Effect of Rare Earth Treatment on Inclusion of E36 Slab for Shipbuilding
-
摘要: 为了控制钢液中夹杂物的形态,确定稀土Y和Ce与O、S反应的先后顺序及稀土夹杂物的形成规律,对E36船板钢稀土变性夹杂进行了热力学计算和试验研究,运用扫描电镜及能谱仪观察分析了E36铸坯中典型夹杂物。实践结果表明:Ce与Y相比要优先与O、S反应;稀土夹杂物形成的顺序为Re2O3、Re2O2S、Re2S3;生成的稀土复合夹杂物尺寸以15、50μm为主,相比未加稀土的夹杂物减少了20~55μm,并且呈规则球状。稀土氧化物多位于铸坯上1/4,稀土硫氧化物多位于铸坯的1/2处;稀土能改善夹杂物的形态、尺寸,对改善钢的性能非常有利。Abstract: In order to control the shape of inclusions in steel liquid and determine the rare earth Y and Ce and O,S reaction sequenceand the formation of the rare earth inclusions,the rare earth degeneration inclusion in E36 ship plate steel had been investigated through thermodynamic calculation and experimental study,and the typical inclusion had been observed using scanning electron microscopyand EDS.It is found out that Ce has more tendency to react with O and S than Y.The sequenceof the rare earth inclusions formed are Re2O3,Re2O2 S,Re2S3.The dominant rare earth compound inclusions are sizes at~15 μm and~50 μm.Compared with the inclusion of steel without rare earth addition,the inclusion size of RE treated steel reduces by 20~55 μm and its shape are more globular.Rare earth oxides mostly locates on the 1/4 thickness of upper surface and rare earth sulfur oxides locates on the 1/2 thickness.Rare earth addition can improve the morphology and size of inclusion,and thusimprove the performance of the steel.
-
Key words:
- E36 ship plate /
- yttrium base of rare earth /
- thermodynamics /
- inclusions
-

计量
- 文章访问数: 51
- HTML全文浏览量: 14
- PDF下载量: 2
- 被引次数: 0