Reduction Behaviors of Pellets under High Reduction Potential
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摘要: 炉顶煤气循环氧气高炉采用纯氧鼓风以及炉顶煤气循环利用工艺使得炉内煤气成分与传统高炉相比发生了改变,炉内的煤气成分主要以H2和CO为主。为了研究还原性气体H2和CO对球团矿还原行为的影响,分别用H2-N2、CO-N2、H2-CO混合气体在1173K下通过热重的方法进行试验。研究发现还原度随着混合气体中H2或CO比例的增加而增加,但是H2的还原能力明显比CO要强。在H2-CO混合气体中H2的加入有利于还原进行。用H2-CO混合气体还原得到的还原速率不能用H2-N2和CO-N2混合气体下得到的还原速率相加得到。微观结构观察发现,用H2进行还原时得到的铁结构较致密,而用CO还原时铁会破裂为许多小碎片。在用含一氧化碳的混合气体进行还原时,还原度曲线在还原后期由于碳沉积导致出现下降的趋势。还原气体中氢气的存在会加剧碳沉积现象,而氮气的存在会抑制这一现象。对还原后试样进行X射线衍射以及化学分析表明试样中的碳以碳化铁(Fe3C)和石墨形式存在。Abstract: As processes of pure oxygen blast and top gas recycling are applied in the top gas recycling oxygen blast furnace,gas compositions in the furnace are dominated by H2 and CO,which are quite different from those in traditional blast furnace.In order to study the influence of H2 and CO on reduction behavior of pellets,experiments were conducted with mixed gas H2-N2,CO-N2 and H2-CO respectively at 1173K by measuring the weight loss.It is found that the reduction degree increases with the increase in H2 or CO ratio in the mixed gas,but the reduction with hydrogen is faster than that with carbon monoxide.The increase in hydrogen content in H2-CO mixture improves the reduction rate while the increase in carbon monoxide in H2-CO mixture lowers the reduction rate.The reduction rate of pellets under H2-CO atmosphere can not be simply calculated by adding together the reduction rates under H2-N2 and CO-N2 atmosphere.The result shows that dense structure of iron is obtained in the reduction with hydrogen while the iron falls apart in the reduction with carbon monoxide.As gas mixture containing carbon monoxide was taken as reducing agent,the reduction curve showed a declining trend due to carbon deposition at the later stage of reduction.It is concluded that the existence of H2 could aggravate the carbon deposition while existence of N2 could restrain carbon deposition.The results of X-ray diffraction and chemical analysis demonstrate carbon in the reduced sample mainly exits in the form of cementite(Fe3C) and graphite.
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Key words:
- pellets /
- reduction /
- hydrogen /
- carbon monoxide /
- high reduction potential /
- carbon deposition
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