF(9)
Abstract:
According to the characteristic of titanium slag produced with ilmenite concentrate in Panzhihua as raw material that the content of calcium and magnesium impurities is high but the TiO2 concentration is low,the analysis for the critical control point in process of melting salt chlorination with tho...
Application of Vanadium and Titanium
Study on Magnetic W,N-codoped TiO2/SiO2/Fe3O4 Photocatalyst
Li Xue, Zhang Ying, Zhang Yan, Jin Ze, Liu Yunyi
2015, 36(5): 20-24. doi: 10.7513/j.issn.1004-7638.2015.05.005
Abstract(68) PDF(2)
Abstract:
Using Fe3O4 nanoparticles as the kernel,SiO2 inert layer as the isolation layer,tetra-n-butyl titanate as the precursor,ammonium tungstate and ammonium nitrate as doping sources,magnetic W,Ncodoped TiO2 photocatalyst was prepared by low-temperature sol method. The properties of the magnetic photocat...
Effect of Calcination Temperature on the Properties of Nano-sized Vanadium Catalyst
Guo Chunmei
2015, 36(5): 25-29. doi: 10.7513/j.issn.1004-7638.2015.05.006
Abstract(103) PDF(3)
Abstract:
Nano-sized vanadium catalysts were prepared under different calcination temperatures,and the micro-morphology,activity,mechanic strength and corrosion resistance of the catalysts were tested and analyzed. The results show that the nano-sized vanadium catalyst prepared at 650 ℃ has the best activity,...
Influence of Cr Content in Ilmenite on Whiteness and Brightness of Titanium Pigments
Lu Ruifang, Wu Jianchun
2015, 36(5): 30-33. doi: 10.7513/j.issn.1004-7638.2015.05.007
Abstract(116) PDF(5)
Abstract:
Taking the two kinds of titanium white RA and RB produced by sulphate process in a domestic corporation as research targets,the influence of Cr content on whiteness and brightness of the crude titanium white pigments was studied. For the corresponding A (raw materials of RA) and B (raw materials of ...
Kinetics of BiVO4 Prepared by Solid Reaction between Bi(NO33·5H2O and NH4VO3 under Calcination
Du Guangchao, Sun Zhaohui, Xian Yong, Chen Haijun, Jing Han, Yin Danfeng, Tang Hongjian
2015, 36(5): 34-39. doi: 10.7513/j.issn.1004-7638.2015.05.008
Abstract(176) PDF(7)
Abstract:
The kinetics of Bi VO4 prepared by the solid reaction of Bi (NO3)3·5H2O and NH4VO3 was investigated using TG-DSC under different heating rates. The results show that the process undergoes two stages. The first period corresponds to the solid and liquid-state reactions and the second period is a soli...
Resources Environment and Energy Saving
Experimental and Thermodynamic Study on Reduction of Carbon-containing Pellet of Vanadium Tailings Smelted by Electric Arc Furnace
Wu Enhui, Zhu Rong, Yang Shaoli, Hou Jing, Li Jun, Wang Zun
2015, 36(5): 40-46. doi: 10.7513/j.issn.1004-7638.2015.05.009
Abstract(116) PDF(4)
Abstract:
The thermodynamics of carbothermal reduction of vanadium and chromium oxides in vanadium tailings was calculated and analyzed. It is shown that the reduction sequence of vanadium oxide is V2O5 →VO2→V2O3→VO→VC→[V],and the reduction sequence of chromium oxide is CrO3→CrO2→Cr2O3→Cr4C →[Cr]. Using elect...
Influence of Acidity Coefficient on Fiber Quality of Adjusted Molten Blast Furnace Slag
Cai Shuang, Zhang Yuzhu, Li Junguo, Li Jie, Wang Liguang
2015, 36(5): 47-52. doi: 10.7513/j.issn.1004-7638.2015.05.010
Abstract(70) PDF(4)
Abstract:
In order to improve the quality of slag fiber,iron tailings were used for adjusting the blast furnace slag. The effect of acidity on the viscosity,melting temperature and mineral compositions of the adjusted blast furnace slag was investigated,and the quality of slag fiber was evidenced to be improv...
