Abstract: In order to resolve the technological problems of precipitation of ammonium polyvanadate （APV） by ammonium salts under acid conditions using high concentration of sodium-containing vanadium solution,the dripping method was adopted to prepare APV under acid conditions with the high concentration of sodium-containing vanadium solution as raw material. The results show that through the dripping method the precipitation rate of vanadium is more than 99% with 50.51% of vanadium,0.089% of Na₂O and 0.074% of sulphur （S） in the obtained APV,under the conditions of 2.30 for reaction pH,90 ℃ of reaction temperature,ammonium addition coefficient K = 1.0 and 10% of addition amount for A seed crystals. After calcination,the quality of obtained vanadium pentoxide （V₂O₅） satisfies the requirements of YB/T5304—2011 standard. This new method can realize the production capacity enhancement and decrease the energy consumption,wastewater treatment burden and production cost significantly.