Numerical Simulation on Scabbing in Oxidation Reactor for Chloride Process Titanium Dioxide
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摘要: 针对某氯化钛白氧化反应器内结疤现状,结合试验分析和数值模拟结果,分析了氧化反应器内结疤产生的原因,得出以下结论:在氧化反应器四氯化钛进料环缝前,结疤主要原因在于高温气体受低温壁面影响而附着停留。增加反应器壁面温度,减少气体的液化是解决环缝前结疤的关键措施。氧化反应器的结构直接影响混合流体的流动状态。增加氧化反应器四氯化钛进料环缝宽度,优化四氯化钛与氧气混合动量比,能有效缓解氧化反应器四氯化钛进料环缝后结疤问题。氧化反应器内疤料的形成减小了管道内径,使系统压力急剧升高,直接导致停炉,缩短系统运行周期。Abstract: Combined with the experimental analyses and numerical simulation,the factors influencing the scarring were analyzed based on the current situation of scarring in an oxidation reactor for chloride process titanium dioxide.The results show that the high temperature gas tends to adhere on the cold wall of gap before TiCl4 feeding,causing scabbing of the oxidation reactor.The ways to prevent scabbing before feeding gap include the enhancement of wall temperature of the reactor and decrease of the gas liquefaction.The fluidization state of mixed fluids is affected by the structure of the oxidation reactor.Increasing the width of feeding gap and optimizing the momentum ratio of TiCl4 and O2 can effectively prevent and decrease the scabbing after the feeding gap.The scabbing reduces the inner diameter of the reactor and increases the system pressure dramatically,which leads to shutdown of the furnace and shortens the operation cycle.
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Key words:
- chloride process titanium dioxide /
- oxidation reactor /
- scarring /
- numerical simulation
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