摘要:
通过采用A精粉、B精粉和轻烧白云石改变球团矿中MgO含量来研究MgO对生球质量和酸性球团矿抗压强度的影响。研究发现:生球的抗压强度和落下强度随着MgO含量的增大先降低后升高, 热爆裂温度先升高后降低, 生球质量的变化主要与矿粉的比表面积等基础性能相关;经过焙烧的球团矿抗压强度随着MgO含量的增加而降低, 一分部Mg原子进入到赤铁矿晶体中并替代了Fe原子, Mg-O键键强低于Fe-O键键强, 同时一少部分MgO进入到渣相中破坏了硅酸盐网络结构, 改善了渣相的流动性, 其中一部分渣相分散到赤铁矿晶粒之间, 其它渣相互聚集一起, 冷却后渣相和赤铁矿晶粒间空隙增大, 导致球团矿抗压强度降低。
Abstract:
Magnesium oxide plays a crucial role in the progress of blast furnace production. In this paper the effect of magnesium oxide on the green ball quality and cruslring strength of acid pellets had been investigated through changing the content of magnesium oxide by adoption of A fine powder,B fine powder and light burned dolomite. It was found out that with the increase of magnesium oxide content,the compressive strength and falling strength of the green ball firstly decreases and then increases,and its thermal explosion temperature firstly increases and then decreases,the change of the green ball quality is mainly related to mineral powder foundation properties such assurface area. The compressive strength of pellets after roasting reduces with the increase of the magnesium oxide content since a portion of the Mg atoms move into hematite and replaces the Fe atoms in crystal,and the strength of Mg-O bond is lower than the strength of Fe-O bond. At the same time,a few magnesium oxide get into the slag phase and destroy the silicate network structure,which improve the liquidity of the slag phase. Parts of the slag phases are dispersed into hematite between grains,other slag phases gather together,the gap between slag phase and hematite becomes more border with the decrease of temperature,resulting in the decrease of compressive strength of the pellets.