摘要:
为了改善植入体材料医用钛合金的综合力学性能及耐腐蚀性,采用粉末冶金法制备Ti-29Nb-4Mo-13Ta-9Zr合金。通过X射线衍射、金相显微镜、扫描电镜、压缩试验及动电位极化曲线测试,研究烧结温度对合金的物相组成、显微结构、抗压强度、弹性模量及电化学腐蚀性的影响。结果表明:随着烧结温度的增加,Ti-29Nb-4Mo-13Ta-9Zr合金出现稳定的β相组织,合金的致密度逐渐增加;当烧结温度为1350℃时,合金的抗压强度为780 MPa,弹性模量相对较低约为66 GPa,综合力学适应性较好,自腐蚀电压较大约为-187.09 mV,自腐蚀电流较小约为11.172μA/cm2,耐腐蚀性明显提高,成为新型医用植入体的潜力材料。
Abstract:
In order to improve the comprehensive mechanical properties and corrosion resistance of titanium alloy used as medical implant materials,Ti-29Nb-4Mo-13Ta-9Zr alloy was prepared by powder metallurgy.The effects of sintering temperature on the phase compositions,microstructure,compressive strength,elastic modulus and electrochemical corrosion of the alloy were studied by X-ray diffraction,metallographic microscope,scanning electron microscope,compression test and potentiodynamic polarization curve test.The results indicate that the stable β phase structure in Ti-29Nb-4Mo-13Ta-9Zr alloy can be formed and the density of the alloy gradually increases with increase of the sintering temperature.At 1 350 ℃ of sintering temperature,the compressive strength of the alloy is 780 MPa and the elastic modulus is about 66 GPa,which improves the comprehensive mechanical adaptability of the alloy.Potentiodynamic polarization curves exhibit that Ti-29Nb-4Mo-13Ta-9Zr alloy sintered at 1 350 ℃ has a self-corrosion voltage of-187.09 mV and self-corrosion current of 11.172 μA/cm2,indicating a better corrosion resistance.Thus,Ti-29Nb-4Mo-13Ta-9Zr alloy is a potential material for implant applications.