Improving LD Gas Recovery on Converter Smelting with Vanadium Titanium Molten Iron
Li Li, Li Fengchun, Zheng Qiying
2015, 36(5): 53-56. doi: 10.7513/j.issn.1004-7638.2015.05.011
Abstract(74) PDF(2)
Abstract:
Systematic analysis of various influence factors on converter gas recovery under the special processes of smelting vanadium-containing molten iron was carried out in this paper. Through industrial experiments,the condition of operation and control level of the relevant processes were optimized,inclu...
Process Mineralogy Study of Sulfide in Panzhihua Vanadium-titanium Magnetite
Hu Houqin
2015, 36(5): 57-62. doi: 10.7513/j.issn.1004-7638.2015.05.012
Abstract(67) PDF(3)
Abstract:
There is a large amount of vanadium titanium magnetite resource in Panzhihua area. Sulfide in the resource is associated with cobalt,nickel,copper and other valuable metals. In this paper sulfide had been investigated by the laser micro spectral analysis,spectral semi-quantitative analysis and elect...
Technical Review
Hot Ductility in V-microalloyed Steels
Banks K M, Tuling A, Mintz B
2015, 36(5): 63-68. doi: 10.7513/j.issn.1004-7638.2015.05.013
Abstract(88) PDF(5)
Abstract:
Transverse cracking resistance is generally displayed in low-C low-N microalloyed steels,but not in microalloyed steels with higher C levels. This paper discusses hot ductility work and commercial experience concerning V microalloyed steels with C levels between 0.05%~0.6 %. These V additions reduce...
Ferrous Metallurgy and Materials
Study on the Preparation Technology of Vanadium and Titanium Iron Concentrate Magnetic Pellets Containing Carbon and Boron
Ma Lan, Yang Shaoli
2015, 36(5): 69-73. doi: 10.7513/j.issn.1004-7638.2015.05.014
Abstract(65) PDF(2)
Abstract:
In this paper,the effects of boron-bearing iron concentrate content,roasting temperature and roasting time on the magnetization indexes of the carbon and boron bearing pellets were investigated by ternary and quadratic orthogonal regression and blank test. The results showed that the magnetic effect...
Basic Sintering Characteristics of Low Titanium Mixed Iron Ore
Liu Song, Li Fumin, Lü Qing
2015, 36(5): 74-78,86. doi: 10.7513/j.issn.1004-7638.2015.05.015
Abstract(74) PDF(2)
Abstract:
Sintering basic characteristics of Xuanhua Steel single titanium containing iron ore powder were determined in order to conduct match optimization test. The results showed that sinter tumbler index increased with increasing mixed iron ore binding phase strength,while low temperature RDI index and mo...
Influence of Separated Granulating Sintering Process Parameters on Vanadium Titanium Sinter Microstructure
Li Yanjiang, Lü Qing, Bai Ruiguo, Ding Haichao, Li Hongwei, Sun Yanqin
2015, 36(5): 79-86. doi: 10.7513/j.issn.1004-7638.2015.05.016
Abstract(66) PDF(2)
Abstract:
In this paper the impact of process parameters such as acidic material sintered grain size,carbon ration and alkalinity on the microstructure of shunt granulation sintered ore had been studied. It was found out that when particle size range of acidic materials expanded,material layer permeability im...
Feasibility of the Synergistic Utilization of Ironsand and Blast Furnace Bag Dust
Liu Yiran, Zhang Jianliang, Wang Zhenyang, Liu Zhengjian, Xing Xiangdong
2015, 36(5): 87-91. doi: 10.7513/j.issn.1004-7638.2015.05.017
Abstract(71) PDF(2)
Abstract:
Due to strongly complementary of ironsand to blast furnace bag dust in terms of the chemical composition and size distribution,the feasibility of synergistic utilization of ironsand and blast furnace bag dust had been investigated where the reduction experiments using ironsand- BF bag dust compound ...
Research on Influence of Basicity on Dropping Performance of Vanadium-titanium Burden
Wang Fujia, Lü Qing, Chen Shujun, Liu Ran, Li Fuming
2015, 36(5): 92-96. doi: 10.7513/j.issn.1004-7638.2015.05.018
Abstract(139) PDF(3)
Abstract:
Experiments were carried out in the lab to simulate dropping zone of blast furnace in a high temperature oven,and the effect on charge softening temperature range,melting temperature range,maximum pressure,droplet comprehensive index and other high temperature physical properties at different basici...
