冶金固废载氧体耦合化学链气化制备富氢还原气的探讨

刘治桐; 张淑会; 兰臣臣; 吕庆; 张淑卿; 孙艳芹

doi:10.7513/j.issn.1004-7638.2025.02.015

冶金固废载氧体耦合化学链气化制备富氢还原气的探讨

doi: 10.7513/j.issn.1004-7638.2025.02.015

1.
华北理工大学冶金与能源学院, 河北唐山 063210
2.
华北理工大学电气工程学院, 河北唐山 063210

基金项目: 唐山市科技计划资助项目（23130203E）；河北省创新能力提升计划项目（24461002D）。

详细信息

作者简介:
刘治桐，2000年出生，男，辽宁阜新人，硕士生，研究方向为低碳冶金，E-mail：lzt18740174840@163.com

通讯作者:
张淑会，1976年出生，女，河北定州人，博士，主要从事高炉低碳冶炼的研究，E-mail：zhangshuhui@ncst.edu.cn

中图分类号: TF09
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- 文章访问数: 36
- HTML全文浏览量: 13
- PDF下载量: 2
- 被引次数: 0
出版历程
- 收稿日期: 2024-09-11
- 刊出日期: 2025-05-06

Discussion on the preparation of hydrogen-rich reducing gas by coupling metallurgical solid waste oxygen carrier and chemical looping gasification technology

1.
College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, Hebei, China
2.
College of Electrical Engineering, North China University of Science and Technology, Tangshan 063210, Hebei, China

摘要

摘要: 氢气以及富氢还原气体的来源是制约氢能在钢铁行业应用的关键，而化学链气化技术可以制备高品质的富氢还原气体，其工艺成熟、成本低廉。载氧体是化学链气化技术中重要的媒介，基于载氧体的性能和类型，综述了化学链气化技术中铁基载氧体的应用现状，冶金固体废弃物载氧体的制备和应用，讨论了冶金固废载氧体耦合化学链气化技术制备富氢还原气体的可行性，并对冶金固废载氧体在化学链气化技术制备富氢还原气体领域的研究趋势和发展方向进行了展望。
- 冶金固体废弃物 /
- 载氧体 /
- 化学链气化 /
- 富氢还原气 /
- 资源循环利用
Abstract: The sources of hydrogen and hydrogen-rich reducing gases are the key factors restricting the application of hydrogen energy in the iron and steel industry. However, chemical looping gasification technology can produce high quality hydrogen-rich reducing gases, and this process is mature with low cost. Oxygen carriers play a crucial role in the chemical looping gasification technology. Based on the capabilities and categories of the oxygen carrier, this paper reviews the application of iron-based oxygen carriers in the chemical looping gasification technology. The preparation and utilization of oxygen carriers from metallurgical solid waste are described in detail. The feasibility of generating hydrogen-rich reducing gases by coupling metallurgical solid waste oxygen carriers with chemical looping gasification technology is discussed further. Finally, the research trends and future development directions of solid waste oxygen carriers by using chemical looping gasification technology to produce hydrogen-rich reducing gas are prospected.
- metallurgical solid waste /
- oxygen carriers /
- chemical looping gasification /
- hydrogen-rich reducing gas /
- resources recycling

HTML全文

图 1 不同掺杂比例Co金属改性Ca₂Fe₂O₅载氧体对合成气产率的影响^[27]

Figure 1. Effect of Co metal modified Ca₂Fe₂O₅ oxygen carriers with different doping ratios on the syngas yield^[27]

下载: 全尺寸图片幻灯片

图 2 不同铁基载氧体化学链气化性能参数对比^[29]

(a)添加水蒸气；（b）未添加水蒸气

Figure 2. Comparison of the chemical looping gasification performance parameters of different iron based oxygen carriers^[29]

下载: 全尺寸图片幻灯片

图 3 以赤泥做载氧体不同温度下蓝藻气化合成气中H₂/CO^[40]

Figure 3. H₂/CO in the cyanobacteria gasification syngas at different temperatures using the red mud as oxygen carriers^[40]

下载: 全尺寸图片幻灯片

图 4 掺杂Ni金属铜渣对合成气组分产率的影响^[45]

Figure 4. Influence of the Ni doped metal copper slag on syngas component yield^[45]

下载: 全尺寸图片幻灯片

图 5 钢渣还原-氧化循环5次和10次后的微观形貌^[53]

(a) 转炉渣-还原氧化循环5次；(b)电炉渣-还原氧化循环5次；(c)转炉渣-还原氧化循环10次；(d)电炉渣-还原氧化循环10次

Figure 5. Microstructures of steel slag after 5 and 10 cycles of reduction-oxidation^[53]

下载: 全尺寸图片幻灯片

表 1 典型赤泥的化学成分^[38−39]

Table 1. Chemical compositions of typical red mud^[38−39] %

样本	文山赤泥	西安赤泥	广西赤泥	越南赤泥	中州赤泥	河南赤泥	山东赤泥
Fe₂O₃	29.34	42.31	74.28	70.32	14.97	26.80	13.94
Al₂O₃	25.46	19.53	12.68	10.86	23.78	28.65	27.15
SiO₂	19.39	17.64	3.13	11.53	20.71	25.91	22.34
TiO₂	5.41	5.64	6.10	0.68	4.97	1.79	4.97
Na₂O	6.20	5.99	0.07	0.61	5.36	12.66	2.50
CaO	13.69	0.61	2.65	0.65	15.64	2.31	22.78
其他	0.51	8.28	1.09	5.35	14.57	1.88	6.32

下载: 导出CSV

表 2 不同铜冶炼工艺的铜渣组成^[43]

Table 2. Compositions of copper slag in the different copper smelting processes^[43] %

冶炼方法	SiO₂	FeO	Fe₂O₃	CaO	MgO	Al₂O₃	Cu
密闭鼓风法	31~39	33~42	3~10	6~19	0.8~7.0	4~12	0.35~2.4
转炉法	16~28	48~65	12~29	1~2	0~2	5~10	1.1~2.9
艾萨法	31~34	40~58	7.5	2.3	2.0	0.2	0.6
闪速熔炉法	28~38	38~54	12~15	5~15	1~3	2~12	0.17~0.33

下载: 导出CSV

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