Discussion on Routes of Recycling Waste Water Produced from APV Precipitation with Acidic Ammonium Salts
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摘要: 根据酸性铵盐沉钒废水的特性,提出其在沉淀设备冲淋、尾渣洗涤和熟料浸出三个方面进行循环利用的途径,并开展相关试验。结果表明:APV在pH值为2.5~3.5的水溶液中溶解的V浓度低于0.15 g/L,利用酸性铵盐沉钒废水作沉淀设备冲淋水能有效解决APV返溶问题,从而减少钒损失。当洗涤温度大于90℃,液固比超过2.5,洗涤时间达到45 min以上,洗涤次数超过3次时,使用酸性铵盐沉钒废水洗涤尾渣的效果优于生产水。用沉钒废水浸出焙烧熟料是完全可行的,其浸出液具有除磷优势。Abstract: Routes of recycling waster water produced from APV precipitation with acidic ammonium salts are proposed,which is expected to be used for rinsing precipitation equipment,washing tailings and leaching roasted materials and corresponding experiments are carried out.The experimental results show that use of waste water for rinsing precipitation equipment can effectively solve the problem of APV redissolution as vanadium concentration of APV is less than 0.15 g/L in the solution with pH value of 2.5~3.5,thus reducing vanadium loss.Using waste water instead of production water offers a better option to wash tailings when washing is conducted at 90 ℃ above,with liquid/solid ratio more than 2.5,for more than 3 times and at least 45 minutes each time.Using waste water for leaching roasted materials is practicable and the leached solution is more desirable for dephosphorization.
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Key words:
- acidic ammonium salts /
- APV precipitation /
- waste water /
- recycling
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