Experimental Study on the Desulfurization of CaO-Al2O3-SiO2-TiO2 Slag System
Wu Long, Hu Tianqi, Hao Yidang, Zhang Guohua, Li Shiqi
2015, 36(5): 97-102. doi: 10.7513/j.issn.1004-7638.2015.05.019
Abstract(52) PDF(2)
Abstract:
In this paper the desulfurization ability of CaO-Al2O3-SiO2-TiO2 slag was studied through the desulfurization experiment by using 10 kg inductive furnace and theoretical calculation by using thermodynamic software Factsage,in order to determine the impact of binary basicity,mass percent of Al2O3 and...
Influence of Basicity on Crystallization Temperature and Crystalline Phase of Mould Powder
Zhang Yifei, Han Xiuli, Liu Lina, Zhang Han
2015, 36(5): 103-107. doi: 10.7513/j.issn.1004-7638.2015.05.020
Abstract(101) PDF(7)
Abstract:
Based on chemical compositions and metallurgical properties of mould powder for hypoperitectic steel,the crystallization temperature and crystalline phase of experimental flux film in different basicity under laboratory conditions were observed by the method of process mineralogy. The results showed...
Experimental Study of Solid Flow in the Moving Bed of Corex Melter Gasifier
Pan Gang, Liu Xunliang, Wen Zhi, Wu Wenfei
2015, 36(5): 108-113. doi: 10.7513/j.issn.1004-7638.2015.05.021
Abstract(71) PDF(2)
Abstract:
Cold model of moving bed of Corex melter gasifier was set up. Flow pattern of solid,geometry and size of deadman were obtained by the trace of tracer particles in the moving bed. Furthermore,the effect of height of moving bed and gas flow on the height and cross- sectional area of deadman were studi...
Research on Pellets Reduction Behavior under Oxygen Blast Furnace
Sun Depeng, Xue Qingguo, Liu Jinzhou, Guo Wentao, Wang Jingsong
2015, 36(5): 114-121. doi: 10.7513/j.issn.1004-7638.2015.05.022
Abstract(73) PDF(2)
Abstract:
In order to determine the reduction process of ironmaking system under the oxygen blast furnace condition,a mathematical model of coupling gas solid heat transfer with chemical reaction in the blast furnace had been developed and been used to obtain the heating systems and the atmosphere change rule...
Analysis of BF Flow Field before and after Slag Formation
Feng Xuewu, Jin Yan, Li Yang, Cheng Changgui, Chang Zhengsheng, Jin Yelei
2015, 36(5): 122-128. doi: 10.7513/j.issn.1004-7638.2015.05.023
Abstract(63) PDF(2)
Abstract:
In order to investigate the difference of molten iron flow field in furnace hearth under normal erosion and adherent dross erosion,basing on the fluid mechanics two 3D mathematical models had been developed,which were used to describe the molten iron flow fields before/after hearth bottom erosion an...
Analysis on Cracking of Abrasion- resistant Steel Plate NM360
Fan Danping, Peng Qichun, Deng Li
2015, 36(5): 129-133. doi: 10.7513/j.issn.1004-7638.2015.05.024
Abstract(42) PDF(2)
Abstract:
The causes of cracks forming in abrasion- resistant steel plate NM360 after cutting had been investigated by means of metallographic microscope and SEM. Observation shows that there are several segregations in the mid- depth of the plate and network carbide distributes along the grain boundary. The ...
Analysis on Non- uniform Hardness in Saw Blade of 65Mn Steel
Chen Liansheng, Qi Xiangyu, Song Jinying, Tian Yaqiang, Zhang Jianyang
2015, 36(5): 134-138. doi: 10.7513/j.issn.1004-7638.2015.05.025
Abstract(61) PDF(4)
Abstract:
The analysis of causes and influencing factors of hardness non- uniform in the 65 Mn saw blades with hot rolled steel had been performed by means of hardness,optical microscopy,SEM and EDS. The result shows that tnon- uniform hardness of 65 Mn hot rolled steel is caused by non- uniform spacing of pe...
2015, 36(5): 139-140.
Abstract(41) PDF(2)
Abstract: